Mechanically and chemically robust ZIF-8 monoliths with high volumetric adsorption capacity

The resultant monoliths are mechanically robust structures and present up to 3 times higher volumetric adsorption capacities than the conventional, powder MOF.This work was funded by the EPSRC IAA Partnership Development Award (RG/75759). D.F.-J. thanks the Royal Society for funding through a University Research Fellowship. T.D.B would like to thank Trinity Hall for funding and Professor Anthony Cheetham for use of lab facilities and equipmentThis is the accepted manuscript of a paper published in the Journal of Materials Chemistry A (Tian T, Velazquez-Garcia J, Bennett TD, Fairen-Jimenez D, Journal of Materials Chemistry A, 2015, 3, 2999-3005, doi:10.1039/c4ta05116e). The final version is available at http://dx.doi.org/10.1039/c4ta05116e

Blue spectra and induced formation of primordial black holes

We investigate the statistical properties of primordial black hole (PBH) formation in the very early Universe. We show that the high level of inhomogeneity of the early Universe leads to the formation of the first generation PBHs. %The existence of these PBHs This causes later the appearance of a dust-like phase of the cosmological expansion. We discuss here a new mechanism for the second generation of PBH formation during the dust-like phase. This mechanism is based on the coagulation process. We demonstrate that the blue power spectrum of initial adiabatic perturbations after inflation leads to overproduction of primordial black holes with $10^9$g$\le M\le10^{15}$g if the power index is $n\ge1.2$.Comment: 16 pages, 2 figure

Closed timelike curves via post-selection: theory and experimental demonstration

Closed timelike curves (CTCs) are trajectories in spacetime that effectively travel backwards in time: a test particle following a CTC can in principle interact with its former self in the past. CTCs appear in many solutions of Einstein's field equations and any future quantum version of general relativity will have to reconcile them with the requirements of quantum mechanics and of quantum field theory. A widely accepted quantum theory of CTCs was proposed by Deutsch. Here we explore an alternative quantum formulation of CTCs and show that it is physically inequivalent to Deutsch's. Because it is based on combining quantum teleportation with post-selection, the predictions/retrodictions of our theory are experimentally testable: we report the results of an experiment demonstrating our theory's resolution of the well-known `grandfather paradox.Comment: 5 pages, 4 figure

Cosmic Microwave Background Temperature and Polarization Anisotropy in Brans-Dicke Cosmology

We develop a formalism for calculating cosmic microwave background (CMB) temperature and polarization anisotropies in cosmological models with Brans-Dicke gravity. We then modify publicly available Boltzmann codes to calculate numerically the temperature and polarization power spectra. Results are illustrated with a few representative models. Comparing with the general-relativistic model with the same cosmological parameters, both the amplitude and the width of the acoustic peaks are different in the Brans-Dicke models. We use a covariance-matrix calculation to investigate whether the effects of Brans-Dicke gravity are degenerate with those of variation in other cosmological parameters and to simultaneously determine whether forthcoming CMB maps might be able to distinguish Brans-Dicke and general-relativistic cosmology. Although the predicted power spectra for plausible Brans-Dicke models differ from those in general relativity only slightly, we find that MAP and/or the Planck Surveyor may in principle provide a test of Brans-Dicke theory that is competitive to solar-system tests. For example, if all other parameters except for the CMB normalization are fixed, a value of the Brans-Dicke parameter omega as large as 500 could be identified with MAP, and for Planck, values as large as omega \simeq3000 could be identified; these sensitivities are decreased roughly by a factor of 3 if we marginalize over the baryon density, Hubble constant, spectral index, and reionization optical depth. In more general scalar-tensor theories, omega may evolve with time, and in this case, the CMB probe would be complementary to that from solar-system tests.Comment: 27 pages, 10 figures, typeset using RevTe

Mapping sites of gibberellin biosynthesis in the Arabidopsis root tip

● Root elongation depends on the action of the gibberellin (GA) growth hormones, which promote cell production in the root meristem and cell expansion in the elongation zone. Sites of GA biosynthesis in the roots of 7 day-old Arabidopsis thaliana seedlings were investigated using tissue-specific GA inactivation in wild type (Col-0) or rescue of GA-deficient dwarf mutants. ● Tissue specific GA-depletion was achieved by ectopic expression of the GA-inactivating enzyme AtGA2ox2, which is specific for C19-GAs, and AtGA2ox7, which acts on C20-GA precursors. In addition, tissue-specific rescue of ga20ox triple and ga3ox double mutants was shown. Furthermore, GUS reporter lines for major GA20ox, GA3ox and GA2ox genes were used to observe their expression domains in the root. ● The effects of expressing these constructs on the lengths of the root apical meristem and cortical cells in the elongation zone confirmed that roots are autonomous for GA biosynthesis, which occurs in multiple tissues, with the endodermis a major site of synthesis. ● The results are consistent with the early stages of GA biosynthesis within the root occurring in the meristematic region and indicate that the penultimate step of GA biosynthesis, GA 20-oxidation, is required in both the meristem and elongation zone

Dusty Nuclear Disks and Filaments in Early Type Galaxies

We examine the dust properties of a nearby distance-limited sample of early type galaxies using the WFPC2 of the Hubble Space Telescope. Dust is detected in 29 out of 67 galaxies (43%), including 12 with small nuclear dusty disks. In a separate sample of 40 galaxies biased for the detection of dust by virtue of their detection in the IRAS 100 micron band, dust is found in ~78% of the galaxies, 15 of which contain dusty disks. In those galaxies with detectable dust, the apparent mass of the dust correlates with radio and far infrared luminosity, becoming more significant for systems with filamentary dust. A majority of IRAS and radio detections are also associated with dusty galaxies rather than dustless galaxies. This indicates that thermal emission from clumpy, filamentary dust is the main source of the far-IR radiation in early type galaxies. Dust in small disk-like morphology tends to be well aligned with the major axis of the host galaxies, while filamentary dust appears to be more randomly distributed with no preference for alignment with any major galactic structure. This suggests that, if the dusty disks and filaments have a common origin, the dust originates externally and requires time to dynamically relax and settle in the galaxy potential in the form of compact disks. More galaxies with visible dust than without dust display emission lines, indicative of ionized gas, although such nuclear activity does not show a preference for dusty disk over filamentary dust. There appears to be a weak relationship between the mass of the dusty disks and central velocity dispersion of the galaxy, suggesting a connection with a similar recently recognized relationship between the latter and the black hole mass.Comment: 17 pages, including 10 figures & 7 tables, to be published in the Astronomical Journa

Microwave and Millimeter Wave Techniques

Contains reports on two research projects.Joint Services Electronics Program (Contract DAAG29-78-C-0020)National Science Foundation (Grant AST77-26896

Quantum fluctuations and CMB anisotropies in one-bubble open inflation models

We first develop a method to calculate a complete set of mode functions which describe the quantum fluctuations generated in one-bubble open inflation models. We consider two classes of models. One is a single scalar field model proposed by Bucher, Goldhaber and Turok and by us as an example of the open inflation scinario, and the other is a two-field model such as the ``supernatural'' inflation proposed by Linde and Mezhlumian. In both cases we assume the difference in the vacuum energy density between inside and outside the bubble is negligible. There are two kinds of mode functions. One kind has usual continuous spectrum and the other has discrete spectrum with characteristic wavelengths exceeding the spatial curvature scale. The latter can be further devided into two classes in terms of its origin. One is called the de Sitter super-curvature mode, which arises due to the global spacetime structure of de Sitter space, and the other is due to fluctuations of the bubble wall. We calculate the spectrum of quantum fluctuations in these models and evaluate the resulting large angular scale CMB anisotropies. We find there are ranges of model parameters that are consistent with observed CMB anisotropies.Comment: 22 pages revtex file, 12 postscript figures, tarred, gzippe