Synergistic effects of ultraviolet radiation, thermal cycling, and atomic oxygen on altered and coated Kapton surfaces

The photovoltaic (PV) power system for Space Station Freedom (SSF) uses solar array blankets which provide structural support for the solar cells and house the electrical interconnections. In the low Earth orbital (LEO) environment where SSF will be located, surfaces will be exposed to potentially damaging environmental conditions including solar ultraviolet (UV) radiation, thermal cycling, and atomic oxygen. It is necessary to use ground based tests to determine how these environmental conditions would affect the mass loss and optical properties of candidate SSF blanket materials. Silicone containing, silicone coated, and SiO(x) coated polyimide film materials were exposed to simulated LEO environmental conditions to determine there durability and whether the environmental conditions of UV, thermal cycling and oxygen atoms act synergistically on these materials. A candidate PV blanket material called AOR Kapton, a polysiloxane polyimide cast from a solution mixture, shows an improvement in durability to oxygen atoms erosion after exposure to UV radiation or thermal cycling combined with UV radiation. This may indicate that the environmental conditions react synergistically with this material, and the damage predicted by exposure to atomic oxygen alone is more severe than that which would occur in LEO where atomic oxygen, thermal cycling and UV radiation are present together

Simulation of the synergistic low Earth orbit effects of vacuum thermal cycling, vacuum UV radiation, and atomic oxygen

In order to assess the low Earth orbit (LEO) durability of candidate space materials, it is necessary to use ground laboratory facilities which provide LEO environmental effects. A facility combining vacuum thermal cycling and vacuum ultraviolet (VUV) radiation has been designed and constructed at NASA Lewis Research Center for this purpose. This facility can also be operated without the VUV lamps. An additional facility can be used to provide VUV exposure only. By utilizing these facilities, followed by atomic oxygen exposure in an RF plasma asher, the effects of the individual vacuum thermal cycling and VUV environments can be compared to the effect of the combined vacuum thermal cycling/VUV environment on the atomic oxygen durability of materials. The synergistic effects of simulated LEO environmental conditions on materials were evaluated by first exposing materials to vacuum thermal cycling, VUV, and vacuum thermal cycling/VUV environments followed by exposure to atomic oxygen in an RP plasma asher. Candidate space power materials such as atomic oxygen protected polyimides and solar concentrator mirrors were evaluated using these facilities. Characteristics of the Vacuum Thermal Cycling/VUV Exposure Facility which simulates the temperature sequences and solar ultraviolet radiation exposure that would be experienced by a spacecraft surface in LEO are discussed. Results of durability evaluations of some candidate space power materials to the simulated LEO environmental conditions will also be discussed. Such results have indicated that for some materials, atomic oxygen durability is affected by previous exposure to thermal cycling and/or VUV exposure

Standardized Entrance Assessment in Kindergarten: A Qualitative Analysis of the Experiences of Teachers, Administrators, and Parents

A brief narrative description of the journal article, document, or resource. This qualitative study examined experiences of teachers, parents, and administrators related to standardized kindergarten entrance assessment to identify strengths and weaknesses of standardized testing in kindergarten. Strengths emerging from the data included consistency of information with core curriculum, and the time and opportunity to begin parent-teacher dialogue. Weaknesses included the narrow scope of the information obtained. (Author/KB

Socio-Dramatic Play as a Vehicle for Curriculum Integration in First Grade

A brief narrative description of the journal article, document, or resource. Describes how the sociodramatic play experiences of a group of first graders served as a vehicle for integrating the classroom curriculum. Considers play as a curricular tool and adults\u27 roles in sociodramatic play. Shows how first-graders\u27 play in connection with creating a card shop incorporated reading, writing, and mathematical skills, and provided opportunities for peer collaboration and teaching. (KB

Perfect State Transfer in Laplacian Quantum Walk

For a graph $G$ and a related symmetric matrix $M$, the continuous-time quantum walk on $G$ relative to $M$ is defined as the unitary matrix $U(t) = \exp(-itM)$, where $t$ varies over the reals. Perfect state transfer occurs between vertices $u$ and $v$ at time $\tau$ if the $(u,v)$-entry of $U(\tau)$ has unit magnitude. This paper studies quantum walks relative to graph Laplacians. Some main observations include the following closure properties for perfect state transfer: (1) If a $n$-vertex graph has perfect state transfer at time $\tau$ relative to the Laplacian, then so does its complement if $n\tau$ is an integer multiple of $2\pi$. As a corollary, the double cone over any $m$-vertex graph has perfect state transfer relative to the Laplacian if and only if $m \equiv 2 \pmod{4}$. This was previously known for a double cone over a clique (S. Bose, A. Casaccino, S. Mancini, S. Severini, Int. J. Quant. Inf., 7:11, 2009). (2) If a graph $G$ has perfect state transfer at time $\tau$ relative to the normalized Laplacian, then so does the weak product $G \times H$ if for any normalized Laplacian eigenvalues $\lambda$ of $G$ and $\mu$ of $H$, we have $\mu(\lambda-1)\tau$ is an integer multiple of $2\pi$. As a corollary, a weak product of $P_{3}$ with an even clique or an odd cube has perfect state transfer relative to the normalized Laplacian. It was known earlier that a weak product of a circulant with odd integer eigenvalues and an even cube or a Cartesian power of $P_{3}$ has perfect state transfer relative to the adjacency matrix. As for negative results, no path with four vertices or more has antipodal perfect state transfer relative to the normalized Laplacian. This almost matches the state of affairs under the adjacency matrix (C. Godsil, Discrete Math., 312:1, 2011).Comment: 26 pages, 5 figures, 1 tabl

Evaporation of ices near massive stars: models based on laboratory TPD data

Hot cores and their precursors contain an integrated record of the physics of the collapse process in the chemistry of the ices deposited during that collapse. In this paper, we present results from a new model of the chemistry near high mass stars in which the desorption of each species in the ice mixture is described as indicated by new experimental results obtained under conditions similar to those hot cores. Our models show that provided there is a monotonic increase in the temperature of the gas and dust surrounding the protostar, the changes in the chemical evolution of each species due to differential desorption are important. The species H$_2$S, SO, SO$_2$, OCS, H$_2$CS, CS, NS, CH$_3$OH, HCOOCH$_3$, CH$_2$CO, C$_2$H$_5$OH show a strong time dependence that may be a useful signature of time evolution in the warm-up phase as the star moves on to the Main Sequence. This preliminary study demonstrates the consequences of incorporating reliable TPD data into chemical models.Comment: 5 pages, accepted by MNRA

Using Picture Books as a Vehicle to Teach Young Children about Social Justice

Most teachers and administrators have witnessed children using a derogatory reference to a group of people as a put down. Put downs usually reference non-mainstream groups who are different in ethnicity, gender, religion, ability, sexual orientation, class, or appearance. Hurtful name calling is but one example of how children express prejudiced beliefs and attitudes toward particular groups of people; non-mainstream children are also often excluded by their peers from activities and social events. Teachers of young children have the challenging task to help eradicate prejudice and discrimination by teaching about social justice. The purpose of this article is to share a strategy for teaching young children about social justice. Described is a project where second graders responded to picture books that focus on social justice issues. Reading and writing were integrated as children listened to stories with social justice themes, briefly discussed them, and then wrote in their response journals. The primary focus of this article is on the children\u27s written responses. Examples of books that engender discussion about social justice is included. (Contains 1 table and 7 endnotes.

The effects of simulated low Earth orbit environments on spacecraft thermal control coatings

Candidate Space Station Freedom radiator coatings including Z-93, YB-71, anodized aluminum and SiO(x) coated silvered Teflon have been characterized for optical properties degradation upon exposure to environments containing atomic oxygen, vacuum ultraviolet (VUV) radiation, and/or silicone contamination. YB-71 coating showed a blue-gray discoloration, which has not been observed in space, upon exposure in atomic oxygen facilities which also provide exaggerated VUV radiation. This is evidence that damage mechanisms occur in these ground laboratory facilities which are different from those which occur in space. Radiator coatings exposed to an electron cyclotron resonance (ECR) atomic oxygen source in the presence of silicone-containing samples showed severe darkening from the intense VUV radiation provided by the ECR and from silicone contamination. Samples exposed to atomic oxygen from the ECR source and to VUV lamps, simultaneously, with in situ reflectance measurement, showed that significantly greater degradation occurred when samples received line-of-site ECR beam exposure than when samples were exposed to atomic oxygen scattered off of quartz surfaces without line-of-site view of the ECR beam. For white paints, exposure to air following atomic oxygen/VUV exposure reversed the darkening due to VUV damage. This illustrates the importance of in situ reflectance measurement

Low Earth orbital atomic oxygen environmental simulation facility for space materials evaluation

Simulation of low Earth orbit atomic oxygen for accelerated exposure in ground-based facilities is necessary for the durability evaluation of space power system component materials for Space Station Freedom (SSF) and future missions. A facility developed at the National Aeronautics and Space Administrations's (NASA) Lewis Research Center provides accelerated rates of exposure to a directed or scattered oxygen beam, vacuum ultraviolet (VUV) radiation, and offers in-situ optical characterization. The facility utilizes an electron-cyclotron resonance (ECR) plasma source to generate a low energy oxygen beam. Total hemispherical spectral reflectance of samples can be measured in situ over the wavelength range of 250 to 2500 nm. Deuterium lamps provide VUV radiation intensity levels in the 115 to 200 nm range of three to five equivalent suns. Retarding potential analyses show distributed ion energies below 30 electron volts (eV) for the operating conditions most suited for high flux, low energy testing. Peak ion energies are below the sputter threshold energy (approximately 30 eV) of the protective coatings on polymers that are evaluated in the facility, thus allowing long duration exposure without sputter erosion. Neutral species are expected to be at thermal energies of approximately .04 eV to .1 eV. The maximum effective flux level based on polyimide Kapton mass loss is 4.4 x 10 exp 6 atoms/((sq. cm)*s), thus providing a highly accelerated testing capability