1,353 research outputs found
Magnetic susceptibility of the frustrated spinels ZnCr2O4, MgCr2O4 and CdCr2O4
We analyzed the magnetic susceptibilities of several Cr spinels using two
recent models for the geometrically frustrated pyrochlore lattice, the Quantum
Tetrahedral Mean Field model and a Generalized Constant Coupling model. Both
models can describe the experimental data for ACr2 O4 (with A = Zn, Mg, and Cd)
satisfactorily, with the former yielding a somewhat better agreement with
experiment for A = Zn, Mg. The obtained exchange constants for nearest and
next-nearest neighbors are discussed.Comment: 4 pages, 1 figure, 1 table, conferenc
Tuning orbital-selective correlation effects in superconducting RbFeSeS
We report on terahertz time-domain spectroscopy on superconducting and
metallic iron chalcogenides RbFeSeS. The
superconducting transition is reduced from 32 K () to 22 K
(), and finally suppressed () by isoelectronic substitution of Se
with S. Dielectric constant and optical conductivity exhibit a
metal-to-insulator transition associated with an orbital-selective Mott phase.
This orbital-selective Mott transition appears at higher temperature
with increasing sulfur content, identifying sulfur substitution as an efficient
parameter to tune orbital-dependent correlation effects in iron-chalcogenide
superconductors. The reduced correlations of the charge carriers can
account for the suppression of the superconductivity and the pseudogap-like
feature between and that was observed for .Comment: 6 pages, 4 figure
Large and Small Polaron Excitations in La2/3(Sr/Ca)1/3MnO3 Films
We present detailed optical measurements of the mid-infrared (MIR)
excitations in thin films of La2/3Sr1/3MnO3 (LSMO) and La2/3Ca1/3MnO3 (LCMO)
across the magnetic transition. The shape of the excitation at about 0.2 eV in
both samples is analyzed in terms of polaron models. We propose to identify the
MIR resonance in LSMO as the excitation of large polarons and that in LCMO as a
small polaron excitation. A scaling behavior for the low-energy side of the
polaronic MIR resonance in LSMO is established
Evolution of optical properties of chromium spinels CdCrO, HgCrS, and ZnCrSe under high pressure
We report pressure-dependent reflection and transmission measurements on
ZnCrSe, HgCrS, and CdCrO single crystals at room
temperature over a broad spectral range 200-24000 cm. The pressure
dependence of the phonon modes and the high-frequency electronic excitations
indicates that all three compounds undergo a pressure-induced structural phase
transition with the critical pressure 15 GPa, 12 GPa, and 10 GPa for
CdCrO, HgCrS, and ZnCrSe, respectively. The
eigenfrequencies of the electronic transitions are very close to the expected
values for chromium crystal-field transitions. In the case of the chalcogenides
pressure induces a red shift of the electronic excitation which indicates a
strong hybridization of the Cr d-bands with the chalcogenide bands.Comment: Accepted for publication in Phys. Rev.
Correlation of structural and spectroscopic properties of a photosynthetic reaction center
Polarized spectra of absorption and light-induced absorbance changes are presented for the crystallized reaction centers of Rhodopseudomonas viridis. We find that a model based on extended dipole interaction between all six pigments is capable of interpreting detailed features such as the contributions from the individual pigments to the various absorption peaks. Even though the pigments are arranged in approximate C2 symmetry, the optical spectra together with the calculations reflect deviations from this symmetry, which may be important in understanding the electron pathway
Femtosecond studies of the reaction center of Rhodopseudomonas viridis: The very first dynamics of the electron-transfer processes
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