Strong and Confined Acids Enable a Catalytic Asymmetric Nazarov Cyclization of Simple Divinyl Ketones

We report a catalytic asymmetric Nazarov cyclization of simple, acylic, alkyl-substituted divinyl ketones using our recently disclosed strong and confined imidodiphosphorimidate Brønsted acids. The corresponding monocyclic cyclopentenones are formed in good yields and excellent regio-, diastereo-, and enantioselectivities. Further, the chemical utility of the obtained enantiopure cyclopentenones is demonstrated

Lattice Simulation of Nuclear Multifragmentation

Motivated by the decade-long debate over the issue of criticality supposedly observed in nuclear multifragmentation, we propose a dynamical lattice model to simulate the phenomenon. Its Ising Hamiltonian mimics a short range attractive interaction which competes with a thermal-like dissipative process. The results here presented, generated through an event-by-event analysis, are in agreement with both experiment and those produced by a percolative (non-dynamical) model.Comment: 8 pages, 3 figure

Contractions, Hopf algebra extensions and cov. differential calculus

We re-examine all the contractions related with the ${\cal U}_q(su(2))$ deformed algebra and study the consequences that the contraction process has for their structure. We also show using ${\cal U}_q(su(2))\times{\cal U}(u(1))$ as an example that, as in the undeformed case, the contraction may generate Hopf algebra cohomology. We shall show that most of the different Hopf algebra deformations obtained have a bicrossproduct or a cocycle bicrossproduct structure, for which we shall also give their dual `group' versions. The bicovariant differential calculi on the deformed spaces associated with the contracted algebras and the requirements for their existence are examined as well.Comment: TeX file, 25 pages. Macros are include