Ground states with cluster structures in a frustrated Heisenberg chain

We examine the ground state of a Heisenberg model with arbitrary spin S on a one-dimensional lattice composed of diamond-shaped units. A unit includes two types of antiferromagnetic exchange interactions which frustrate each other. The system undergoes phase changes when the ratio $\lambda$ between the exchange parameters varies. In some phases, strong frustration leads to larger local structures or clusters of spins than a dimer. We prove for arbitrary S that there exists a phase with four-spin cluster states, which was previously found numerically for a special value of $\lambda$ in the S=1/2 case. For S=1/2 we show that there are three ground state phases and determine their boundaries.Comment: 4 pages, uses revtex.sty, 2 figures available on request from [email protected], to be published in J. Phys.: Cond. Mat

Effects of Single-site Anisotropy on Mixed Diamond Chains with Spins 1 and 1/2

Effects of single-site anisotropy on mixed diamond chains with spins 1 and 1/2 are investigated in the ground states and at finite temperatures. There are phases where the ground state is a spin cluster solid, i.e., an array of uncorrelated spin-1 clusters separated by singlet dimers. The ground state is nonmagnetic for the easy-plane anisotropy, while it is paramagnetic for the easy-axis anisotropy. Also, there are the N\'eel, Haldane, and large-$D$ phases, where the ground state is a single spin cluster of infinite size and the system is equivalent to the spin-1 Heisenberg chain with alternating anisotropy. The longitudinal and transverse susceptibilities and entropy are calculated at finite temperatures in the spin-cluster-solid phases. Their low-temperature behaviors are sensitive to anisotropy.Comment: 8 pages, 4 figure

Bosonic representation of one-dimensional Heisenberg ferrimagnets

The energy structure and the thermodynamics of ferrimagnetic Heisenberg chains of alternating spins S and s are described in terms of the Schwinger bosons and modified spin waves. In the Schwinger representation, we average the local constraints on the bosons and diagonalize the Hamiltonian at the Hartree-Fock level. In the Holstein-Primakoff representation, we optimize the free energy in two different ways introducing an additional constraint on the staggered magnetization. A new modified spin-wave scheme, which employs a Lagrange multiplier keeping the native energy structure free from temperature and thus differs from the original Takahashi Scheme, is particularly stressed as an excellent language to interpret one-dimensional quantum ferrimagnetism. Other types of one-dimensional ferrimagnets and the antiferromagnetic limit S=s are also mentioned.Comment: to be published in Phys. Rev. B 69, No. 6, 0644XX (2004

Finite Temperature Properties of the Mixed Diamond Chain with Spins 1 and 1/2

We formulate statistical mechanics for the mixed diamond chain with spins of magnitudes 1 and 1/2. Owing to a series of conservation laws, any eigenstate of this system is decomposed into eigenstates of finite odd-length spin-1 chains. The ground state undergoes five quantum phase transitions with varying the parameter $\lambda$ controlling frustration. We obtain the values of the residual entropy and the Curie constant which characterize each phase and phase boundary at low temperatures. We further find various characteristic finite-temperature properties such as the nonmonotonic temperature dependence of the magnetic susceptibility, the multipeak structure in the $\lambda$-dependence of entropy, the plateau-like temperature dependence of entropy and the multipeak structure of specific heat.Comment: 23 pages, 10 figure

Infrared absorption by a tunneling proton in crystalline 5-bromo-9-hydroxyphenalenone

5-bromo-9-hydroxyphenalenone absorbs infrared radiation strongly at $\rm 83\; cm^{-1}$ when cooled to 5 K. The absorption is attributed to a transition from the ground state to the first excited state of a tunneling proton in a double-well potential of the intramolecular hydrogen bond. The temperature dependence of the spectrum was studied in detail. The linewidth was exceptionally large. Two mechanisms of the broadening are discussed. The atomic motion in a deuterated crystal corresponding to the tunneling freezes at 34 K in a deuteration-induced phase transition. This is the first spectroscopic evidence for the absorption of radiation by a tunneling proton in a neat molecular crystal