Analysis of auto-ignition of heated hydrogen-air mixtures with different detailed reaction mechanisms

Auto-ignition processes of hydrogen, diluted with nitrogen, in heated air are numerically investigated by means of an unsteady laminar flamelet approach in mixture fraction space. The focus is on the auto-ignition delay time and the most reactive mixture fraction as obtained with five chemical mechanisms. Two strongly different levels of dilution, corresponding to experiments in the open literature, are considered. This concerns low-temperature chemistry at atmospheric pressure. The temperature of the air stream is much higher than the temperature of the fuel stream in the cases under study. We extensively investigate the effect of the co-flow temperature, the conditional scalar dissipation rate and the resolution in mixture fraction space for one case. With respect to the conditional scalar dissipation rate, we discuss the Amplitude Mapping Closure (AMC) model with imposed maximum scalar dissipation rate at mixture fraction equal to 0.5, as well as a constant conditional scalar dissipation rate value over the entire mixture fraction value range. We also illustrate that an auto-ignition criterion, based on a temperature rise, leads to similar results as an auto-ignition criterion, based on OH mass fraction, provided that the hydrogen is not too strongly diluted

LES-CMC simulations of different auto-ignition regimes of hydrogen in a hot turbulent air Co-flow

Large-Eddy Simulation (LES) results in combination with first-order Conditional Moment Closure (CMC) are presented for a hydrogen jet, diluted with nitrogen, issued into a turbulent co-flowing hot air stream. The fuel mixes with the co-flow air, ignites and forms a lifted-like flame. Global trends in the experimental observations are in general well reproduced: the auto-ignition length decreases with increase in co-flow temperature and increases with increase in co-flow velocity. In the experiments, the co-flow temperature was varied, so that different auto-ignition regimes, including low Damkohler number situations, were obtained (no ignition, random spots, flashback and lifted flame). All regimes are recovered in the simulations. Auto-ignition is found to be the stabilizing mechanism. The impact of different detailed chemistry mechanisms on the auto-ignition predictions is discussed. With increasing air temperature, the differences between the mechanisms considered diminish. The evolution of temperature, H2O, H, HO2 and OH from inert to burning conditions is discussed in mixture fraction space

Simulation of hydrogen auto-ignition in a turbulent co-flow of heated air with LES and CMC approach

Large-Eddy Simulations (LES) with the first order Conditional Moment Closure (CMC) approach of a nitrogen-diluted hydrogen jet, igniting in a turbulent co-flowing hot air stream, are discussed. A detailed mechanism (nine species, 19 reactions) is used to represent the chemistry. Our study covers the following aspects: CFD mesh resolution; CMC mesh resolution; inlet boundary conditions and conditional scalar dissipation rate modelling. The Amplitude Mapping Closure for the conditional scalar dissipation rate produces acceptable results. We also compare different options to calculate conditional quantities in CMC resolution. The trends in the experimental observations are in general well reproduced. The auto-ignition length decreases with an increase in co-flow temperature and increases with increase in co-flow velocity. The phenomena are not purely chemically controlled: the turbulence and mixing play also affect the location of auto-ignition. In order to explore the effect of turbulence, two options were applied: random noise and turbulence generator based on digital filter. It was found that stronger turbulence promotes ignition

Numerical simulations of hydrogen auto-ignition in a turbulent co-flow of heated air

Our research objective is the performance of Large-Eddy Simulation (LES) with the first order Conditional Moment Closure (CMC) of the test case experimentally studied by Markides and Mastorakos [1]. The experiment concerns auto-ignition of hydrogen, diluted with nitrogen, in a co-flow of heated air. A 19 step, nine species detailed mechanism is used for the reaction. Simulations reveal that the injected hydrogen mixes with co-flowing air and a diffusion flame is established. The configuration is sensitive to inlet boundary conditions, as all major turbulence effects are expected to be dominated by the inflow conditions. Preliminary LES results are presented. Stand-alone chemistry calculations are also presented to illustrate sensitivity on chemistry mechanisms

New scintillation hodoscope for CLAS12 and partial wave analysis of the channel γ p → p K⁺ K⁻

This thesis consists of two parts that have contributed to a new meson spectroscopy program, MesonEx, which is currently taking place in Hall B of the upgraded Thomas Jefferson National Accelerator Facility (JLab) in the USA. The first, hardware part, presents design, testing, construction and calibration of a fast-timing scintillation Hodoscope for a new Forward Tagger detector, that has been installed inside the upgraded CEBAF Large Acceptance Spectrometer (CLAS12) which is situated in the Hall B of JLab. The Forward Tagger is a key apparatus for measurement of quasi-real photoproduction of mesons in the MesonEx, and a necessary device for other new hadron spectroscopy programs. The second, software and analysis part, presents contributions to the general HAdron SPEctroscopy CenTre (HASPECT) analysis framework, that has been developed in preparation for the MesonEx data analysis. The software contribution consists of finalizing HASPECT simulation and analysis chains in a model-independent way, and developing a mass-independent partial wave analysis procedure. This procedure has been tested via analysis of the γ p → p K+ K- channel from the g11a CLAS data, in the photon energy range Eγ = 3:0 - 3:8 GeV and momentum transfer squared range -t = 0:6 - 0:7 (GeV/c2)2. The first result of this analysis is the differential cross section for the ϕ(1020) resonance photoproduction. This result has been compared with a previous analysis result, and a good agreement has validated the developed analysis procedure. Furthermore, S, P and D partial waves have been extracted from the data set, using the same procedure, and ambiguous solutions for these partial waves have been calculated, using the method of Barrelet zeros which is for the first time applied to photoproduction of the K+ and K- mesons on the proton. Distributions of the calculated solutions have been compared with the fit results. It is found that the physical solution contains contributions of the ϕ(1020) in the P-wave and the a2(1320) in the D-wave

Study of a turbulent nitrogen-diluted hydrogen-air diffusion flame through large-eddy simulations coupled with a first order conditional moment closure method

this work concerns numerical simulations of a hydrogen diffusion flame, using Large Eddy Simulations (LES) and Conditional Moment Closure (CMC) as turbulent combustion model. In order to explore the effect of turbulence, two types of inlet boundary conditions are applied: White Noise and a method of Random Spots. The analysis of Favre-averaged profiles of velocity, mixture fraction, temperature and species has led to the conclusion that the method of Random Spots is in much better agreement with the experimental data, as expected. However, several discrepancies between simulations and experiments can also be caused by the boundary conditions applied at the sides and the outlet of the domain