Discovery of a bright transient ultraluminous X-ray source Suzaku J1305-4931 in NGC 4945

This paper reports the discovery of a bright X-ray transient source, Suzaku J1305-4913, in the south-west arm of the nearby Seyfert II galaxy NGC 4945. It was detected at a 0.5 -- 10 keV flux of $2.2 \times 10^{-12}$ erg cm$^{-2}$ s$^{-1}$ during the Suzaku observation conducted on 2006 January 15 -- 17, but was undetectable in a shorter observation on 2005 August 22 --23, with an upper limit of $1.7 \times 10^{-14}$ erg cm$^{-2}$ s$^{-1}$ (90% confidence level). At a distance of 3.7 Mpc, the bolometric luminosity of the source becomes $L_{\rm bol} = 4.4 \times 10^{39} \alpha$ erg s$^{-1}$, where $\alpha = (\cos 60^\circ / \cos i)$ and $i$ is the disk inclination. Therefore, the source is classified into so-called ultraluminous X-ray sources (ULXs). The time-averaged X-ray spectrum of the source is described by a multi-color disk model, with the innermost accretion disk temperature of $T_{\rm in} = 1.69_{-0.05}^{+0.06}$ keV. During the 2006 January observation, it varied by a factor of 2 in intensity, following a clear correlation of $L_{\rm bol} \propto T_{\rm in}^4$. It is inferred that the innermost disk radius $R_{\rm in}$ stayed constant at $R_{\rm in} = 79_{-3.9}^{+4.0} \alpha^{1/2}$ km, suggesting the presence of a standard accretion disk. Relating $R_{\rm in}$ with the last stable orbit around a non-rotating black hole yields a rather low black hole mass, $\sim 9 \alpha^{1/2}$ solar masses, which would imply that the source is shining at a luminosity of $\sim3 \alpha^{1/2}$ times the Eddington limit. These results can be better interpreted by invoking sub-Eddington emission from a rapidly spinning black hole with a mass of 20 -- 130 solar masses.Comment: 21 pages, 10 figures, Accepted for PASJ 2nd Suzaku special issu

Discotic liquid crystals of transition metal complexes 48: Synthesis of novel phthalocyanine-fullerene dyads and effect of a methoxy group on their clearing points

In our previous work, we could successfully synthesize the 1:1 phthalocyanine-fullerene (Pc-C-60) dyads, (OFbaC(60))PcCu(OCH3) 2, in very high yields (81 similar to 96%) by using Prato reaction. In this study, we have prepared novel Pc-C-60 dyads, (OFbaC(60)) PcM (M = Co (a), Ni (b), Cu (c), metal free (d)) 3a-3d without the methoxy group. The target Pc-C-60 dyads 3a-3d could be successfully synthesized in good yields also by Prato reaction. It is surprising for us that removal of a very small methoxy group from the big (OFbaC(60))PcCu(OCH3) molecule (2) significantly lowers the cp of (OFbaC(60))PcCu (3c) by about 70 degrees C in comparison with that of 2 having the methoxy group. Very interestingly, each of the novel dyads 3a-3d synthesized here shows perfect homeotropic alignment in the tetragonal columnar phase (Col(tet)). Moreover, it is noteworthy that 3c and 3d show only one Col(tet.o) mesophase having ordered stacking distance with perfect homeotropic alignment. Such simple phase transition can contribute to maintain stable performance in wide temperature range, when they will be applied to organic thin film solar cells.ArticleJOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 17(4):264-282 (2013)journal articl

Discotic liquid crystals of transition metal complexes 50(dagger): spiranthes-like supramolecular structure of phthalocyanine-fullerene dyads

We have synthesized novel liquid crystalline Pc-C-60 dyads (CnS)(6)PcCu-C-60 (n = 14, 16, 18: 1a-1c) by using our developed synthetic method in order to investigate the mesomorphism and alignment behavior. Each of the (CnS)(6)PcCu-C-60 dyads shows perfect homeotropic alignment in the Col(ho) mesophase between two glass plates for n = 14, 16, 18 and also on a glass plate for n = 14, although none of the parent Pc compounds (CnS)(8)PcCu and the Pc precursors (CnS)(6)PcCu-OH and (CnS)(6)PcCu-OFBA shows homeotropic alignment. It may be attributed to the strong affinity between fullerene and glass surface. Although the reason is not so clear at the present time, this is very useful guideline for the molecular design to prepare homeotropic alignment-showing discotic liquid crystals. Very interestingly, the spherical C-60 parts form a helical structure around the column formed by the disk-like Pc parts. This supramolecular structure very resembles spiranthes. The spiranthes-like supramolecular structure is compatible with one-dimensional nano-array expecting the high conversion efficiency of solar cells.ArticleJOURNAL OF PORPHYRINS AND PHTHALOCYANINES. 18(5):366-379 (2014)journal articl

Cuticular Hydrocarbon Content that Affects Male Mate Preference of Drosophila melanogaster from West Africa

Intraspecific variation in mating signals and preferences can be a potential source of incipient speciation. Variable crossability between Drosophila melanogaster and D. simulans among different strains suggested the abundance of such variations. A particular focus on one combination of D. melanogaster strains, TW1(G23) and Mel6(G59), that showed different crossabilities to D. simulans, revealed that the mating between females from the former and males from the latter occurs at low frequency. The cuticular hydrocarbon transfer experiment indicated that cuticular hydrocarbons of TW1 females have an inhibitory effect on courtship by Mel6 males. A candidate component, a C25 diene, was inferred from the gas chromatography analyses. The intensity of male refusal of TW1 females was variable among different strains of D. melanogaster, which suggested the presence of variation in sensitivity to different chemicals on the cuticle. Such variation could be a potential factor for the establishment of premating isolation under some conditions

A new heterozygous compound mutation in the CTSA gene in galactosialidosis

Galactosialidosis is an autosomal recessive lysosomal storage disease caused by the combined deficiency of lysosomal β-galactosidase and neuraminidase due to a defect in the protective protein/cathepsin A. Patients present with various clinical manifestations and are classified into three types according to the age of onset: the early infantile type, the late infantile type, and the juvenile/adult type. We report a Japanese female case of juvenile/adult type galactosialidosis. Clinically, she presented with short stature, coarse facies, angiokeratoma, remarkable action myoclonus, and cerebellar ataxia. The patient was diagnosed with galactosialidosis with confirmation of impaired β-galactosidase and neuraminidase function in cultured skin fibroblasts. Sanger sequencing for CTSA identified a compound heterozygous mutation consisting of NM_00308.3(CTSA):c.746 + 3A>G and c.655-1G>A. Additional analysis of her mother’s DNA sequence indicated that the former mutation originated from her mother, and therefore the latter was estimated to be from the father or was a de novo mutation. Both mutations are considered pathogenic owing to possible splicing abnormalities. One of them (c.655-1G>A) is novel because it has never been reported previously

Formation of an Ultracarbonaceous Antarctic Micrometeorite through Minimum Aqueous Alteration in a Small Porous Icy Body

A comprehensive study of the organic chemistry and mineralogy of an ultracarbonaceous micrometeorite (UCAMM D05IB80) collected from near the Dome Fuji Station, Antarctica, was carried out to understand the genetic relationship among organic materials, silicates, and water. The micrometeorite is composed of a dense aggregate of ∼5 µm-sized hollow ellipsoidal organic material containing submicrometer-sized phases such as glass with embedded metal and sulfides (GEMS) and mineral grains. There is a wide area of organic material (∼15 × 15 μm) in its interior. Low-Ca pyroxene is much more abundant than olivine and shows various Mg/(Mg + Fe) ratios ranging from ∼1.0 to 0.78, which is common to previous works on UCAMMs. By contrast, GEMS grains in this UCAMM have unusual chemical compositions. They are depleted in both Mg and S, which suggests that these elements were leached out from the GEMS grains during very weak aqueous alteration, without the formation of phyllosilicates. The organic materials have two textures—smooth and globular with an irregular outline—and these are composed of imine, nitrile and/or aromatic nitrogen heterocycles, and amide. The ratio of nitrogen to carbon (N/C) in the smooth region of the organics is ∼0.15, which is five times higher than that of insoluble organic macromolecules in types 1 and 2 carbonaceous chondritic meteorites. In addition, the UCAMM organic materials are soluble in epoxy and are thus hydrophilic; this polar nature indicates that they are very primitive. The surface of the material is coated with an inorganic layer, a few nanometers thick, that consists of C, O, Si, S, and Fe. Sulfur is also contained in the interior, implying the presence of organosulfur moieties. There are no isotopic anomalies of D, 13C, or 15N in the organic material. Interstellar photochemistry alone would not be sufficient to explain the N/C ratio of the UCAMM organics; therefore, we suggest that a very small amount of fluid on a comet must have been necessary for the formation of the UCAMM. The GEMS grains depleted in Mg and S in the UCAMM prove a very weak degree of aqueous alteration; weaker than that of carbonaceous chondrites. Short-duration weak alteration probably caused by planetesimal shock locally melted cometary ice grains and released water that dissolved the organics; the fluid would likely have not mobilized because of the very low thermal conductivity of the porous icy body. This event allowed the formation of the large organic puddle of the UCAMM, as well as organic matter sulfurization, formation of thin membrane-like layers of minerals, and deformation of organic nanoglobules.アクセプト後にタイトル・アブストラクト等変更あり、著者最終稿は変更前のタイトル"Formation of an Ultracarbonaceous Antarctic Micrometeorite through Minimum Aqueous Alteration in a Small Porous Icy Body"This work was supported by a Grant-in-Aid for Scientific Research from the Japanese Ministry of Education, Culture, Sports, Science and Technology (No. 22224010, PI: H. Nagahara). The STXM facility at the beamline 5.3.2.2, ALS, is supported by the Department of Energy, Basic Energy Sciences Program

Organic chemical variation between hydrous and anhydrous Antarctic micrometeorites

第6回極域科学シンポジウム[OA] 南極隕石11月17日（火）　国立国語研究所 2階 講