Enhanced binding revisited for a spinless particle in non-relativistic QED

We consider a spinless particle coupled to a quantized Bose field and show that such a system has a ground state for two classes of short-range potentials which are alone too weak to have a zero-energy resonance

Setting and analysis of the multi-configuration time-dependent Hartree-Fock equations

In this paper we motivate, formulate and analyze the Multi-Configuration Time-Dependent Hartree-Fock (MCTDHF) equations for molecular systems under Coulomb interaction. They consist in approximating the N-particle Schrodinger wavefunction by a (time-dependent) linear combination of (time-dependent) Slater determinants. The equations of motion express as a system of ordinary differential equations for the expansion coefficients coupled to nonlinear Schrodinger-type equations for mono-electronic wavefunctions. The invertibility of the one-body density matrix (full-rank hypothesis) plays a crucial role in the analysis. Under the full-rank assumption a fiber bundle structure shows up and produces unitary equivalence between convenient representations of the equations. We discuss and establish existence and uniqueness of maximal solutions to the Cauchy problem in the energy space as long as the density matrix is not singular. A sufficient condition in terms of the energy of the initial data ensuring the global-in-time invertibility is provided (first result in this direction). Regularizing the density matrix breaks down energy conservation, however a global well-posedness for this system in L^2 is obtained with Strichartz estimates. Eventually solutions to this regularized system are shown to converge to the original one on the time interval when the density matrix is invertible.Comment: 48 pages, 1 figur

Properties of periodic Dirac-Fock functional and minimizers

Existence of minimizers for the Dirac-Fock model for crystals was recently proved by Paturel and Séré and the authors [9]. In this paper, inspired by Ghimenti and Lewin's result [12] for the periodic Hartree-Fock model, we prove that the Fermi level of any periodic Dirac-Fock minimizer is either empty or totally filled when α/c\leq C_{cri} and α > 0. Here c is the speed of light, α is the fine structure constant, and C cri is a constant only depending on the number of electrons and on the charge of nuclei per cell. More importantly, we provide an explicit upper bound for C_{cri} .Our result implies that any minimizer of the periodic Dirac-Fock model is a projector when α/c\leq C_{cri} and α > 0 In particular, the non-relativistic regime (i.e., c >>1) and the weak coupling regime (i.e., 0< α <<1) are covered.The proof is based on a delicate study of a second-order expansion of the periodic Dirac-Fock functional composed with a retraction that was introduced by Séré in [23] for atoms and molecules and later extended to the case of crystals in

Properties of periodic Dirac--Fock functional and minimizers

Existence of minimizers for the Dirac--Fock model in crystals was recently proved by Paturel and S\'er\'e and the authors \cite{crystals} by a retraction technique due to S\'er\'e \cite{Ser09}. In this paper, inspired by Ghimenti and Lewin's result \cite{ghimenti2009properties} for the periodic Hartree--Fock model, we prove that the Fermi level of any periodic Dirac--Fock minimizer is either empty or totally filled when $\frac{\alpha}{c}\leq C_{\rm cri}$ and $\alpha>0$. Here $c$ is the speed of light, $\alpha$ is the fine structure constant, and $C_{\rm cri}$ is a constant only depending on the number of electrons and on the charge of nuclei per cell. More importantly, we provide an explicit upper bound for $C_{\rm cri}$. Our result implies that any minimizer of the periodic Dirac--Fock model is a projector when $\frac{\alpha}{c}\leq C_{\rm cri}$ and $\alpha>0$. In particular, the non-relativistic regime (i.e., $c\gg1$) and the weak coupling regime (i.e., $0<\alpha\ll1$) are covered. The proof is based on a delicate study of a second-order expansion of the periodic Dirac--Fock functional composed with the retraction used in \cite{crystals}

Self-energy of one electron in non-relativistic QED

AbstractWe investigate the self-energy of one electron coupled to a quantized radiation field by extending the ideas developed in Hainzl (Ann. H. Poincaré, in press). We fix an arbitrary cut-off parameter Λ and recover the α2-term of the self-energy, where α is the coupling parameter representing the fine structure constant. Thereby we develop a method which allows to expand the self-energy up to any power of α. This implies that perturbation theory in α is correct if Λ is fix. As an immediate consequence we obtain enhanced binding for electrons