123 research outputs found
The suppression of superconductivity in MgCNi3 by Ni-site doping
The effects of partial substitution of Cu and Co for Ni in the intermetallic
perovskite superconductor MgCNi3 are reported. Calculation of the expected
electronic density of states suggests that electron (Cu) and hole (Co) doping
should have different effects. For MgCNi3-xCux, solubility of Cu is limited to
approximately 3% (x = 0.1), and Tc decreases systematically from 7K to 6K. For
MgCNi3-xCox, solubility of Co is much more extensive, but bulk
superconductivity disappears for Co doping of 1% (x = 0.03). No signature of
long range magnetic ordering is observed in the magnetic susceptibility of the
Co doped material.Comment: submitted, Solid State Communication
Contaminations contaminate common databases
The polymerase chain reaction (PCR) is a very powerful method to detect and identify pathogens. The high sensitivity of the method, however, comes with a cost; any of the millions of artificial DNA copies generated by PCR can serve as a template in a following experiment. If not identified as contaminations, these may result in erroneous conclusions on the occurrence of the pathogen, thereby inflating estimates of host range and geographic distribution. In the present paper, we evaluate whether several published records of avian haemosporidian parasites, in either unusual host species or geographical regions, might stem from PCR contaminations rather than novel biological findings. The detailed descriptions of these cases are shedding light upon the steps in the work process that might lead to PCR contaminations. By increasing the awareness of this problem, it will aid in developing procedures that keep these to a minimum. The examples in the present paper are from haemosporidians of birds, however the problem of contaminations and suggested actions should apply generally to all kinds of PCR‐based identifications, not just of parasites and pathogens
Strongly linked current flow in polycrystalline forms of the new superconductor MgB2
The discovery of superconductivity at 39 K in MgB2[1] raises many issues. One
of the central questions is whether this new superconductor resembles a
high-temperature-cuprate superconductor or a low-temperature metallic
superconductor in terms of its current carrying characteristics in applied
magnetic fields. In spite of the very high transition temperatures of the
cuprate superconductors, their performance in magnetic fields has several
drawbacks[2]. Their large anisotropy restricts high bulk current densities to
much less than the full magnetic field-temperature (H-T) space over which
superconductivity is found. Further, weak coupling across grain boundaries
makes transport current densities in untextured polycrystalline forms low and
strongly magnetic field sensitive[3,4]. These studies of MgB2 address both
issues. In spite of the multi-phase, untextured, nano-scale sub-divided nature
of our samples, supercurrents flow throughout without the strong sensitivity to
weak magnetic fields characteristic of Josephson-coupled grains[3].
Magnetization measurements over nearly all of the superconducting H-T plane
show good temperature scaling of the flux pinning force, suggestive of a
current density determined by flux pinning. At least two length scales are
suggested by the magnetization and magneto optical (MO) analysis but the cause
of this seems to be phase inhomogeneity, porosity, and minority insulating
phase such as MgO rather than by weakly coupled grain boundaries. Our results
suggest that polycrystalline ceramics of this new class of superconductor will
not be compromised by the weak link problems of the high temperature
superconductors, a conclusion with enormous significance for applications if
higher temperature analogs of this compound can be discovered
Superconductivity in the non-oxide Perovskite MgCNi3
The oxide perovskites are a large family of materials with many important
physical properties. Of particular interest has been the fact that this
structure type provides an excellent structural framework for the existence of
superconductivity. The high Tc copper oxides are the most famous examples of
superconducting perovskites, but there are many others [1]. Intermetallic
compounds have been the source of many superconducting materials in the past,
but they have been eclipsed in recent years by the perovskite oxides. The
recent discovery of superconductivity in MgB2 [2] suggests that intermetallic
compounds with simple structure types are worth serious reconsideration as
sources of new superconducting materials. Here we report the observation of
superconductivity at 8 K in the perovskite structure intermetallic compound
MgCNi3, linking what appear at first sight to be mutually exclusive classes of
superconducting materials. The observation of superconductivity in MgCNi3
indicates that MgB2 will not be the only one of its kind within the chemical
paradigm that it suggests for new superconducting materials
Thin Film Magnesium Boride Superconductor with Very High Critical Current Density and Enhanced Irreversibility Field
The discovery of superconductivity at 39 K in magnesium diboride offers the
possibility of a new class of low-cost, high-performance superconducting
materials for magnets and electronic applications. With twice the critical
temperature of Nb_3Sn and four times that of Nb-Ti alloy, MgB_2 has the
potential to reach much higher fields and current densities than either of
these technological superconductors. A vital prerequisite, strongly linked
current flow, has already been demonstrated even at this early stage. One
possible drawback is the observation that the field at which superconductivity
is destroyed is modest. Further, the field which limits the range of practical
applications, the irreversibility field H*(T), is ~7 T at liquid helium
temperature (4.2 K), significantly lower than ~10 T for Nb-Ti and ~20 T for
Nb_3Sn. Here we show that MgB_2 thin films can exhibit a much steeper
temperature dependence of H*(T) than is observed in bulk materials, yielding
H*(4.2 K) above 14 T. In addition, very high critical current densities at 4.2
K, 1 MA/cm_2 at 1 T and 10_5 A/cm_2 at 10 T, are possible. These data
demonstrate that MgB_2 has credible potential for high-field superconducting
applications.Comment: 4 pages pdf, submitted to Nature 3/20/0
Reproductive risk factors associated with breast cancer in women in Bangui: a case–control study
Risk factors of breast cancer and knowledge about the disease: an integrative revision of Latin American studies
Catalysis Research of Relevance to Carbon Management: Progress, Challenges, and Opportunities
X-ray Structure Of (n-heterocyclic)(η4-diene)-dicarbonyliron(0) Compounds
(N-Heterocyclic)(η4-diene)dicarbonyliron(0) compounds, where the N-heterocycles are quinoline and pyrazine and the diene is the diethyl ester of the hexa-2,4-dien-1,6-dioic acid (diethyl muconate) were studied by X-ray diffraction. The measurements demonstrated that the N-heterocycle occupies different positions of a tetragonal pyramid in these compounds. Quinoline occupies a basal position and pyrazine an apical position. This is discussed in terms of the π-bonding ability of the ligands. © 1987.32019199Buchkremer, (1973) Ph.D. Thesis, , Ruhr Universität, BochumKrüger, Trag, Molekül- und Kristallstruktur von Bis(1,3-cyclohexadien)monocarbonyleisen (1971) Angewandte Chemie, 83, p. 250De Paoli, Fruehauf, Grevels, Koerner von Gustorf, Krüger, (1977) J. Organomet. Chem., 136, p. 219Fruehauf, Grevels, Landers, Carbonyl(1,4-diaza-1,3-dien)(1,3-dien)eisen-komplexe: photochemische darstellung über tricarbonyl(1,4-diaza-1,3-dien)eisen (1979) Journal of Organometallic Chemistry, 179, p. 349De Paoli, Makita, (1981) J. Organomet. Chem., 216, p. 79Vichi, Raithby, McPartlyn, (1983) J. Organomet. Chem., 256, p. 111Sheldrick, (1976) SHELX 76, A Program for Crystal Structure Determination, , University of CambridgeKrüger, Barnett, (1978) The Organic Chemistry of Iron, 1. , E.A.Koerner von Gustorf, F.W. Grevels, I. Fischler, Academic Press, LondonBellachioma, Cardaci, Mechanism of the reaction of chelated tricarbonyliron complexes of ?,?-unsaturated Schiff bases with Group 5 ligands (1977) Journal of the Chemical Society, Dalton Transactions, p. 2181Marks, Grevels, Fischler, (1978) The Organic Chemistry of Iron, 1. , E.A.Koerner von Gustorf, Academic Press, LondonBehrens, Thiele, Pürzer, Würstl, Moll, (1978) J. Organomet. Chem., 160, p. 255Moll, Seibold, Popp, (1980) J. Organomet. Chem., 191, p. 19
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