1 research outputs found
Sulfonated Poly(arylene sulfide sulfone nitrile) Multiblock Copolymers with Ordered Morphology for Proton Exchange Membranes
Ordered
morphologies in disulfonated polyÂ(arylene sulfide sulfone
nitrile) (SPSN) copolymers were generated via thermal annealing followed
by multiblock copolymer synthesis. While SPSN random copolymers (R-SPSN)
showed featureless morphologies, the SPSN multiblock copolymers (B-SPSN)
exhibited cocontinuous lamellar morphologies with a center-to-center
interdomain size of up to 40 nm. In spite of the well-ordered, interconnected
hydrophilic domains, the water self-diffusion coefficient (e.g., <i>D</i> = (0.7–2.0) × 10<sup>–10</sup> m<sup>2</sup> s<sup>–1</sup>) and proton conductivity (e.g., σ
= 0.16–0.20 S cm<sup>–1</sup> in deionized water at
30 °C) through B-SPSN were lower than those of the corresponding
R-SPSN (e.g., <i>D</i> = (3.5–3.9) × 10<sup>–10</sup> m<sup>2</sup> s<sup>–1</sup> and σ
= 0.21 S cm<sup>–1</sup>) due to the relatively lower water
uptake of the B-SPSN after thermal annealing. The reduced water uptake
of B-SPSN was beneficial to reduction of peroxide degradation rate.
Thermal annealing produced significant gains in morphological ordering
and finer control over desired membrane properties for proton conduction
applications