1 research outputs found
Regioselectivity of Selenium-Mediated Carbonylation of Organolithium Compounds with Carbon Monoxide
- Author
- Abel E. W.
- Akira Nishiyama
- Bank S.
- Bank S.
- Carbonylation of lithio derivatives of hydrocarbons see: (a)
- For carbonylation of lithium enolates of ketones and aldehydes see (a)
- For carbophilic addition of organocopper reagents to SeCO:
- For reviews of carbonylation see: (a)
- Hajime Maeda
- Imidoylation of lithio derivatives of hydrocarbons:
- Kazuhiro Okada
- Kim S.
- Kollár L.
- Liotta and co-workers reported that α-alkylselenoketones were obtained by the reaction of lithium enolates of ketones with selenium in the presence of additives such as HMPA followed by trapping with alkyl halides
- Maeda H.
- N-Carbonylation of lithium azaenolates of amides formamides, ureas, and carbamates:
- Noboru Sonoda
- Nobuaki Kambe
- Ruwet A.
- Shin-ichi Fujiwara
- Theoretical study on generation of carbonyl selenide (SeCO):
- Theoretical study on structure bonding, and aggregation of organolithium compounds shown in Scheme 1:
- There are only a few other reports for 1 3-dioxoalkanes involving a selenol ester unit(s). (a)
- Tsutomu Shin-ike
- We already examined the reaction of isoselenocyanate having isoelectronic structure with SeCO, with organolithium compounds focusing on the siteselectivities. Phenyllithium attacked selenium exclusively, whereas lithium enolate of a ketone reacted with SeCO at both its C- and O-nucleophilic centers attacking the central carbon of SeCO
- Publication venue
- 'Informa UK Limited'
- Publication date
- Field of study
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