Regioselectivity of Selenium-Mediated Carbonylation of Organolithium Compounds with Carbon Monoxide
- Authors
- Abel E. W.
- Akira Nishiyama
- Bank S.
- Bank S.
- see: (a) Carbonylation of lithio derivatives of hydrocarbons
- see (a) For carbonylation of lithium enolates of ketones and aldehydes
- For carbophilic addition of organocopper reagents to SeCO:
- see: (a) For reviews of carbonylation
- Hajime Maeda
- Imidoylation of lithio derivatives of hydrocarbons:
- Kazuhiro Okada
- Kim S.
- Kollár L.
- Liotta and co-workers reported that α-alkylselenoketones were obtained by the reaction of lithium enolates of ketones with selenium in the presence of additives such as HMPA followed by trapping with alkyl halides
- Maeda H.
- formamides, ureas, and carbamates: N-Carbonylation of lithium azaenolates of amides
- Noboru Sonoda
- Nobuaki Kambe
- Ruwet A.
- Shin-ichi Fujiwara
- Theoretical study on generation of carbonyl selenide (SeCO):
- bonding, and aggregation of organolithium compounds shown in Scheme 1: Theoretical study on structure
- There are only a few other reports for 1,3-dioxoalkanes involving a selenol ester unit(s). (a)
- Tsutomu Shin-ike
- having isoelectronic structure with SeCO, with organolithium compounds focusing on the siteselectivities. Phenyllithium attacked selenium exclusively, whereas lithium enolate of a ketone reacted with SeCO at both its C- and O-nucleophilic centers attacking the central carbon of SeCO We already examined the reaction of isoselenocyanate
- Publication date
- Publisher
- 'Informa UK Limited'
- Doi
Abstract
Abstract is not available.Similar works
Available Versions
Last time updated on 03/09/2020