The role of some metal ions in enhancement of photocatalytic activity of Fe2O3-V2O5 binary oxide

Fe2O3-V2O5 mixed oxides were synthesized with solid-state dispersion (SSD) and coprecipitation methods. In addition, transition metal oxides such as CuO, NiO, and Co3O4 were successfully loaded on the synthesized catalyst (Fe2O3-V2O5) using the SSD method. The composite catalysts were inspected for their photocatalytic activities in degrading 2,4-dichlorophenol under UV light enforcement. The produced samples were analyzed using X-ray diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, diffuse reflectance spectroscopy, scanning electron microscopy, photoluminescence, and the Brunauer-Emmett-Teller method. The addition of transition metal oxides improved the photocatalytic activity of Fe2O3-V2O5 (SSD). 1CuO wt% Fe2O3-V2O5 exhibited the highest percentage of 2,4-dichlorophenol degradation (100%) and the highest reaction rate (1.83 mg/L min) in 30 min. This finding is attributed to the distribution of CuO

V2O5-TiO2 heterostructural semiconductors: Synthesis and photocatalytic elimination of organic contaminant

V2O5-TiO2 binary oxide catalysts were successfully prepared with different wt% V2O5 loading by solid state mechanical mixing (SSDMMix), and these nanocomposites were modified with hexadecyltrimethylammonium bromide (HTAB) and cetyl trimethylammonium bromide (CTAB) and polyvinyl alcohol (PVA) as surfactant. The resulting catalysts were characterized by X-ray diffraction (XRD), diffuse reflectance spectroscopy (DRS), scanning electron microscopy (SEM), Braun-Emmet-Teller (BET) analysis of surface area techniques. The photocatalytic activities of all samples were evaluated by degradation of 4-chlorophenol (4CP) in aqueous solution under UV irradiation. 50 wt% V2O5-TiO2 photocatalyst exhibited much higher photocatalytic activity than pure V2O5, TiO2 and P-25. The interaction between V2O5 and TiO2 affected the photocatalytic efficiency of binary oxide catalysts. In addition, CTAB and HTABassisted samples significantly enhanced the efficiency of 50V(2)O(5)-TiO2 binary oxide catalyst. The highest percentage of 4-chlorophenol degradation (100%) and highest reaction rate (1.69mg L-1 min(-1)) were obtained in 30 minutes with (50V(2)O(5)-TiO2)-CTAB catalyst. It is concluded that the addition of surfactant to binary oxide remarkably enhanced the photocatalytic activity by modifying the optical and electronic properties of V2O5 and TiO2