Photoreductive Dissolution of Iron Oxides Trapped in Ice and Its Environmental Implications

The availability of iron has been thought to be a main limiting factor for the productivity of phytoplankton and related with the uptake of atmospheric CO_2 and algal blooms in fresh and sea waters. In this work, the formation of bioavailable iron (Fe(II)_(aq)) from the dissolution of iron oxide particles was investigated in the ice phase under both UV and visible light irradiation. The photoreductive dissolution of iron oxides proceeded slowly in aqueous solution (pH 3.5) but was significantly accelerated in polycrystalline ice, subsequently releasing more bioavailable ferrous iron upon thawing. The enhanced photogeneration of Fe(II)_(aq) in ice was confirmed regardless of the type of iron oxides [hematite, maghemite (γ-Fe_2O_3), goethite (α-FeOOH)] and the kind of electron donors. The ice-enhanced dissolution of iron oxides was also observed under visible light irradiation, although the dissolution rate was much slower compared with the case of UV radiation. The iron oxide particles and organic electron donors (if any) in ice are concentrated and aggregated in the liquid-like grain boundary region (freeze concentration effect) where protons are also highly concentrated (lower pH). The enhanced photodissolution of iron oxides should occur in this confined boundary region. We hypothesized that electron hopping through the interconnected grain boundaries of iron oxide particles facilitates the separation of photoinduced charge pairs. The outdoor experiments carried out under ambient solar radiation of Ny-Ålesund (Svalbard, 78°55′N) also showed that the generation of dissolved Fe(II)_(aq) via photoreductive dissolution is enhanced when iron oxides are trapped in ice. Our results imply that the ice(snow)-covered surfaces and ice-cloud particles containing iron-rich mineral dusts in the polar and cold environments provide a source of bioavailable iron when they thaw

Serum Vitamin E is Associated with Osteoarthritis among Korean Older Adults

Objectives: We aimed to examine the cross-sectional association between serum vitamin E level and osteoarthritis in Korean older adults. Methods: Data from the Korea National Health and Nutrition Examination Survey 2016 – 2018 were used. Overall, 978 participants aged ≥ 65 years were included in the study. Demographic, lifestyle, and health data were obtained through interviews or self-reported questionnaires. Patients with osteoarthritis were defined if they had responded “yes” to any of these three questions related to diagnosis, current condition, and treatment. Multivariate logistic regression analysis was performed to assess the association between serum vitamin E level and osteoarthritis. Results: After multivariate adjustment, a higher level of vitamin E was found to be associated with a higher prevalence of osteoarthritis (Odds ratio: 2.27, 95 % Confidence Interval: 1.19 – 4.34, p for trend = 0.037). Conclusion: A higher level of serum vitamin E was associated with increased osteoarthritis prevalence in older Koreans. Further prospective or clinical studies are needed to verify the causality

Forage Rye Cultivars for Animal Feed in Korea

Rye (Secale cereal L.) is well known for its overwintering ability and has the highest tolerance to cold temperature of the small grain cereals such as wheat, barley, and oat. Rye is used as livestock pasture and as green manure in Korea, and its cultivation area for fodder is about 50,000 ha in 2014. Most rye is grown as a fall-sown annual crop, generally called “winter rye”. In Korea, rye cultivation for whole crop silage (WCS) in the winter-season rice field can be considered as a promising way to enhance feed supply. The WCS production can be an efficient way to use farm products as livestock feed, and it can also contribute to increasing farm income. Although rye is inferior in several ways to the predominant cereal crops (wheat, rice, and maize), it will continue to be an important crop for farmers in Korea because of its winter hardiness and early harvesting by rapid growing ability

The Association between Disturbed Eating Behavior and Socioeconomic Status: The Online Korean Adolescent Panel Survey (OnKAPS)

Background: A limited amount of research, primarily conducted in Western countries, has suggested that higher socioeconomic status (SES) is associated with higher risk of eating disorders (EDs). However, little is known about this association in Asian countries. We examined the association of SES with disturbed eating behavior (DEB) and related factors in Korean adolescents. Subjects A nationwide online panel survey was conducted in a sample of adolescents (n = 6,943, 49.9% girls). DEB was measured with the 26-item Eating Attitudes Test (EAT-26). Participants who scored ≥20 on the EAT-26 were considered to have DEB. Participants’ SES was determined based on self-reported household economic status. Results: The prevalence of DEB was 12.7%: 10.5% among boys and 14.8% among girls. Both boys and girls with DEB were more likely to perceive themselves as obese, experience higher levels of stress, and have lower academic achievement. The risk for DEB was significantly higher in boys of higher SES than in those of middle SES (OR = 1.45, 95%CI = 1.05–1.99 for high SES; OR = 5.16, 95%CI: 3.50–7.61 for highest SES). Among girls, higher risk of DEB was associated with the highest and lowest SES (OR = 1.52, 95%CI: 1.13–2.06 for lowest SES; OR = 2.22, 95%CI: 1.34–3.68 for highest SES). Conclusions: Despite the lower prevalence of obesity in Korea compared with Western countries, the prevalence of DEB in Korean adolescents was high, especially among girls. Moreover, the association between SES and DEB followed a U-shaped curve for girls and a J-shaped curve for boys

Fatigue Prediction of the Discharge Pipe in Reciprocating Compressor

In this paper, a fatigue prediction of the line discharge tube for reciprocating compressor being installed in a refrigerator was studied. The tube usually gets plenty of the repeated loads caused by the start and stop motion of a reciprocating compressor. There are two representative methods to predict the fatigue stress. At first the stress-life can be applied to the problem which takes a lot of repeated stress within the elastic strain range. Second is the strain-life method which can be used when it comes to the problem of a small repeated stress in the plastic strain range. This paper presents the stress-life method how the design parameters of a discharge pipe relate to the fatigue prediction and analyzes the co-relation between them

Faunal Composition of Macro-moth in Rural Haitats, Compared to Semi-natural and Natural Habitats in the Southern Part of Korean Peninsula

Mokpo National University, KoreaPromoting Environmental Pesearch in Pan-Japan Sea Area : Young Researchers\u27 Network, Schedule: March 8-10,2006,Kanazawa Excel Hotel Tokyu, Japan, Organized by: Kanazawa University 21st-Century COE Program, Environmental Monitoring and Prediction of Long- & Short- Term Dynamics of Pan-Japan Sea Area ; IICRC(Ishikawa International Cooperation Research Centre), Sponsors : Japan Sea Research ; UNU-IAS(United Nations University Institute of Advanced Studies)+Ishikawa Prefecture Government ; City of Kanazaw