Optimization of Removal Efficiency and Minimum Contact Time for Cadmium and Zinc Removal onto Iron-modified Zeolite in a Two-stage Batch Sorption Reactor

In highly congested industrial sites where significant volumes of effluents have to be treated in the minimum contact time, the application of a multi-stage batch reactor is suggested. To achieve better balance between capacity utilization and cost efficiency in design optimization, a two-stage batch reactor is usually the optimal solution. Thus, in this paper, a two-stage batch sorption design approach was applied to the experimental data of cadmium and zinc uptake onto iron-modified zeolite. The optimization approach involves the application of the Vermeulen’s approximation model and mass balance equation to kinetic data. A design analysis method was developed to optimize the removal efficiency and minimum total contact time by combining the time required in the two-stages, in order to achieve the maximum percentage of cadmium and zinc removal using a fixed mass of zeolite. The benefits and limitations of the two-stage design approach have been investigated and discussed. This work is licensed under a Creative Commons Attribution 4.0 International License

Design of Fixed Bed Column for Lead Removal on Natural Zeolite Based on Batch Studies

This paper presents the prediction of breakthrough curves for the fixed bed column based on batch studies. Batch equilibrium studies of lead removal on natural zeolite clinoptilolite have been performed. The obtained experimental data have been tested according to the Langmuir and the Freundlich isotherm, and their parameters have been calculated. These parameters and the Mass Transfer Model have been used to predict theoretical breakthrough curves. Theoretical breakthrough curves have been compared with the experimental ones and good agreement has been observed. This indicates that the Mass Transfer Model is applicable for prediction of breakthrough curves from batch studies. The overall mass transfer coefficient has been calculated from column experiments. This value allows for calculation of the height of the mass transfer zone as a very important parameter necessary for column design