Encapsulation of metallic iron magnetic nanoparticles by polyacrylamide in water suspensions

Received: 28.06.2017; accepted: 24.07.2017; published: 20.10.2017.Theoretical consideration of the factors of the stability of metallic iron magnetic nanoparticles (MNPs) in water suspensions was done using extended DLVO (Derjaguin-Landau-Verwey-Overbeek) approach based on the balance among Van der Waals, electrostatic, magnetic and steric interactions. Magnetic and steric interactions dominate over other in suspensions of Fe MNPs. To test the theory Fe MNPs with average diameter 84 nm were synthesized by electrical explosion of wire and encapsulated by polyacrylamide in water suspension to provide steric repulsion. It was shown that encapsulation resulted in the efficient diminishing of the aggregation of metallic iron MNPs in water

Rejecting noise in Baikal-GVD data with neural networks

Baikal-GVD is a large ($\sim$ 1 km$^3$) underwater neutrino telescope installed in the fresh waters of Lake Baikal. The deep lake water environment is pervaded by background light, which produces detectable signals in the Baikal-GVD photosensors. We introduce a neural network for an efficient separation of these noise hits from the signal ones, stemming from the propagation of relativistic particles through the detector. The neural network has a U-net like architecture and employs temporal (causal) structure of events. On Monte-Carlo simulated data, it reaches 99% signal purity (precision) and 98% survival efficiency (recall). The benefits of using neural network for data analysis are discussed, and other possible architectures of neural networks, including graph based, are examined

Iron oxide nanoparticles fabricated by electric explosion of wire: Focus on magnetic nanofluids

Nanoparticles of iron oxides (MNPs) were prepared using the electric explosion of wire technique (EEW). The main focus was on the fabrication of de-aggregated spherical nanoparticles with a narrow size distribution. According to XRD the major crystalline phase was magnetite with an average diameter of MNPs, depending on the fraction. Further separation of air-dry EEW nanoparticles was performed in aqueous suspensions. In order to provide the stability of magnetite suspension in water, we found the optimum concentration of the electrostatic stabilizer (sodium citrate and optimum pH level) based on zeta-potential measurements. The stable suspensions still contained a substantial fraction of aggregates which were disintegrated by the excessive ultrasound treatment. The separation of the large particles out of the suspension was performed by centrifuging. The structural features, magnetic properties and microwave absorption of MNPs and their aqueous solutions confirm that we were able to obtain an ensemble in which the magnetic contributions come from the spherical MNPs. The particle size distribution in fractionated samples was narrow and they showed a similar behaviour to that expected of the superparamagnetic ensemble. Maximum obtained concentration was as high as 5 % of magnetic material (by weight). Designed assembly of de-aggregated nanoparticles is an example of on-purpose developed magnetic nanofluid. Copyright © 2012 Author(s)