48 research outputs found
Nuclear recoil effect on the magnetic-dipole decay rates of atomic levels
The effect of finite nuclear mass on the magnetic-dipole transition
probabilities between fine-structure levels of the same term is investigated.
Based on a rigorous QED approach a nonrelativistic formula for the recoil
correction to first order in m_e/M is derived. Numerical results for
transitions of experimental interest are presented.Comment: 9 page
Relativistic calculations of isotope shifts in highly charged ions
The isotope shifts of forbidden transitions in Be- and B-like argon ions are
calculated. It is shown that only using the relativistic recoil operator can
provide a proper evaluation of the mass isotope shift, which strongly dominates
over the field isotope shift for the ions under consideration. Comparing the
isotope shifts calculated with the current experimental uncertainties indicates
very good perspectives for a first test of the relativistic theory of the
recoil effect in middle-Z ions
Radiation Chemistry of Overirradiated Aqueous Solutions of Hydrogen Cyanide and Ammonium Cyanide
The radiolysis of aqueous solutions (O2-free) of HCN and NH4CN was examined at very large doses of 60Co gamma radiation (up to 230 Mrad). In this dose range the cyanide initially present (0.12 M) is decomposed and only its radiolytic products participate in the radiation-induced chemical process. It has been found that the weight of the dry residue containing the mixture of nonvolatile radiolytic products increases as doses increase up to 40 Mrad (up to about 4 g/l), but with further dose increases remains practically unchanged (NH4CN) or decreases slightly (HCN). Carboxylic and amino acids are present in overirradiated samples. At increasing doses their concentrations decrease, with the exception of oxalic and malonic acids, which are continually produced and accumulate. This is also the case with the abundant NH3 and CO2, as well as with several other products that were generated at lower radiation-chemical yields. The molecular weights of the radiolytic products are up to 20,000 daltons throughout the dose range studied. Their amounts gradually change with increasing doses above 30 Mrad: The compounds with Mw between 2,000 and 6,000 daltons become more abundant, while the amounts of polymers with Mw between 6,000 and 20,000 decrease. The relevance of these findings for studies of chemical evolution is considered