117 research outputs found
A generalized Ramsey excitation scheme with suppressed light shift
We experimentally investigate a recently proposed optical excitation scheme
[V.I. Yudin et al., Phys. Rev. A 82, 011804(R)(2010)] that is a generalization
of Ramsey's method of separated oscillatory fields and consists of a sequence
of three excitation pulses. The pulse sequence is tailored to produce a
resonance signal which is immune to the light shift and other shifts of the
transition frequency that are correlated with the interaction with the probe
field. We investigate the scheme using a single trapped 171Yb+ ion and excite
the highly forbidden 2S1/2-2F7/2 electric-octupole transition under conditions
where the light shift is much larger than the excitation linewidth, which is in
the Hertz range. The experiments demonstrate a suppression of the light shift
by four orders of magnitude and an immunity against its fluctuations.Comment: 5 pages, 4 figure
Atomic clocks with suppressed blackbody radiation shift
We develop a nonstandard concept of atomic clocks where the blackbody
radiation shift (BBRS) and its temperature fluctuations can be dramatically
suppressed (by one to three orders of magnitude) independent of the
environmental temperature. The suppression is based on the fact that in a
system with two accessible clock transitions (with frequencies v1 and v2) which
are exposed to the same thermal environment, there exists a "synthetic"
frequency v_{syn} (v1-e12 v2) largely immune to the BBRS. As an example, it is
shown that in the case of ion 171Yb+ it is possible to create a clock in which
the BBRS can be suppressed to the fractional level of 10^{-18} in a broad
interval near room temperature (300\pm 15 K). We also propose a realization of
our method with the use of an optical frequency comb generator stabilized to
both frequencies v1 and v2. Here the frequency v_{syn} is generated as one of
the components of the comb spectrum and can be used as an atomic standard.Comment: 5 pages, 2 figure
Multiple coupling of silanes with imido complexes of Mo
The bis(imido) complexes (tBuNv)2Mo(PMe3)(L) (L = PMe3, C2H4) react with up to three equivalents of
silane PhSiH3 to give the imido-bridged disilyl silyl Mo(VI) complex (tBuN){μ-tBuN(SiHPh)2}Mo(H)(SiH2Ph)-
(PMe3)2 (3) studied by NMR, IR and X-ray diffraction. NMR data supported by DFT calculations show that
complex 3 is an unusual example of a silyl hydride of Mo(VI), without significant Si⋯H interaction. Mechanistic
NMR studies revealed that silane addition proceeds in a stepwise manner via a series of Si–H⋯M
agostic and silanimine complexes whose structures were further elucidated by DFT calculation
Multiple coupling of silanes with imido complexes of Mo
The bis(imido) complexes (tBuNv)2Mo(PMe3)(L) (L = PMe3, C2H4) react with up to three equivalents of
silane PhSiH3 to give the imido-bridged disilyl silyl Mo(VI) complex (tBuN){μ-tBuN(SiHPh)2}Mo(H)(SiH2Ph)-
(PMe3)2 (3) studied by NMR, IR and X-ray diffraction. NMR data supported by DFT calculations show that
complex 3 is an unusual example of a silyl hydride of Mo(VI), without significant Si⋯H interaction. Mechanistic
NMR studies revealed that silane addition proceeds in a stepwise manner via a series of Si–H⋯M
agostic and silanimine complexes whose structures were further elucidated by DFT calculation
Measurement of the Pion Form Factor in the Energy Range 1.04-1.38 GeV with the CMD-2 Detector
The cross section for the process is measured in the
c.m. energy range 1.04-1.38 GeV from 995 000 selected collinear events
including 860000 events, 82000 events, and 33000
events. The systematic and statistical errors of measuring the
pion form factor are equal to 1.2-4.2 and 5-13%, respectively.Comment: 5 pages, 2 figure
Measurement of the cross section with the CMD-3 detector at the VEPP-2000 collider
The process has been studied in the
center-of-mass energy range from 1500 to 2000\,MeV using a data sample of 23
pb collected with the CMD-3 detector at the VEPP-2000 collider.
Using about 24000 selected events, the cross
section has been measured with a systematic uncertainty decreasing from 11.7\%
at 1500-1600\,MeV to 6.1\% above 1800\,MeV. A preliminary study of
production dynamics has been performed
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