976 research outputs found
Frustration and Melting of Colloidal Molecular Crystals
Using numerical simulations we show that a variety of novel colloidal
crystalline states and multi-step melting phenomena occur on square and
triangular two-dimensional periodic substrates. At half-integer fillings
different kinds of frustration effects can be realized. A two-step melting
transition can occur in which individual colloidal molecules initially rotate,
destroying the overall orientational order, followed by the onset of interwell
colloidal hopping, in good agreement with recent experiments.Comment: 6 pages, 3 postscript figures. Procedings of International Conference
on Strongly Coupled Coulomb Systems, Santa Fe, 200
Fast scanning calorimetry of lysozyme unfolding at scanning rates from 5 K/min to 500,000 K/min
© 2018 Elsevier B.V. Background: Protein denaturation is often studied using differential scanning calorimetry (DSC). However, conventional instruments are limited in the temperature scanning rate available. Fast scanning calorimetry (FSC) provides an ability to study processes at much higher rates while using extremely small sample masses [ng]. This makes it a very interesting technique for protein investigation. Methods: A combination of conventional DSC and fast scanning calorimeters was used to study denaturation of lysozyme dissolved in glycerol. Glycerol was chosen as a solvent to prevent evaporation from the micro-sized samples of the fast scanning calorimeter. Results: The lysozyme denaturation temperatures in the range of scanning rates from 5 K/min to ca. 500,000 K/min follow the Arrhenius law. The experimental results for FSC and conventional DSC fall into two distinct clusters in a Kissinger plot, which are well approximated by two parallel straight lines. Conclusions: The transition temperatures for the unfolding process measured on fast scanning calorimetry sensor are significantly lower than what could be expected from the results of conventional DSC using extrapolation to high scanning rates. Evidence for the influence of the relative surface area on the unfolding temperature was found. General significance: For the first time, fast scanning calorimetry was employed to study protein denaturation with a range of temperature scanning rates of 5 orders of magnitude. Decreased thermal stability of the micro-sized samples on the fast scanning calorimeter raise caution over using bulk solution thermal stability data of proteins for applications where micro-sized dispersed protein solutions are used, e.g., spray drying
Localisation and colocalisation of KK-theory at sets of primes
Given a set of prime numbers S, we localise equivariant bivariant Kasparov
theory at S and compare this localisation with Kasparov theory by an exact
sequence. More precisely, we define the localisation at S to be KK^G(A,B)
tensored with the ring of S-integers Z[S^-1]. We study the properties of the
resulting variants of Kasparov theory.Comment: 16 page
Inter-Edge interaction in the Quantum Hall Effect
We consider effects of the interaction between electrons drifting along the
opposite sides of a narrow sample under the conditions of the quantum Hall
effect. A spatial variation of this interaction leads to backward scattering of
collective excitations propagating along the edges. Experiments on propagation
of the edge modes in samples with constrictions may give information about the
strength of the inter-edge electron interaction in the quantum Hall regime.Comment: 12 Pages, Latex, Accepted for publication in PRL
Ordering of localized moments in Kondo lattice models
We describe the transition from a ferromagnetic phase, to a disordered para-
magnetic phase, which occurs in one-dimensional Kondo lattice models with
partial conduction band filling. The transition is the quantum order-disorder
transition of the transverse-field Ising chain, and reflects double-exchange
ordered regions of localized spins being gradually destroyed as the coupling to
the conduction electrons is reduced. For incommensurate conduction band
filling, the low-energy properties of the localized spins near the transition
are dominated by anomalous ordered (disordered) regions of localized spins
which survive into the paramagnetic (ferromagnetic) phase. Many interesting
properties follow, including a diverging susceptibility for a finite range of
couplings into the paramagnetic phase. Our critical line equation, together
with numerically determined transition points, are used to determine the range
of the double-exchange interaction. Models we consider are the spin 1/2 Kondo
lattices with antiferromagnetic (Kondo) coupling, with ferromagnetic (Hund's
rule) coupling, and the Kondo lattice with repulsive interactions between the
conduction electrons.Comment: 18 pages, 6 embedded eps figures. To appear in Phys Rev
Aharonov-Bohm Oscillations in a One-Dimensional Wigner Crystal-Ring
We calculate the magnetic moment (`persistent current') in a strongly
correlated electron system --- a Wigner crystal --- in a one-dimensional
ballistic ring. The flux and temperature dependence of the persistent current
in a perfect ring is shown to be essentially the same as for a system of
non-interacting electrons. In contrast, by incorporating into the ring geometry
a tunnel barrier that pins the Wigner crystal, the current is suppressed and
its temperature dependence is drastically changed. The competition between two
temperature effects --- the reduced barrier height for macroscopic tunneling
and loss of quantum coherence --- may result in a sharp peak in the temperature
dependence. The character of the macroscopic quantum tunneling of a Wigner
crystal ring is dictated by the strength of pinning. At strong pinning the
tunneling of a rigid Wigner crystal chain is highly inhomogeneous, and the
persistent current has a well-defined peak at
independent of the barrier height ( is the sound velocity of the Wigner
crystal, is the length of the ring). In the weak pinning regime, the Wigner
crystal tunnels through the barrier as a whole and if the effect of
the barrier is to suppress the current amplitude and to shift the crossover
temperature from to . ( is the
amplitude of the pinning potential, is the drift velocity of a Wigner crystal ring with lattice spacing
). For very weak pinning, , the influence of the barrier on the
persistent current of a Wigner crystal ring is negligibly small.Comment: 30 pages, RevTeX, 2 figures available on reques
When Models Interact with their Subjects: The Dynamics of Model Aware Systems
A scientific model need not be a passive and static descriptor of its
subject. If the subject is affected by the model, the model must be updated to
explain its affected subject. In this study, two models regarding the dynamics
of model aware systems are presented. The first explores the behavior of
"prediction seeking" (PSP) and "prediction avoiding" (PAP) populations under
the influence of a model that describes them. The second explores the
publishing behavior of a group of experimentalists coupled to a model by means
of confirmation bias. It is found that model aware systems can exhibit
convergent random or oscillatory behavior and display universal 1/f noise. A
numerical simulation of the physical experimentalists is compared with actual
publications of neutron life time and {\Lambda} mass measurements and is in
good quantitative agreement.Comment: Accepted for publication in PLoS-ON
Granular discharge and clogging for tilted hoppers
We measure the flux of spherical glass beads through a hole as a systematic
function of both tilt angle and hole diameter, for two different size beads.
The discharge increases with hole diameter in accord with the Beverloo relation
for both horizontal and vertical holes, but in the latter case with a larger
small-hole cutoff. For large holes the flux decreases linearly in cosine of the
tilt angle, vanishing smoothly somewhat below the angle of repose. For small
holes it vanishes abruptly at a smaller angle. The conditions for zero flux are
discussed in the context of a {\it clogging phase diagram} of flow state vs
tilt angle and ratio of hole to grain size
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