Frustration and Melting of Colloidal Molecular Crystals

Using numerical simulations we show that a variety of novel colloidal crystalline states and multi-step melting phenomena occur on square and triangular two-dimensional periodic substrates. At half-integer fillings different kinds of frustration effects can be realized. A two-step melting transition can occur in which individual colloidal molecules initially rotate, destroying the overall orientational order, followed by the onset of interwell colloidal hopping, in good agreement with recent experiments.Comment: 6 pages, 3 postscript figures. Procedings of International Conference on Strongly Coupled Coulomb Systems, Santa Fe, 200

Fast scanning calorimetry of lysozyme unfolding at scanning rates from 5 K/min to 500,000 K/min

© 2018 Elsevier B.V. Background: Protein denaturation is often studied using differential scanning calorimetry (DSC). However, conventional instruments are limited in the temperature scanning rate available. Fast scanning calorimetry (FSC) provides an ability to study processes at much higher rates while using extremely small sample masses [ng]. This makes it a very interesting technique for protein investigation. Methods: A combination of conventional DSC and fast scanning calorimeters was used to study denaturation of lysozyme dissolved in glycerol. Glycerol was chosen as a solvent to prevent evaporation from the micro-sized samples of the fast scanning calorimeter. Results: The lysozyme denaturation temperatures in the range of scanning rates from 5 K/min to ca. 500,000 K/min follow the Arrhenius law. The experimental results for FSC and conventional DSC fall into two distinct clusters in a Kissinger plot, which are well approximated by two parallel straight lines. Conclusions: The transition temperatures for the unfolding process measured on fast scanning calorimetry sensor are significantly lower than what could be expected from the results of conventional DSC using extrapolation to high scanning rates. Evidence for the influence of the relative surface area on the unfolding temperature was found. General significance: For the first time, fast scanning calorimetry was employed to study protein denaturation with a range of temperature scanning rates of 5 orders of magnitude. Decreased thermal stability of the micro-sized samples on the fast scanning calorimeter raise caution over using bulk solution thermal stability data of proteins for applications where micro-sized dispersed protein solutions are used, e.g., spray drying

Localisation and colocalisation of KK-theory at sets of primes

Given a set of prime numbers S, we localise equivariant bivariant Kasparov theory at S and compare this localisation with Kasparov theory by an exact sequence. More precisely, we define the localisation at S to be KK^G(A,B) tensored with the ring of S-integers Z[S^-1]. We study the properties of the resulting variants of Kasparov theory.Comment: 16 page

Inter-Edge interaction in the Quantum Hall Effect

We consider effects of the interaction between electrons drifting along the opposite sides of a narrow sample under the conditions of the quantum Hall effect. A spatial variation of this interaction leads to backward scattering of collective excitations propagating along the edges. Experiments on propagation of the edge modes in samples with constrictions may give information about the strength of the inter-edge electron interaction in the quantum Hall regime.Comment: 12 Pages, Latex, Accepted for publication in PRL

Ordering of localized moments in Kondo lattice models

We describe the transition from a ferromagnetic phase, to a disordered para- magnetic phase, which occurs in one-dimensional Kondo lattice models with partial conduction band filling. The transition is the quantum order-disorder transition of the transverse-field Ising chain, and reflects double-exchange ordered regions of localized spins being gradually destroyed as the coupling to the conduction electrons is reduced. For incommensurate conduction band filling, the low-energy properties of the localized spins near the transition are dominated by anomalous ordered (disordered) regions of localized spins which survive into the paramagnetic (ferromagnetic) phase. Many interesting properties follow, including a diverging susceptibility for a finite range of couplings into the paramagnetic phase. Our critical line equation, together with numerically determined transition points, are used to determine the range of the double-exchange interaction. Models we consider are the spin 1/2 Kondo lattices with antiferromagnetic (Kondo) coupling, with ferromagnetic (Hund's rule) coupling, and the Kondo lattice with repulsive interactions between the conduction electrons.Comment: 18 pages, 6 embedded eps figures. To appear in Phys Rev

Aharonov-Bohm Oscillations in a One-Dimensional Wigner Crystal-Ring

We calculate the magnetic moment (`persistent current') in a strongly correlated electron system --- a Wigner crystal --- in a one-dimensional ballistic ring. The flux and temperature dependence of the persistent current in a perfect ring is shown to be essentially the same as for a system of non-interacting electrons. In contrast, by incorporating into the ring geometry a tunnel barrier that pins the Wigner crystal, the current is suppressed and its temperature dependence is drastically changed. The competition between two temperature effects --- the reduced barrier height for macroscopic tunneling and loss of quantum coherence --- may result in a sharp peak in the temperature dependence. The character of the macroscopic quantum tunneling of a Wigner crystal ring is dictated by the strength of pinning. At strong pinning the tunneling of a rigid Wigner crystal chain is highly inhomogeneous, and the persistent current has a well-defined peak at $T\sim 0.5\ \hbar s/L$ independent of the barrier height ($s$ is the sound velocity of the Wigner crystal, $L$ is the length of the ring). In the weak pinning regime, the Wigner crystal tunnels through the barrier as a whole and if $V_p>T_0$ the effect of the barrier is to suppress the current amplitude and to shift the crossover temperature from $T_0$ to $T^*\simeq \sqrt{V_{p}T_{0}}$. ($V_{p}$ is the amplitude of the pinning potential, $T_{0} =\hbar v_{F}/L ,\; v_{F}\sim \hbar/ma$ is the drift velocity of a Wigner crystal ring with lattice spacing $a$). For very weak pinning, $V_p\ll T_0$, the influence of the barrier on the persistent current of a Wigner crystal ring is negligibly small.Comment: 30 pages, RevTeX, 2 figures available on reques

When Models Interact with their Subjects: The Dynamics of Model Aware Systems

A scientific model need not be a passive and static descriptor of its subject. If the subject is affected by the model, the model must be updated to explain its affected subject. In this study, two models regarding the dynamics of model aware systems are presented. The first explores the behavior of "prediction seeking" (PSP) and "prediction avoiding" (PAP) populations under the influence of a model that describes them. The second explores the publishing behavior of a group of experimentalists coupled to a model by means of confirmation bias. It is found that model aware systems can exhibit convergent random or oscillatory behavior and display universal 1/f noise. A numerical simulation of the physical experimentalists is compared with actual publications of neutron life time and {\Lambda} mass measurements and is in good quantitative agreement.Comment: Accepted for publication in PLoS-ON

Granular discharge and clogging for tilted hoppers

We measure the flux of spherical glass beads through a hole as a systematic function of both tilt angle and hole diameter, for two different size beads. The discharge increases with hole diameter in accord with the Beverloo relation for both horizontal and vertical holes, but in the latter case with a larger small-hole cutoff. For large holes the flux decreases linearly in cosine of the tilt angle, vanishing smoothly somewhat below the angle of repose. For small holes it vanishes abruptly at a smaller angle. The conditions for zero flux are discussed in the context of a {\it clogging phase diagram} of flow state vs tilt angle and ratio of hole to grain size