229 research outputs found

    Analogue of the quantum hanle effect and polarization conversion in non-hermitian plasmonic metamaterials

    Full text link
    This document is the Accepted Manuscript version of a Published Work that appeared in final form in Nano Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/page/policy/articlesonrequest/index.htmlThe Hanle effect, one of the first manifestations of quantum theory introducing the concept of coherent superposition between pure states, plays a key role in numerous aspects of science varying from applicative spectroscopy to fundamental astrophysical investigations. Optical analogues of quantum effects help to achieve deeper understanding of quantum phenomena and, in turn, to develop cross-disciplinary approaches to realizations of new applications in photonics. Here we show that metallic nanostructures can be designed to exhibit a plasmonic analogue of the quantum Hanle effect and the associated polarization rotation. In the original Hanle effect, time-reversal symmetry is broken by a static magnetic field. We achieve this by introducing dissipative level crossing of localized surface plasmons due to nonuniform losses, designed using a non-Hermitian formulation of quantum mechanics. Such artificial plasmonic "atoms" have been shown to exhibit strong circular birefringence and circular dichroism which depends on the value of loss or gain in the metal-dielectric nanostructure. © 2012 American Chemical Society.This work has been supported in part by EPSRC (UK). P.G. acknowledges Royal Society for a Newton International Fellowship. F.J.R.-F. acknowledges support from grant FPI of GV and the Spanish MICINN under contracts CONSOLIDER EMET CSD2008-00066 and TEC2011-28664-C02-02.Ginzburg, P.; Rodríguez Fortuño, FJ.; Martínez Abietar, AJ.; Zayats, AV. (2012). Analogue of the quantum hanle effect and polarization conversion in non-hermitian plasmonic metamaterials. Nano Letters. 12(12):6309-6314. https://doi.org/10.1021/nl3034174S63096314121

    Resonances On-Demand for Plasmonic Nano-Particles

    Full text link
    A method for designing plasmonic particles with desired resonance spectra is presented. The method is based on repetitive perturbations of an initial particle shape while calculating the eigenvalues of the various quasistatic resonances. The method is rigorously proved, assuring a solution exists for any required spectral resonance location. Resonances spanning the visible and the near-infrared regimes, as designed by our method, are verified using finite-difference time-domain simulations. A novel family of particles with collocated dipole-quadrupole resonances is designed, demonstrating the unique power of the method. Such on-demand engineering enables strict realization of nano-antennas and metamaterials for various applications requiring specific spectral functions

    The B6 database: a tool for the description and classification of vitamin B6-dependent enzymatic activities and of the corresponding protein families

    Get PDF
    BACKGROUND: Enzymes that depend on vitamin B6 (and in particular on its metabolically active form, pyridoxal 5'-phosphate, PLP) are of great relevance to biology and medicine, as they catalyze a wide variety of biochemical reactions mainly involving amino acid substrates. Although PLP-dependent enzymes belong to a small number of independent evolutionary lineages, they encompass more than 160 distinct catalytic functions, thus representing a striking example of divergent evolution. The importance and remarkable versatility of these enzymes, as well as the difficulties in their functional classification, create a need for an integrated source of information about them. DESCRIPTION: The B6 database http://bioinformatics.unipr.it/B6db contains documented B6-dependent activities and the relevant protein families, defined as monophyletic groups of sequences possessing the same enzymatic function. One or more families were associated to each of 121 PLP-dependent activities with known sequences. Hidden Markov models (HMMs) were built from family alignments and incorporated in the database. These HMMs can be used for the functional classification of PLP-dependent enzymes in genomic sets of predicted protein sequences. An example of such analyses (a census of human genes coding for PLP-dependent enzymes) is provided here, whereas many more are accessible through the database itself. CONCLUSION: The B6 database is a curated repository of biochemical and molecular information about an important group of enzymes. This information is logically organized and available for computational analyses, providing a key resource for the identification, classification and comparative analysis of B6-dependent enzymes

    Lanthanoid “Bottlebrush” Clusters: Remarkably Elongated Metal-Oxo Core Structures with Controllable Lengths

    Get PDF
    Large metal-oxo clusters consistently assume spherical or regular polyhedral morphologies rather than high-aspect-ratio structures. Access to elongated core structures has now been achieved by the reaction of lanthanoid salts with a tetrazole-functionalized calixarene in the presence of a simple carboxylate coligand.The resulting Ln19 and Ln12 clusters are constructed from apex-fused Ln5O6 trigonal bipyramids and are formed consistently under a range of reaction conditions and reagent ratios. Altering the carboxylate coligandstructure reliably controls the cluster length, giving access to a new class of rod-like clusters of variable length

    Management of toxic ingestions with the use of renal replacement therapy

    Get PDF
    Although rare, renal replacement therapy (RRT) for the treatment of the metabolic, respiratory and hemodynamic complications of intoxications may be required. Understanding the natural clearance of the medications along with their volume of distribution, protein binding and molecular weight will help in understanding the benefit of commencing RRT. This information will aid in choosing the optimal forms of RRT in an urgent setting. Overdose of common pediatric medications are discussed with suggestions on the type of RRT within this educational review

    International project finance: review and implications for international finance and international business

    Get PDF
    corecore