A molecular dynamics computer simulation study of room-temperature ionic liquids. I. Equilibrium solvation structure and free energetics

Solvation in 1-ethyl-3-methylmidazolium chloride and in 1-ethyl-3-methylimidazolium hexafluorophosphate near equilibrium is investigated via molecular dynamics computer simulations with diatomic and benzenelike molecules employed as probe solutes. It is found that electrostriction plays an important role in both solvation structure and free energetics. The angular and radial distributions of cations and anions become more structured and their densities near the solute become enhanced as the solute charge separation grows. Due to the enhancement in structural rigidity induced by electrostriction, the force constant associated with solvent configuration fluctuations relevant to charge shift and transfer processes is also found to increase. The effective polarity and reorganization free energies of these ionic liquids are analyzed and compared with those of highly polar acetonitrile. Their screening behavior of electric charges is also investigated.Comment: 12 page

Gauge coupling renormalization in orbifold field theories

We investigate the gauge coupling renormalization in orbifold field theories preserving 4-dimensional N=1 supersymmetry in the framework of 4-dimensional effective supergravity. As a concrete example, we consider the 5-dimensional Super-Yang-Mills theory on a slice of AdS_5. In our approach, one-loop gauge couplings can be determined by the loop-induced axion couplings and the tree level properties of 4-dimensional effective supergravity which are much easier to be computed.Comment: 18 pages, JHEP style; 1-loop corrections to gauge kinetic functions are fully computed, references are adde

Patterning of ferroelectric nanodot arrays using a silicon nitride shadow mask

We grew well-ordered arrays of ferroelectric Pb (Zr0.2 Ti0.8) O3 (PZT) nanodots on a SrRu O3 SrTi O3 substrate by pulsed laser deposition. A silicon nitride shadow mask with ordered holes was used for patterning of the PZT arrays. Each dot has a height of ???15 nm and a diameter of ???120 nm with a similar dome shape over a large area. The ferroelectric properties of individual PZT dots were investigated by piezoresponse force microscopy. A single dot could be polarized individually and the polarized state remained unrelaxed to ???20 min.open232

1/f spectrum and memory function analysis of solvation dynamics in a room-temperature ionic liquid

To understand the non-exponential relaxation associated with solvation dynamics in the ionic liquid 1-ethyl-3-methylimidazolium hexafluorophosphate, we study power spectra of the fluctuating Franck-Condon energy gap of a diatomic probe solute via molecular dynamics simulations. Results show 1/f dependence in a wide frequency range over 2 to 3 decades, indicating distributed relaxation times. We analyze the memory function and solvation time in the framework of the generalized Langevin equation using a simple model description for the power spectrum. It is found that the crossover frequency toward the white noise plateau is directly related to the time scale for the memory function and thus the solvation time. Specifically, the low crossover frequency observed in the ionic liquid leads to a slowly-decaying tail in its memory function and long solvation time. By contrast, acetonitrile characterized by a high crossover frequency and (near) absence of 1/f behavior in its power spectra shows fast relaxation of the memory function and single-exponential decay of solvation dynamics in the long-time regime.Comment: 10 pages, 4 figure

Radius-dependent gauge unification in AdS5

We examine the relation of the 4-dimensional low energy coupling of bulk gauge boson in a slice of AdS5 to the 5-dimensional fundamental couplings as a function of the orbifold radius R. This allows us to address the gauge coupling unification in AdS5 by means of the radius running as well as the conventional momentum running. We then compute the radius dependence of 1-loop low energy couplings in generic AdS5 theory with 4-dimensional supersymmetry, and discuss the low energy predictions when the 5-dimensional couplings are assumed to be unified.Comment: 11 pages, 2 figures, revtex, v3: analysis was generalized to S^1/Z_2*Z_2 orbifoldin

TeV scale 5D SU(3)WSU(3)_W unification and the fixed point anomaly cancellation with chiral split multiplets

A possibility of 5D gauge unification of $SU(2)_L \times U(1)_Y$ in $SU(3)_W$ is examined. The orbifold compactification allows fixed points where $SU(2)_L\times U(1)_Y$ representations can be assigned. We present a few possibilities which give long proton lifetime, top-bottom mass hierarchy from geometry, and reasonable neutrino masses. In general, these {\it chiral models} can lead to fixed point anomalies. We can show easily, due to the simplicity of the model, that these anomalies are cancelled by the relevant Chern-Simons terms for all the models we consider. It is also shown that the fixed point U(1)--graviton--graviton anomaly cancels without the help from the Chern-Simons term. Hence, we conjecture that the fixed point anomalies can be cancelled if the effective 4D theory is made anomaly free by locating chiral fermions at the fixed points.Comment: LaTeX file of 19 pages with 1 figur

Mixed Bino-Wino-Higgsino Dark Matter in Gauge Messenger Models

Almost degenerate bino and wino masses at the weak scale is one of unique features of gauge messenger models. The lightest neutralino is a mixture of bino, wino and higgsino and can produce the correct amount of the dark matter density if it is the lightest supersymmetric particle. Furthermore, as a result of squeezed spectrum of superpartners which is typical for gauge messenger models, various co-annihilation and resonance regions overlap and very often the correct amount of the neutralino relic density is generated as an interplay of several processes. This feature makes the explanation of the observed amount of the dark matter density much less sensitive to fundamental parameters. We calculate the neutralino relic density assuming thermal history and present both spin independent and spin dependent cross sections for the direct detection. We also discuss phenomenological constraints from b to s gamma and muon g-2 and compare results of gauge messenger models to well known results of the mSUGRA scenario.Comment: 27 pages, 9 figures, references added, version to appear at JCA

Dynamical solution to the μ\mu problem at TeV scale

We introduce a new confining force (\mu-color) at TeV scale to dynamically generate a supersymmetry preserving mass scale which would replace the \mu parameter in the minimal supersymmetric standard model (MSSM). We discuss the Higgs phenomenology and also the pattern of soft supersymmetry breaking parameters allowing the correct electroweak symmetry breaking within the \mu-color model, which have quite distinctive features from the MSSM and also from other generalizations of the MSSM.Comment: 12 pages, REVte