Synthesis and Properties of La1−x_{1-x}Srx_xNiO3_3 and La1−x_{1-x}Srx_xNiO2_2

Superconductivity has been realized in films of La$_{1-x}$Sr$_x$NiO$_2$. Here we report synthesis and characterization of polycrystalline samples of La$_{1-x}$Sr$_x$NiO$_3$ and La$_{1-x}$Sr$_x$NiO$_2$ ($0\le x\le 0.2$). Magnetization and resistivity measurements reveal that La$_{1-x}$Sr$_x$NiO$_3$ are paramagnetic metals and La$_{1-x}$Sr$_x$NiO$_2$ exhibit insulating behavior. Superconductivity is not detected in bulk samples of La$_{1-x}$Sr$_x$NiO$_2$. The absence of superconductivity in bulk La$_{1-x}$Sr$_x$NiO$_2$ may be due to the generation of hydroxide during reduction or a small amount of nickel impurities. The effect of interface in films of La$_{1-x}$Sr$_x$NiO$_2$ may also play a role for superconductivity.Comment: 9 pages, 4 figure

Electronic correlations and energy gap in the bilayer nickelate La3_{3}Ni2_{2}O7_{7}

The discovery of superconductivity with a critical temperature of 80~K in La$_{3}$Ni$_{2}$O$_{7}$ under pressure has received enormous attention. La$_{3}$Ni$_{2}$O$_{7}$ is not superconducting under ambient pressure but exhibits a density-wave-like transition at $T^{\ast} \simeq 115$~K. Understanding the electronic correlations, charge dynamics and dominant orbitals are important steps towards the mechanism of superconductivity and other instabilities. Here, our optical study shows that La$_{3}$Ni$_{2}$O$_{7}$ features strong electronic correlations which significantly reduce the electron's kinetic energy and place it in the proximity of the Mott phase. The low-frequency optical conductivity reveals two Drude components arising from multiple bands dominated by the Ni-$d_{x^2 - y^2}$ and Ni-$d_{3z^2 - r^2}$ orbitals at the Fermi level. Above $T^{\ast}$, the scattering rates for both Drude components vary linearly with temperature, indicating non-Fermi-liquid behavior which may be associated with spin-fluctuation scattering. Below $T^{\ast}$, a gap opens in the Ni-$d_{3z^2 - r^2}$ orbital, suggesting the importance of the Ni-$d_{3z^2 - r^2}$ orbital in the density-wave-like instability. Our experimental results provide key insights into the mechanism of the density-wave-like order and superconductivity in La$_{3}$Ni$_{2}$O$_{7}$.Comment: 26 pages, 4 figures, Comments are welcome and appreciate

Single crystal growth and superconductivity in RbNi2_2Se2_2

We report the synthesis and characterization of RbNi$_2$Se$_2$, an analog of the iron chalcogenide superconductor Rb$_x$Fe$_2$Se$_2$, via transport, angle resolved photoemission spectroscopy, and density functional theory calculations. A superconducting transition at $T_{c}$ = 1.20 K is identified. In normal state, RbNi$_2$Se$_2$ shows paramagnetic and Fermi liquid behaviors. A large Sommerfeld coefficient yields a heavy effective electron mass of $m^{*}\approx6m_{e}$. In the superconducting state, zero-field electronic specific-heat data $C_{es}$ can be described by a two-gap BCS model, indicating that RbNi$_2$Se$_2$ is a multi-gap superconductor. Our density functional theory calculations and angle resolved photoemission spectroscopy measurements demonstrate that RbNi$_2$Se$_2$ exhibits relatively weak correlations and multi-band characteristics, consistent with the multi-gap superconductivity.Comment: 7 pages, 4 figure

Orbital-Dependent Electron Correlation in Double-Layer Nickelate La3Ni2O7

The latest discovery of high temperature superconductivity near 80K in La3Ni2O7 under high pressure has attracted much attention. Many proposals are put forth to understand the origin of superconductivity. The determination of electronic structures is a prerequisite to establish theories to understand superconductivity in nickelates but is still lacking. Here we report our direct measurement of the electronic structures of La3Ni2O7 by high-resolution angle-resolved photoemmission spectroscopy. The Fermi surface and band structures of La3Ni2O7 are observed and compared with the band structure calculations. A flat band is formed from the Ni-3dz2 orbitals around the zone corner which is 50meV below the Fermi level. Strong electron correlations are revealed which are orbital- and momentum-dependent. Our observations will provide key information to understand the origin of high temperature superconductivity in La3Ni2O7.Comment: 18 pages, 4 figure

Superconductivity near 80 Kelvin in single crystals of La3Ni2O7 under pressure

High-transition-temperature (high-T_c) superconductivity in cuprates has been discovered for more than three decades, but the underlying mechanism remains a mystery. Cuprates are the only unconventional superconducting family that host bulk superconductivity with T_cs above the liquid nitrogen boiling temperature at 77 Kelvin. Here we report an observation of superconductivity in single crystals of La3Ni2O7 with a maximum T_c of 80 Kelvin at pressures between 14.0-43.5 gigapascals using high-pressure resistance and mutual inductive magnetic susceptibility measurements. The superconducting phase under high pressure exhibits an orthorhombic structure of Fmmm space group with the 3d_(x^2-y^2 ) and 3d_(z^2 ) orbitals of Ni cations strongly interacting with oxygen 2p orbitals. Our density functional theory calculations suggest the superconductivity emerges coincidently with the metallization of the {\sigma}-bonding bands under the Fermi level, consisting of the 3d_(z^2 ) orbitals with the apical oxygens connecting Ni-O bilayers. Thus, our discoveries not only reveal important clues for the high-T_c superconductivity in this Ruddlesden-Popper double-layered perovskite nickelates but also provide a new family of compounds to investigate the high-T_c superconductivity mechanism.Comment: 15 pages with extended dat

Single-crystal growth and superconductivity in RbNi2Se2

We report the synthesis and characterization of RbNi2Se2, an analog of the iron chalcogenide superconductor RbxFe2Se2, via transport, angle-resolved photoemission spectroscopy, and density functional theory calculations. A superconducting transition at Tc=1.20 K is identified. In the normal state, RbNi2Se2 shows paramagnetic and Fermi-liquid behaviors. A large Sommerfeld coefficient yields an effective electron mass of m∗≈6me. In the superconducting state, zero-field electronic specific-heat data Ces can be described by a two-gap BCS model, indicating that RbNi2Se2 is a possible multigap superconductor. Our density functional theory calculations and angle-resolved photoemission spectroscopy measurements demonstrate that RbNi2Se2 exhibits relatively weak correlations and multiband characteristics, consistent with the multigap superconductivity

Exchange field enhanced upper critical field of the superconductivity in compressed antiferromagnetic EuTe2

We report high pressure studies on the C-type antiferromagnetic semiconductor EuTe2 up to 36.0 GPa. A structural transition from the I4/mcm to C2/m space group is identified at ~16 GPa. Superconductivity is discovered above ~5 GPa in both the I4/mcm and C2/m space groups. In the low-pressure phase (< 16 GPa), the antiferromagnetic transition temperature is enhanced with increasing pressure due to the enhanced magnetic exchange interactions. Magnetoresistance measurements indicate an interplay between the local moments of Eu2+ and the conduction electrons of Te 5p orbits. The upper critical field of the superconductivity is well above the Pauli limit. Across the structural transition to the high-pressure phase (> 16 GPa), EuTe2 becomes nonmagnetic and the superconducting transition temperature evolves smoothly with the upper critical field below the Pauli limit. Therefore, the high upper critical field of EuTe2 in the low-pressure phase is due to the exchange field compensation effect of the Eu magnetic order and the superconductivity in both structures may arise in the framework of the BCS theory.Comment: 11 pages,5 figures with 8 pages supplementar