sj-docx-1-tam-10.1177_17588359231221907 – Supplemental material for Major adverse cardiovascular events in advanced-stage lung cancer: a multicenter cohort study

Supplemental material, sj-docx-1-tam-10.1177_17588359231221907 for Major adverse cardiovascular events in advanced-stage lung cancer: a multicenter cohort study by Chih-Hao Chang, Shih-Hao Huang, Hung-Yu Huang, Meng-Hung Lin, Chung-Shu Lee, Hsin-Fu Lee, Jason Chia-Hsun Hsieh and Chun-Yu Cheng in Therapeutic Advances in Medical Oncology</p

Additional file 1 of Epidemiology and outcomes of multidrug-resistant bacterial infection in non-cystic fibrosis bronchiectasis

Supplementary Material 1: sTable 1. The standard criteria of antibiotics sensitivity by disc diffusion method in CGMH; sTable 2. Demographics and Clinical Characteristics before and after propensity score matchin

Cooperative Effect of Unsheltered Amide Groups on CO₂ Adsorption Inside Open-Ended Channels of a Zinc(II)–Organic Framework

A unique spatial arrangement of amide groups for CO₂ adsorption is found in the open-ended channels of a zinc­(II)–organic framework {[Zn₄(BDC)₄(BPDA)₄]·5DMF·3H₂O}_<i>n</i> (<b>1</b>, BDC = 1,4-benzyl dicarboxylate, BPDA = <i>N,N′</i>-bis­(4-pyridinyl)-1,4-benzenedicarboxamide). Compound <b>1</b> consists of 4⁴-<b>sql</b> [Zn₄(BDC)₄] sheets that are further pillared by a long linker of BPDA and forms a 3D porous framework with an α-Po 4¹²·6³ topology. Remarkably, the unsheltered amide groups in <b>1</b> provide a positive cooperative effect on the adsorption of CO₂ molecules, as shown by the significant increase in the CO₂ adsorption enthalpy with increasing CO₂ uptake. At ambient condition, a 1:1 ratio of active amide sites to CO₂ molecules was observed. In addition, compound <b>1</b> favors capture of CO₂ over N₂. DFT calculations provided rationale for the intriguing 1:1 ratio of amide sorption sites to CO₂ molecules and revealed that the nanochamber of compound <b>1</b> permits the slipped-parallel arrangement of CO₂ molecules, an arrangement found in crystal and gas-phase CO₂ dimer

Cooperative Effect of Unsheltered Amide Groups on CO₂ Adsorption Inside Open-Ended Channels of a Zinc(II)–Organic Framework

A unique spatial arrangement of amide groups for CO₂ adsorption is found in the open-ended channels of a zinc­(II)–organic framework {[Zn₄(BDC)₄(BPDA)₄]·5DMF·3H₂O}_<i>n</i> (<b>1</b>, BDC = 1,4-benzyl dicarboxylate, BPDA = <i>N,N′</i>-bis­(4-pyridinyl)-1,4-benzenedicarboxamide). Compound <b>1</b> consists of 4⁴-<b>sql</b> [Zn₄(BDC)₄] sheets that are further pillared by a long linker of BPDA and forms a 3D porous framework with an α-Po 4¹²·6³ topology. Remarkably, the unsheltered amide groups in <b>1</b> provide a positive cooperative effect on the adsorption of CO₂ molecules, as shown by the significant increase in the CO₂ adsorption enthalpy with increasing CO₂ uptake. At ambient condition, a 1:1 ratio of active amide sites to CO₂ molecules was observed. In addition, compound <b>1</b> favors capture of CO₂ over N₂. DFT calculations provided rationale for the intriguing 1:1 ratio of amide sorption sites to CO₂ molecules and revealed that the nanochamber of compound <b>1</b> permits the slipped-parallel arrangement of CO₂ molecules, an arrangement found in crystal and gas-phase CO₂ dimer