Liquid ethylene-propylene copolymers

Oligomers are prepared by heating solid ethylene-propylene rubber in container that retains solid and permits liquid product to flow out as it is formed. Molecular weight and viscosity of liquids can be predetermined by process temperature. Copolymers have low viscosity for given molecular weight

Mixed polyvalent-monovalent metal coating for carbon-graphite fibers

An improved coating of gasification catalyst for carbon-graphite fibers is provided comprising a mixture of a polyvalent metal such as calcium and a monovalent metal such as lithium. The addition of lithium provides a lighter coating and a more flexible coating when applied to a coating of a carboxyl containing resin such as polyacrylic acid since it reduces the crosslink density. Furthermore, the presence of lithium provides a glass-like substance during combustion which holds the fiber together resulting in slow, even combustion with much reduced evolution of conductive fragments. The coated fibers are utilized as fiber reinforcement for composites

Low-Mass X-ray Binaries and Globular Clusters in Early-Type Galaxies. I. Chandra Observations

We present a Chandra survey of LMXBs in 24 early-type galaxies. Correcting for detection incompleteness, the X-ray luminosity function (XLF) of each galaxy is consistent with a powerlaw with negative logarithmic differential slope, beta~2.0. However, beta strongly correlates with incompleteness, indicating the XLF flattens at low-Lx. The composite XLF is well-fitted by a powerlaw with a break at 2.21(+0.65,-0.56)E38 erg/s and beta=1.40(+0.10,-0.13) and 2.84(+0.39,-0.30) below and above it, respectively. The break is close to the Eddington limit for a 1.4Msun neutron-star, but the XLF shape rules out its representing the division between neutron-star and black-hole systems. Although the XLFs are similar, we find evidence of some variation between galaxies. The high-Lx XLF slope does not correlate with age, but may correlate with [alpha/Fe]. Considering only LMXBs with Lx>1E37 erg/s, matching the LMXBs with globular clusters (GCs) identified in HST observations of 19 of the galaxies, we find the probability a GC hosts an LMXB is proportional to LGC^alpha ZFe^gamma} where alpha=1.01+/-0.19 and gamma=0.33+/-0.11. Correcting for GC luminosity and colour effects, and detection incompleteness, we find no evidence that the fraction of LMXBs with Lx>1e37 erg/s in GCs (40%), or the fraction of GCs hosting LMXBs (~6.5%) varies between galaxies. The spatial distribution of LMXBs resembles that of GCs, and the specific frequency of LMXBs is proportional to the GC specific luminosity, consistent with the hypothesis that all LMXBs form in GCs. If the LMXB lifetime is tau and the duty cycle is Fd, our results imply ~1.5 (tau/1E8 yr)^-1 /Fd LMXBs are formed per Gyr per GC and we place an upper limit of 1 active LMXB in the field per 3.4E9Lsun of V-band luminosity.Comment: 24 pages, 17 figures and 6 tables. Accepted for publication in the Astrophysical Journal. Expanded discussion and various minor revisions to improve robustness of results. Conclusions unchange

Gas Sorption and Luminescence Properties of a Terbium(III)-Phosphine Oxide Coordination Material with Two-Dimensional Pore Topology

The structure, stability, gas sorption properties and luminescence behaviour of a new lanthanide-phosphine oxide coordination material are reported. The polymer PCM-15 is based on Tb(III) and tris(p-carboxylated) triphenylphosphine oxide and has a 5,5-connected net topology. It exhibits an infinite three-dimensional structure that incorporates an open, two-dimensional pore structure. The material is thermally robust and remains crystalline under high vacuum at 150 degrees C. When desolvated, the solid has a CO2 BET surface area of 1187 m(2) g(-1) and shows the highest reported uptake of both O-2 and H-2 at 77 K and 1 bar for a lanthanide-based coordination polymer. Isolated Tb(III) centres in the as-synthesized polymer exhibit moderate photoluminescence. However, upon removal of coordinated OH2 ligands, the luminescence intensity was found to approximately double; this process was reversible. Thus, the Tb(III) centre was used as a probe to detect directly the desolvation and resolvation of the polymer.Welch Foundation F-1738, F-1631National Science Foundation 0741973, CHE-0847763Chemistr

Jet-gas interactions in z~2.5 radio galaxies: evolution of the ultraviolet line and continuum emission with radio morphology

We present an investigation into the nature of the jet-gas interactions in a sample of 10 radio galaxies at 2.3<z<2.9 using deep spectroscopy of the UV line and continuum emission obtained at Keck II and the Very Large Telescope. Kinematically perturbed gas, which we have shown to be within the radio structure in previous publications, is always blueshifted with respect to the kinematically quiescent gas, is usually spatially extended, and is usually detected on both sides of the nucleus. In the three objects from this sample for which we are able to measure line ratios for both the perturbed and quiescent gases, we suggest that the former has a lower ionization state than the latter. We propose that the perturbed gas is part of a jet-induced outflow, with dust obscuring the outflowing gas that lies on the far side of the object. The spatial extent of the blueshifted perturbed gas, typically ~35 kpc, implies that the dust is spatially extended at least on similar spatial scales. We also find interesting interrelationships between UV line, UV continuum and radio continuum properties of this sample.Comment: Accepted for publication in MNRA

Resupply/repair of solid or hybrid attitude propulsion subsystems. Volume 2 - Technical study Final report, 1 Jul. - 31 Dec. 1970

Configuration of hybrid attitude propulsion system for orbiting space statio

Concept study for a high-efficiency nanowire-based thermoelectric

Materials capable of highly efficient, direct thermal-to-electric energy conversion would have substantial economic potential. Theory predicts that thermoelectric efficiencies approaching the Carnot limit can be achieved at low temperatures in one-dimensional conductors that contain an energy filter such as a double-barrier resonant tunneling structure. The recent advances in growth techniques suggest that such devices can now be realized in heterostructured, semiconductor nanowires. Here we propose specific structural parameters for InAs/InP nanowires that may allow the experimental observation of near-Carnot efficient thermoelectric energy conversion in a single nanowire at low temperature

Bridging the microscopic and the hydrodynamic in active filament solutions

Hydrodynamic equations for an isotropic solution of active polar filaments are derived from a microscopic mean-field model of the forces exchanged between motors and filaments. We find that a spatial dependence of the motor stepping rate along the filament is essential to drive bundle formation. A number of differences arise as compared to hydrodynamics derived (earlier) from a mesoscopic model where relative filament velocities were obtained on the basis of symmetry considerations. Due to the anisotropy of filament diffusion, motors are capable of generating net filament motion relative to the solvent. The effect of this new term on the stability of the homogeneous state is investigated.Comment: 7 pages, 2 figures, submitted to Europhys. Let

Rheology of Active Filament Solutions

We study the viscoelasticity of an active solution of polar biofilaments and motor proteins. Using a molecular model, we derive the constitutive equations for the stress tensor in the isotropic phase and in phases with liquid crystalline order. The stress relaxation in the various phases is discussed. Contractile activity is responsible for a spectacular difference in the viscoelastic properties on opposite sides of the order-disorder transition.Comment: 4 pages, 1 figur