Contribution of agricultural and non-agricultural use of pesticides to the environmental impact on aquatic life in regional surface water systems

By means of a modelling tool an analysis was made of the local variation in the use of pesticides in the province of Utrecht in The Netherlands, and the potential environmental impact of pesticide emissions on the aquatic ecosystems. The aim of this study was to identify and quantify the major sources of pesticide use and environmental impact, taking the regional variation of pesticide use into account. The analysis was targeted at different levels: detailed (individual active substances, individual agricultural crops, civil land-use types, hydrological catchment basins) and globally covering agricultural use, non-agricultural use (some civil sectors) and recreational shipping. The results can be used for the (re)design of environmental monitoring programmes of pesticides in surface waters and for the development of region based policies towards sustainable pesticide use. The analysis tool that was developed is considered to be applicable for other regions as wel

Bestrijdingsmiddelen in stroomgebieden en grondwaterbeschermingsgebieden in de provincie Utrecht

Een analyse is gemaakt van de locale verschillen in het gebruik en de daaruit volgende milieubelasting van bestrijdingsmiddelen in de provincie Utrecht met het doel de bronnen met de grootste bijdrage aan het bestrijdingsmiddelengebruik en milieueffecten te identificeren. Hierbij werd ingestoken op verschillende niveaus: gedetailleerd (individuele stoffen, teeltgroepen, typen grondgebruik) en globaal (de sectoren landbouw, niet-landbouw, en recreatievaart (antifouling). De resultaten van de analyse kunnen worden gebruikt voor afstemming van de controle op het voorkomen van bestrijdingsmiddelen in oppervlaktewater en grondwater (monitoring) en de ontwikkeling van gebiedsgericht beleid omtrent het bestrijdingsmiddelengebrui

Fuel consumption and associated emissions from seagoing ships at berth derived from an on-board survey

A methodology is presented to estimate the emissions of ships at berth based on their actual fuel consumption and the fuel quality. Accurate estimates of emissions from ships at berth demand reliable knowledge of the fuel consumption while at berth and associated fuel characteristics. However, assured information about energy use and fuel consumption of seagoing ships at berth is scarce. Proper estimation of ship emissions at berth is crucial for understanding the impact of shipping emissions on air quality and health in harbour cities as well as for a proper evaluation of the impact of abatement measures such as shore-side electricity and/or restrictions of sulphur content for shipping fuels to be used in ports. Therefore, a survey of energy consumption and fuel use on board of 89 seagoing ships was made in close cooperation with the Port of Rotterdam. Rotterdam is the major port of Europe ensuring that the results will have relevance for the larger European domain. On board of the ships at berth, a questionnaire was filled in by the chief engineer of that particular ship, assisted by two former mechanical shipping engineers employed at our organization. Survey results as well as the emission estimations are compared to the (scarce) information that is available and expert judgements in recent studies. The compiled survey data underlie the current Dutch emission estimation methodology for emissions of ships at berth. © 2009 Elsevier Ltd. All rights reserved

A revised estimate of copper emissions from road transport in UNECE-Europe and its impact on predicted copper concentrations

Comparisons of measured and model-predicted atmospheric copper concentrations show a severe underestimation of the observed concentrations by the models. This underestimation may be (partly) due to underestimated emissions of copper to air. Since the phase out of asbestos brake lining material, the composition of brake lining material has changed and may contain up to ∼15% copper. This makes brake wear from vehicles potentially an important source of atmospheric (particulate) copper concentrations. In this paper, we reassess the copper emissions due to exhaust emissions and brake wear from road transport. Overall, our reassessments result in an estimate of total copper emission to air in UNECE-Europe of 4.0-5.5 ktonnes yr-1, which is substantially higher than the previous estimate of 2.8 ktonnes yr-1. Copper concentrations over Europe are calculated with the LOTOS-EUROS model using the revised emission data as model input. The results show that the revised emission estimates are a major step towards gap closure of predicted versus observed copper concentrations in ambient air. Brake wear emissions may be responsible for 50-75% of the total copper emissions to air for most of Western Europe. The hypothesis that road transport is an important source of copper emissions is tested and confirmed by (1) reviewing available literature data of chemically speciated PM data from road tunnel studies and (2) the gradient observed in copper concentrations from ambient PM monitoring going from rural sites to street stations. The literature review and observational data suggest that the majority of the emitted PM10 brake wear particles is in the PM2.5-10 size range. The results of this study indicate that modification of brake lining composition is an important mitigation option to reduce copper exposure of the population in Western Europe. © 2007 Elsevier Ltd. All rights reserved

Brake wear from vehicles as an important source of diffuse copper pollution

In this article we show that brake wear from road traffic vehicles is an important source of atmospheric (participate) copper concentrations in Europe. Consequently, brake wear also contributes significantly to deposition fluxes of copper to surface waters. We estimated the copper emission due to brake wear to be 2.4 kiloton per year. For comparison, the official database for Europe (without brake wear) totals 2.6 kiloton per year. In Western Europe the brake wear emissions dominate the total emission of copper. Using the spatially resolved emission data, copper distributions over Europe were calculated with the LOTOS-EUROS model. Without brake wear the model underestimates observed copper concentrations by a factor of 3, which is in accordance with other studies. Including the brake wear emissions largely removes the bias. We find that 75% of the atmospheric copper input in the North Sea may be due to brake wear. We estimate that about 25% of the total copper input in the Dutch part of the North Sea stems from brake wear. Although the estimated brake wear copper emission is associated with a large uncertainty, it significantly improves our understanding of the copper cycle in the environment. © IWA Publishing 2007