Prediction of Stable Ground-State Lithium Polyhydrides under High Pressures

Hydrogen-rich compounds are important for understanding the dissociation of dense molecular hydrogen, as well as searching for room temperature Bardeen-Cooper-Schrieffer (BCS) superconductors. A recent high pressure experiment reported the successful synthesis of novel insulating lithium polyhydrides when above 130 GPa. However, the results are in sharp contrast to previous theoretical prediction by PBE functional that around this pressure range all lithium polyhydrides (LiHn (n = 2-8)) should be metallic. In order to address this discrepancy, we perform unbiased structure search with first principles calculation by including the van der Waals interaction that was ignored in previous prediction to predict the high pressure stable structures of LiHn (n = 2-11, 13) up to 200 GPa. We reproduce the previously predicted structures, and further find novel compositions that adopt more stable structures. The van der Waals functional (vdW-DF) significantly alters the relative stability of lithium polyhydrides, and predicts that the stable stoichiometries for the ground-state should be LiH2 and LiH9 at 130-170 GPa, and LiH2, LiH8 and LiH10 at 180-200 GPa. Accurate electronic structure calculation with GW approximation indicates that LiH, LiH2, LiH7, and LiH9 are insulative up to at least 208 GPa, and all other lithium polyhydrides are metallic. The calculated vibron frequencies of these insulating phases are also in accordance with the experimental infrared (IR) data. This reconciliation with the experimental observation suggests that LiH2, LiH7, and LiH9 are the possible candidates for lithium polyhydrides synthesized in that experiment. Our results reinstate the credibility of density functional theory in description H-rich compounds, and demonstrate the importance of considering van der Waals interaction in this class of materials.Comment: 34 pages, 15 figure

Generation of frequency multiplexed entangled single photons assisted by the entanglement

We present a scheme to generate the frequency multiplexed entangled (FME) single photons based on the entanglement between two species atomic mixture ensemble. The write and reads fields driven according to a certain timing sequence, the generation of FME single photons can be repeated until success is achieved. The source might have significant applications in wavelength division multiplexing quantum key distribution.Comment: 4 pages, 4 figures, submitted to PR

Sedimentation of the Lower Cretaceous Xiagou formation and Its Response to Regional Tectonics in the Qingxi Sag, Jiuquan Basin, NW China

Under the constraint of an isochronous sequence stratigraphic framework, sediment infill of the Xiagou Formation reflects the overall control of dynamic tectonic movements and episodic sedimentations in the Qingxi Sag. Structure reactivity during post-depositional processes could cause stratigraphic variations in longitudinal time and lateral space. This study documents sediment infill features and their response to the tectonic evolutions of the Qingxi Sag. The data sets include comparison of cores, well drilling, 3D seismic, inter-well correlation, wave impedance inversion profiles, original strata recovery data, sedimentary fades spatial evolution and their superimposition with paleogeomorphology. The Jiuquan Basin is a Mesozoic-Cenozoic superposition basin comprising an early rifting graben phase and a later compression phase. Since the Early Cretaceous, the basin has undergone four major tectonic episodes: 1) extension during the Early Cretaceous, 2) tectonic inversion caused by northwest-southeast contraction from the Late Cretaceous to the Paleocene, 3) weak extension from the Eocene to the Miocene and 4) contraction from the Miocene to the present. Therefore, the Jiuquan Basin is the product of taphrogenic, collisional and shearing movements. Seismic interpretations of sequence and maximum flooding surface divide the Xiagou Formation into three third order sequences: SQK1g(0), SQK1g(1) and SQK1g(2+3). Five sedimentary facies associations are identified: the shoreland plain, fan delta dominated sedimentary systems, turbidite deposits, shallow lakes and half-deep lake systems. From K1g(0) to K1g(2+3), decreased sandstone percentages in three fan delta areas indicate a continuously transgressive process, which shows the transition from proximal to distal sites in most statistic wells and an obvious decrease of fan delta scales. The northeast-southwest faults control the lakeward distributions of delta fronts and turbidite fans. The correspondence of sedimentary infill and its response to tectonic movements have been demonstrated in the Qingxi Sag. The more active eastern part of the northeastern boundary fault has an important influence on the northeastward migration of depocenters in the Xiagou Formation. The topography developed continuously from K1g(0) to K1g(2+3), but the diminished subsidence indicates the dominant geological process varying from intense fault rifting in an early period to relatively gentle and overall subsidence in a later period during the Early Cretaceous. (C) 2013 Elsevier Ltd. All rights reserved.Key Laboratory of Tectonics and Petroleum Resources, Ministry of Education TPR-2011-09Project of "Double strong effect, driving mechanism and hydrocarbon significance of tectonic activity during depositional period of Dongying Formation in Qikou and Nanpu Sag, Eastern China" 41272122Geological Science

Effects of losses in the hybrid atom-light interferometer

Enhanced Raman scattering can be obtained by injecting a seeded light field which is correlated with the initially prepared collective atomic excitation. This Raman amplification process can be used to realize atom-light hybrid interferometer. We numerically calculate the phase sensitivities and the signal-to-noise ratios of this interferometer with the method of homodyne detection and intensity detection, and give their differences between this two methods. In the presence of loss of light field and atomic decoherence the measure precision will be reduced which can be explained by the break of the intermode decorrelation conditions of output modesComment: 9 pages, 7 figure