52 research outputs found
Computational Study of the Magnetic Structure of NaIrO
The magnetic structure of honeycomb iridate NaIrO is of paramount
importance to its exotic properties. The magnetic order is established
experimentally to be zigzag antiferromagnetic. However, the previous assignment
of ordered moment to the -axis is tentative. We examine the magnetic
structure of NaIrO using first-principles methods. Our calculations
reveal that total energy is minimized when the zigzag antiferromagnetic order
is magnetized along . Such a magnetic configuration
is explained by adding anisotropic interactions to the nearest-neighbor
Kitaev-Heisenberg model. Spin-wave spectrum is also calculated, where the
calculated spin gap of meV can in principle be measured by future
inelastic neutron scattering experiments. Finally we emphasize that our
proposal is consistent with all known experimental evidence, including the most
relevant resonant x-ray magnetic scattering measurements [X. Liu \emph{et al.}
{Phys. Rev. B} \textbf{83}, 220403(R) (2011)].Comment: 18 pages, 7 figure
Transition of AC electroosmotic flow from linear to nonlinear state in different pH environment
Electroosmotic flow (EOF) exists widely at the solid-liquid interface in the
presence of external electric field. However, the EOF driven by an alternating
current (AC) electric field in diverse chemical environments was far from being
well understood due to limited experimental investigations. In this
investigation, through the high-resolution laser-induced fluorescent
photobleaching anemometer (LIFPA), the transient velocity according to the AC
EOF on the electric double layer (EDL) far from the electrodes has been
experimentally characterized, by means of time series and power spectra. With
analyzing the transient velocity, the transition of AC EOF from linear to
nonlinear behavior is observed in a broad parameter space, e.g. mean flow
velocity, the frequency and intensity of the AC electric field, and the pH
value of the bulk fluid. To take all these parameters into account, an
electro-inertial velocity has been applied as the characteristic velocity,
instead of the commonly applied Helmholtz-Smouluchowski velocity. Then, the
transitional electric field intensity and the corresponding
dimensionless parameter are systematically studied. A power-law
relationship between the linear term coefficient and has been
established, with the scaling exponents determined by the pH value of the
electrolyte solution. We hope the current investigation can provide a deeper
understanding of the transition of AC EOF and the instantaneous response of
EOFs in other forms. It also provides a simple model to understand the coupling
between electric field and fluid flow, in both linear and nonlinear status
Onset of nonlinear electroosmotic flow under AC electric field
Nonlinearity of electroosmotic flows (EOFs) is ubiquitous and plays a crucial
role in the mass and energy transfer in ion transport, specimen mixing,
electrochemistry reaction, and electric energy storage and utilizing. When and
how the transition from a linear regime to a nonlinear one is essential for
understanding, prohibiting or utilizing nonlinear EOF. However, suffers the
lacking of reliable experimental instruments with high spatial and temporal
resolutions, the investigation of the onset of nonlinear EOF still stays in
theory. Herein, we experimentally studied the velocity fluctuations of EOFs
driven by AC electric field via ultra-sensitive fluorescent blinking tricks.
The linear and nonlinear AC EOFs are successfully identified from both the time
trace and energy spectra of velocity fluctuations. The critical electric field
() separating the two statuses is determined and is discovered by
defining a generalized scaling law with respect to the convection velocity
() and AC frequency () as ~. The
universal control parameters are determined with surprising accuracy for
governing the status of AC EOFs. We hope the current investigation could be
essential in the development of both theory and applications of nonlinear EOF
Large-Scale Flow in Micro Electrokinetic Turbulent Mixer
In the present work, we studied the three-dimensional (3D) mean flow field in a micro electrokinetic (μEK) turbulence based micromixer by micro particle imaging velocimetry (μPIV) with stereoscopic method. A large-scale solenoid-type 3D mean flow field has been observed. The extraordinarily fast mixing process of the μEK turbulent mixer can be primarily attributed to two steps. First, under the strong velocity fluctuations generated by μEK mechanism, the two fluids with different conductivity are highly mixed near the entrance, primarily at the low electric conductivity sides and bias to the bottom wall. Then, the well-mixed fluid in the local region convects to the rest regions of the micromixer by the large-scale solenoid-type 3D mean flow. The mechanism of the large-scale 3D mean flow could be attributed to the unbalanced electroosmotic flows (EOFs) due to the high and low electric conductivity on both the bottom and top surface
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