1 research outputs found
High-Performance Large-Scale Flexible Dye-Sensitized Solar Cells Based on Anodic TiO<sub>2</sub> Nanotube Arrays
A simple
strategy to fabricate flexible dye-sensitized solar cells involves
the use of photoanodes based on TiO<sub>2</sub> nanotube (TNT) arrays
with rear illumination. The TNT films (tube length ∼35 μm)
were produced via anodization, and sensitized with N719 dye for photovoltaic
characterization. Pt counter electrodes of two types were used: a
conventional FTO/glass substrate for a device of rigid type and an
ITO/PEN substrate for a device of flexible type. These DSSC devices
were fabricated into either a single-cell structure (active area 3.6
× 0.5 cm<sup>2</sup>) or a parallel module containing three single
cells (total active area 5.4 cm<sup>2</sup>). The flexible devices
exhibit remarkable performance with efficiencies η = 5.40 %
(single cell) and 4.77 % (parallel module) of power conversion, which
outperformed their rigid counterparts with η = 4.87 % (single
cell) and 4.50 % (parallel model) under standard one-sun irradiation.
The flexible device had a greater efficiency of conversion of incident
photons to current and a broader spectral range than the rigid device;
a thinner electrolyte layer for the flexible device than for the rigid
device is a key factor to improve the light-harvesting ability for
the TNT-DSSC device with rear illumination. Measurements of electrochemical
impedance spectra show excellent catalytic activity and superior diffusion
characteristics for the flexible device. This technique thus provides
a new option to construct flexible photovoltaic devices with large-scale,
light-weight, and cost-effective advantages for imminent applications
in consumer electronics