Truncation of Unitary Operads

We introduce truncation ideals of a $\Bbbk$-linear unitary symmetric operad and use them to study ideal structure, growth property and to classify operads of low Gelfand-Kirillov dimension

Boron carboxylate catalysis of homoallylboration.

Boron tris(trifluoroacetate) is identified as the first effective catalyst for the homoallyl- and homocrotylboration of aldehydes by cyclopropylcarbinylboronates. NMR spectroscopic studies and theoretical calculations of key intermediates and transition states both suggest that a ligand-exchange mechanism, akin to our previously reported PhBCl2-promoted homoallylations, is operative. Our experimental and theoretical results also suggest that the catalytic activity of boron tris(trifluoroacetate) might originate from more facile catalytic turnover of the trifluoroacetate ligands (in agreement with DFT calculations) or from a lower propensity for formation of off-pathway reservoir intermediates (as observed by (1)H NMR). This work shows that carboxylates are viable catalytic ligands for homoallyl- and homocrotylations of carbonyl compounds and opens the door to the development of catalytic asymmetric versions of this transformation

Spectral Representation Theory for Dielectric Behavior of Nonspherical Cell Suspensions

Recent experiments revealed that the dielectric dispersion spectrum of fission yeast cells in a suspension was mainly composed of two sub-dispersions. The low-frequency sub-dispersion depended on the cell length, while the high-frequency one was independent of it. The cell shape effect was simulated by an ellipsoidal cell model but the comparison between theory and experiment was far from being satisfactory. Prompted by the discrepancy, we proposed the use of spectral representation to analyze more realistic cell models. We adopted a shell-spheroidal model to analyze the effects of the cell membrane. It is found that the dielectric property of the cell membrane has only a minor effect on the dispersion magnitude ratio and the characteristic frequency ratio. We further included the effect of rotation of dipole induced by an external electric field, and solved the dipole-rotation spheroidal model in the spectral representation. Good agreement between theory and experiment has been obtained.Comment: 19 pages, 5 eps figure

Many-body Green's function theory of ferromagnetic Heisenberg systems with single-ion anisotropies in more than one direction

The behaviour of ferromagnetic systems with single-ion anisotropies in more than one direction is investigated with many-body Green's function theory generalizing earlier work with uniaxial anisotropies only. It turns out to be of advantage to construct Green's functions in terms of the spin operators S^x, S^y and S^z, instead of the commonly used S^+,S^- and S^z operators. The exchange energy terms are decoupled by RPA and the single-ion anisotropy terms by a generalization of the Anderson-Callen decoupling. We stress that in the derivation of the formalism none of the three spatial axes is special, so that one is always able to select a reference direction along which a magnetization component is not zero. Analytical expressions are obtained for all three components of the magnetization and the expectation values , and for any spin quantum number S. The formalism considers both in-plane and out-of-plane anisotropies. Numerical calculations illustrate the behaviour of the magnetization for 3-dimensional and 2-dimensional systems for various parameters. In the 2-dimensional case, the magnetic dipole-dipole coupling is included, and a comparison is made between in-plane and out-of-plane anisotropies.Comment: 16 pages, 8 figures, missing figures adde

Ballistic spin field-effect transistors: Multichannel effects

We study a ballistic spin field-effect transistor (SFET) with special attention to the issue of multi-channel effects. The conductance modulation of the SFET as a function of the Rashba spin-orbit coupling strength is numerically examined for the number of channels ranging from a few to close to 100. Even with the ideal spin injector and collector, the conductance modulation ratio, defined as the ratio between the maximum and minimum conductances, decays rapidly and approaches one with the increase of the channel number. It turns out that the decay is considerably faster when the Rashba spin-orbit coupling is larger. Effects of the electronic coherence are also examined in the multi-channel regime and it is found that the coherent Fabry-Perot-like interference in the multi-channel regime gives rise to a nested peak structure. For a nonideal spin injector/collector structure, which consists of a conventional metallic ferromagnet-thin insulator-2DEG heterostructure, the Rashba-coupling-induced conductance modulation is strongly affected by large resonance peaks that arise from the electron confinement effect of the insulators. Finally scattering effects are briefly addressed and it is found that in the weakly diffusive regime, the positions of the resonance peaks fluctuate, making the conductance modulation signal sample-dependent.Comment: 18 pages, 15 figure