6 research outputs found
Protocols for the Miller indexing of Sb2Se3 and a non-x-ray method of orienting its single crystals
Multi-Phase Sputtered TiO2-Induced Current–Voltage Distortion in Sb2Se3 Solar Cells
Despite the recent success of CdS/Sb2Se3 heterojunction devices, cadmium toxicity, parasitic absorption from the relatively narrow CdS band gap (2.4 eV) and multiple reports of inter-diffusion at the interface forming Cd(S,Se) and Sb2(S,Se)3 phases, present significant limitations to this device architecture. Among the options for alternative partner layers in antimony chalcogenide solar cells, the wide band gap, non-toxic titanium dioxide (TiO2) has demonstrated the most promise. It is generally accepted that the anatase phase of the polymorphic TiO2 is preferred, although there is currently an absence of analysis with regard to phase influence on device performance. This work reports approaches to distinguish between TiO2 phases using both surface and bulk characterization methods. A device fabricated with a radio frequency (RF) magnetron sputtered rutile-TiO2 window layer (FTO/TiO2/Sb2Se3/P3HT/Au) achieved an efficiency of 6.88% and near-record short–circuit current density (Jsc) of 32.44 mA cm−2, which is comparable to established solution based TiO2 fabrication methods that produced a highly anatase-TiO2 partner layer and a 6.91% efficiency device. The sputtered method introduces reproducibility challenges via the enhancement of interfacial charge barriers in multi-phase TiO2 films with a rutile surface and anatase bulk. This is shown to introduce severe S-shaped current–voltage (J–V) distortion and a drastic fill–factor (FF reduction in these devices
Sb 5s2 lone pairs and band alignment of Sb2Se3: a photoemission and density functional theory study
The presence of a lone pair of 5s electrons at the valence band maximum (VBM) of Sb2Se3 and the
resulting band alignments are investigated using soft and hard X-ray photoemission spectroscopy in
parallel with density functional theory (DFT) calculations. Vacuum-cleaved and exfoliated bulk crystals of
Sb2Se3 are analysed using laboratory and synchrotron X-ray sources to acquire high resolution valence
band spectra with both soft and hard X-rays. Utilising the photon-energy dependence of different orbital
cross-sections and corresponding DFT calculations, the various orbital contributions to the valence band
could be identified, including the 5s orbital’s presence at the VBM. The ionization potential is also
determined and places the VBM at 5.13 eV below the vacuum level, similar to other materials with 5s2
lone pairs, but far above those of related materials without lone pairs of electrons