Multiphonon decay of strong mode in quantum lattice

A nonperturbative theory of multiphonon anharmonic decay of strongly excited local mode is developed whereby the mode is considered classically and phonons, quantum mechanically. The decay rate of the mode is expressed via the negative frequency parts of the phonon pair correlation functions. In the case of two-phonon decay the later satisfy the linear integral equations while in the case of two- and more-phonon decay they satisfy the nonlinear integral equations. As a result, the processes mentioned differently depend on the mode amplitude A: two-phonon processes smoothly deminish if A tends to infinity while three- and more-phonon processes are fully switched-off at large amplitudes and they abruptly switch-on if the amplitude approaches the critical value. At that the decay rate gets rather high value (of the order of the mode quantum per period). The final stage of the relaxation is well described by the perturbation theory.Comment: 13 pages. submitted to Zeitschrift fur Physik B, to appear Vol.104, Dec. 199

Pressure dependence of two-level systems in disordered atomic chain

The dependence of two-level systems in disordered atomic chain on pressure, both positive and negative was studied numerically. The disorder was produced through the use of interatomic pair potentials having more than one energy minimum. It was found that there exists a correlation between the energy separation of the minima of two-level systems Delta and the variation of this separation with pressure. The correlation may have either positive or negative sign, implying that the asymmetry of two-level systems may in average increase or decrease with pressure depending on the interplay of different interactions between atoms in disordered state. The values of Delta depend on the sign of pressure.Comment: 5 pages, 5 figure

Structure and time-dependence of quantum breathers

Quantum states of a discrete breather are studied in two ways. One method involves numerical diagonalization of the Hamiltonian, the other uses the path integral to examine correlations in the eigenstates. In both cases only the central nonlinearity is retained. To reduce truncation effects in the numerical diagonalization, a basis is used that involves a quadratic local mode. A similar device is used in the path integral method for deducing localization. Both approaches lead to the conclusion that aside from quantum tunneling the quantized discrete breather is stable.Comment: 33 pages, 20 figures, to appear in J. Chem. Phy