Effects of grain size and shape in modeling reflectance spectra of mineral mixtures

The effects of grain size and shape on the reflectance spectra of mineral mixtures are investigated to improve a reflectance model called the isograin model, whose prototype was proposed by M. Kinoshita in 1985. The sample powder was assumed to consist of an infinite number of layers, each of which has the same thickness with the grain size d

Spin-1/2 Triangular Lattice with Orbital Degeneracy in a Metallic Oxide Ag2NiO2

A novel metallic and magnetic transition metal oxide Ag2NiO2 is studied by means of resistivity, magnetic susceptibility, specific heat and X-ray diffraction. The crystal structure is characterized by alternating stacking of a Ni3+O2 layer and a (Ag2)+ layer, the former realizing a spin-1/2 triangular lattice with eg orbital degeneracy and the latter providing itinerant electrons. It is found that the NiO2 layer exhibits orbital ordering at Ts = 260 K and antiferromagnetic spin ordering at TN = 56 K. Moreover, a moderately large mass enhancement is found for the itinerant electrons, suggesting a significant contribution from the nearly localized Ni 3d state to the Ag 5s state that forms a broad band.Comment: 9 pages, 5 figures, to be published in Rapid Communications, Phys. Rev.

HED Meteorites, Carbonaceous Chondrites, Vesta, and Space Weathering.

第3回極域科学シンポジウム/第35回南極隕石シンポジウム 11月29日（木） 国立国語研究所 2階講

A Possible Phase Transition in beta-pyrochlore Compounds

We investigate a lattice of interacting anharmonic oscillators by using a mean field theory and exact diagonalization. We construct an effective five-state hopping model with intersite repulsions as a model for beta-pyrochlore AOs_2O_6(A=K, Rb or Cs). We obtain the first order phase transition line from large to small oscillation amplitude phases as temperature decreases. We also discuss the possibility of a phase with local electric polarizations. Our theory can explain the origin of the mysterious first order transition in KOs_2O_6.Comment: 4 pages, 4 figures, submitted to J. Phys. Soc. Jp

Green's function of fully anharmonic lattice vibration

Motivated by the discovery of superconductivity in beta-pyrochlore oxides, we study property of rattling motion coupled with conduction electrons. We derive the general expression of the Green's function of fully anharmonic lattice vibration within the accuracy of the second order perturbation of electron-ion interaction by introducing self-energy, vertex-correction, and normalization factor for each transition. Using the expression, we discuss the characteristic properties of the spectral function in the entire range from weakly anharmonic potential to double-well case, and calculate NMR relaxation rate due to the two phonon Raman process

Strong-Coupling Theory of Rattling-Induced Superconductivity

In order to clarify the mechanism of the enhancement of superconducting transition temperature $T_{\rm c}$ due to anharmonic local oscillation of a guest ion in a cage composed of host atoms, i.e., {\it rattling}, we analyze the anharmonic Holstein model by applying the Migdal-Eliashberg theory. From the evaluation of the normal-state electron-phonon coupling constant, it is found that the strong coupling state is developed, when the bottom of a potential for the guest ion becomes wide and flat. Then, $T_{\rm c}$ is enhanced with the increase of the anharmonicity in the potential, although $T_{\rm c}$ is rather decreased when the potential becomes a double-well type due to very strong anharmonicity. From these results, we propose a scenario of anharmonicity-controlled strong-coupling tendency for superconductivity induced by rattling. We briefly discuss possible relevance of the present scenario with superconductivity in $\beta$-pyrochlore oxides.Comment: 8 pages, 6 figure

Upper critical field and de Haas-van Alphen oscillations in KOs2_2O6_6 measured in a hybrid magnet

Magnetic torque measurements have been performed on a KOs$_2$O$_6$ single crystal in magnetic fields up to 35.3 T and at temperatures down to 0.6 K. The upper critical field is determined to be $\sim$30 T. De Haas-van Alphen oscillations are observed. A large mass enhancement of (1+$\lambda$) = $m^* / m_{band}$ = 7.6 is found. It is suggested that, for the large upper critical field to be reconciled with Pauli paramagnetic limiting, the observed mass enhancement must be of electron-phonon origin for the most part.Comment: 4 pages, 4 figures, published versio

Effects of Rattling Phonons on the Quasiparticle Excitation and Dynamics in the Superconducting β\beta-Pyrochlore KOs2_2O6_6

Microwave penetration depth $\lambda$ and surface resistance at 27 GHz are measured in high quality crystals of KOs$_2$O$_6$. Firm evidence for fully-gapped superconductivity is provided from $\lambda(T)$. Below the second transition at $T_{\rm p}\sim 8$ K, the superfluid density shows a step-like change with a suppression of effective critical temperature $T_{\rm c}$. Concurrently, the extracted quasiparticle scattering time shows a steep enhancement, indicating a strong coupling between the anomalous rattling motion of K ions and quasiparticles. The results imply that the rattling phonons help to enhance superconductivity, and that K sites freeze to an ordered state with long quasiparticle mean free path below $T_{\rm p}$.Comment: 5 pages, 5 figures, to be published in Phys. Rev. Let

Phonon Dynamics and Multipolar Isomorphic Transition in beta-pyrochlore KOs2O6

We investigate with a microscopic model anharmonic K-cation oscillation observed by neutron experiments in beta-pyrochlore superconductor KOs2O6, which also shows a mysterious first-order structural transition at Tp=7.5 K. We have identified a set of microscopic model parameters that successfully reproduce the observed temperature dependence and the superconducting transition temperature. Considering changes in the parameters at Tp, we can explain puzzling experimental results about electron-phonon coupling and neutron data. Our analysis demonstrates that the first-order transition is multipolar transition driven by the octupolar component of K-cation oscillations. The octupole moment does not change the symmetry and is characteristic to noncentrosymmetric K-cation potential.Comment: 5 pages, 4 figures, submitted to J. Phys. Soc. Jp

Electronic and Magnetic Structure of LaCuO2.5_{2.5}

The recently-discovered ``ladder'' compound LaCuO$_{2.5}$ has been found to admit hole doping without altering its structure of coupled copper oxide ladders. While susceptibility measurements on the parent compound suggest a spin gap and a spin-liquid state, NMR results indicate magnetic order at low temperatures. These seemingly contradictory results may be reconciled if in fact the magnetic state is near the crossover from spin liquid to antiferromagnet, and we investigate this possibility. From a tight-binding fit to the valence LDA bandstructure, we deduce that the strength of the interladder hopping term is approximately half that of intraladder hopping, showing that the material is three-dimensional in character. A mean-field treatment of the insulating magnetic state gives a spin-liquid phase whose spin gap decreases with increasing interladder coupling, vanishing (signalling a transition to the ordered phase) at a value somewhat below that obtained for LaCuO$_{2.5}$. The introduction of an on-site repulsion term, $U$, to the band scheme causes a transition to an antiferromagnetic insulator for rather small but finite values of $U$, reflecting the predominance of (one-dimensional) ladder behavior, and an absence of any special nesting features.Comment: 8 pages + 5 figure