46 research outputs found

    Samenwerking in de wetenschap

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    Rede Wageninge

    A nesting conformation of the 5ā€²-bromo-1ā€²,3ā€²-xylyl-18-crown-5Ā·tert-butylammonium hexafluorophosphate complex; the correlation of the structures of crown ether complexes in the solid state and in solution

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    Single-crystal X-ray analysis of the 5ā€²-bromo-1ā€²,3ā€²-xylyl-18-crown-5Ā· tert-butylammonium hexafluorophosphate complex shows that the complex is of the ā€œnestingā€ type in which the cation and the aryl group are on the same face of the macroring and that the macroring has a (ag+a) (agāˆ’a) (ag+a) (agāˆ’a)(ag+a) (agāˆ’a) conformation

    Malkanguniol, one of the polyalcohols from celastrus paniculatus willd

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    The synthesis of 4H-pyran containing hemispherands via pyrylium salts

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    Two new hemispherands 2a and 2b containing a central 4H-pyran unit were synthesized via appropiately substituted 2,6-phenyl pyrylium salts; largest Ī”Go values of complexation of 2a and 2b with different alkali picrates are found for Na+ and K+
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