30,108 research outputs found

    The ontology of temperature in nonequilibrium systems

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    The laws of thermodynamics provide a clear concept of the temperature for an equilibrium system in the continuum limit. Meanwhile, the equipartition theorem allows one to make a connection between the ensemble average of the kinetic energy and the uniform temperature. When a system or its environment is far from equilibrium, however, such an association does not necessarily apply. In small systems, the regression hypothesis may not even apply. Herein, we show that in small nonequilibrium systems, the regression hypothesis still holds though with a generalized definition of the temperature. The latter must now be defined for each such manifestation.Comment: J.Chem.Phys. (in press); 23 pages, 3 figures, 1 tabl

    High-Resolution Optical Spectroscopy of DY Cen: Diffuse Interstellar Bands in a Proto-Fullerene Circumstellar Environment?

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    We search high-resolution and high-quality VLT/UVES optical spectra of the hot R Coronae Borealis star DY Cen for electronic transitions of the C-60 molecule and diffuse interstellar bands (DIBs). We report the non-detection of the strongest C-60 electronic transitions (e. g., those at similar to 3760, 3980, and 4024 angstrom). The absence of C-60 absorption bands may support recent laboratory results, which show that the similar to 7.0, 8.5, 17.4, and 18.8 mu m emission features seen in DY Cen-and other similar objects with polycyclic-aromatic-hydrocarbon-like dominated IR spectra-are attributable to proto-fullerenes or fullerene precursors rather than to C-60. DIBs toward DY Cen are normal for its reddening; the only exception is the DIB at 6284 angstrom (possibly also the 7223 angstrom DIB) which is found to be unusually strong. We also report the detection of a new broad (FWHM similar to 2 angstrom) and unidentified feature centered at similar to 4000 angstrom. We suggest that this new band may be related to the circumstellar proto-fullerenes seen at infrared wavelengths.Director's Discretionary Time (DDT) program 284.D-5048Spanish Ministry of Economy and Competitiveness AYA-2011-27754Robert A. Welch Foundation of Houston, Texas F-634McDonald Observator
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