90 research outputs found

    In vitro corrosion of ZEK100 plates in Hank's Balanced Salt Solution

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    Background: In recent years magnesium alloys have been intensively investigated as potential resorbable materials with appropriate mechanical and corrosion properties. Particularly in orthopedic research magnesium is interesting because of its mechanical properties close to those of natural bone, the prevention of both stress shielding and removal of the implant after surgery. Methods: ZEK100 plates were examined in this in vitro study with Hank's Balanced Salt Solution under physiological conditions with a constant laminar flow rate. After 14, 28 and 42 days of immersion the ZEK100 plates were mechanically tested via four point bending test. The surfaces of the immersed specimens were characterized by SEM, EDX and XRD. Results: The four point bending test displayed an increased bending strength after 6 weeks immersion compared to the 2 week group and 4 week group. The characterization of the surface revealed the presence of high amounts of O, P and Ca on the surface and small Mg content. This indicates the precipitation of calcium phosphates with low solubility on the surface of the ZEK100 plates. Conclusions: The results of the present in vitro study indicate that ZEK100 is a potential candidate for degradable orthopedic implants. Further investigations are needed to examine the degradation behavior

    Clara Immerwahr: A Life in the Shadow of Fritz Haber

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    We examine the life of Clara Haber, nee Immerwahr (1870–1915), including her tragic suicide and its possible relation to the involvement of her husband, Fritz Haber, in chemical warfare. Clara earned a doctorate in chemistry from the University of Breslau, in 1900, as the first woman ever, and married the physical chemist Fritz Haber within a year of her graduation. With no employment available for female scientists, Clara freelanced as an instructor in the continued education of women, mainly housewives, while struggling not to become a housewife herself. Her duties as the designated head of a posh household hardly brought fulfillment to her life. The outbreak of WWI further exacerbated the situation, as Fritz Haber applied himself in extraordinary ways to aid the German war effort, which included his initiative to develop chemical weapons. The night that he celebrated the “success” of the first chlorine cloud attack and his promotion to the rank of captain, Clara committed suicide. However, we found little evidence to support express claims that Clara was an outspoken pacifist who took her life because of her disapproval of her husband’s engagement in chemical warfare. We examine the origin of this “myth of Clara Immerwahr” that took root in the 1990s from the perspective offered by the available scholarly sources, including those that have only recently come to light

    Abstracts from the 8th International Conference on cGMP Generators, Effectors and Therapeutic Implications

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    This work was supported by a restricted research grant of Bayer AG

    Die Bankbeziehungen zwischen Deutschland und Russland im 19. Jahrhundert: Beilage zum Geschaeftsbericht 1989

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    SIGLEAvailable from Bibliothek des Instituts fuer Weltwirtschaft, ZBW, Duesternbrook Weg 120, D-24105 Kiel C 192996 / FIZ - Fachinformationszzentrum Karlsruhe / TIB - Technische InformationsbibliothekDEGerman

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