106 research outputs found
Decay Process for Three - Species Reaction - Diffusion System
We propose the deterministic rate equation of three-species in the reaction -
diffusion system. For this case, our purpose is to carry out the decay process
in our three-species reaction-diffusion model of the form . The
particle density and the global reaction rate are also shown analytically and
numerically on a two-dimensional square lattice with the periodic boundary
conditions. Especially, the crossover of the global reaction rate is discussed
in both early-time and long-time regimes.Comment: 6 pages, 3 figures, Late
Reaction-diffusion fronts with inhomogeneous initial conditions
Properties of reaction zones resulting from A+B -> C type reaction-diffusion
processes are investigated by analytical and numerical methods. The reagents A
and B are separated initially and, in addition, there is an initial macroscopic
inhomogeneity in the distribution of the B species. For simple two-dimensional
geometries, exact analytical results are presented for the time-evolution of
the geometric shape of the front. We also show using cellular automata
simulations that the fluctuations can be neglected both in the shape and in the
width of the front.Comment: 11 pages, 3 figures, submitted to J. Phys.
Liesegang patterns: Effect of dissociation of the invading electrolyte
The effect of dissociation of the invading electrolyte on the formation of
Liesegang bands is investigated. We find, using organic compounds with known
dissociation constants, that the spacing coefficient, 1+p, that characterizes
the position of the n-th band as x_n ~ (1+p)^n, decreases with increasing
dissociation constant, K_d. Theoretical arguments are developed to explain
these experimental findings and to calculate explicitly the K_d dependence of
1+p.Comment: RevTex, 8 pages, 3 eps figure
Formation of Liesegang patterns: A spinodal decomposition scenario
Spinodal decomposition in the presence of a moving particle source is
proposed as a mechanism for the formation of Liesegang bands. This mechanism
yields a sequence of band positions x_n that obeys the spacing law
x_n~Q(1+p)^n. The dependence of the parameters p and Q on the initial
concentration of the reagents is determined and we find that the functional
form of p is in agreement with the experimentally observed Matalon-Packter law.Comment: RevTex, 4 pages, 4 eps figure
Diffusion-Limited Annihilation with Initially Separated Reactants
A diffusion-limited annihilation process, A+B->0, with species initially
separated in space is investigated. A heuristic argument suggests the form of
the reaction rate in dimensions less or equal to the upper critical dimension
. Using this reaction rate we find that the width of the reaction front
grows as in one dimension and as in two
dimensions.Comment: 9 pages, Plain Te
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