5 research outputs found
P(NMe<sub>2</sub>)<sub>3</sub>‑Mediated Reductive (1 + 4) Annulation Reaction of Isatins with Nitroalkenes: An Access to Spirooxindolyl Isoxazoline <i>N</i>‑Oxides and Their Corresponding Isoxazolines
The reductive (1
+ 4) annulation reaction of isatins and substituted
nitroalkenes mediated by a trivalent phosphorus reagent has been realized
for the first time, providing easy access to spirooxindolyl isoxazoline <i>N</i>-oxides in moderate to excellent yields with a flexible
substrate scope. This reaction presumably proceeds through a Michael
addition–intramolecular substitution sequence via active in
situ generated Kukhtin–Ramirez zwitterions from isatins and
PÂ(NMe<sub>2</sub>)<sub>3</sub>. It is also demonstrated that the spirooxindolyl
isoxazoline <i>N</i>-oxides can be readily converted into
the corresponding isoxazolines in good yields
P(NMe<sub>2</sub>)<sub>3</sub>‑Mediated Reductive (1 + 4) Annulation Reaction of Isatins with Nitroalkenes: An Access to Spirooxindolyl Isoxazoline <i>N</i>‑Oxides and Their Corresponding Isoxazolines
The reductive (1
+ 4) annulation reaction of isatins and substituted
nitroalkenes mediated by a trivalent phosphorus reagent has been realized
for the first time, providing easy access to spirooxindolyl isoxazoline <i>N</i>-oxides in moderate to excellent yields with a flexible
substrate scope. This reaction presumably proceeds through a Michael
addition–intramolecular substitution sequence via active in
situ generated Kukhtin–Ramirez zwitterions from isatins and
PÂ(NMe<sub>2</sub>)<sub>3</sub>. It is also demonstrated that the spirooxindolyl
isoxazoline <i>N</i>-oxides can be readily converted into
the corresponding isoxazolines in good yields
Vehicle-Mounted Pavement Health Monitoring System Based on a Spring-Guide-Assisted Triboelectric Sensor
The present pavement health monitoring is limited by
a professional
staff patrol. Herein, a vehicle-mounted pavement health monitoring
system (VPHMS) based on a spring-guide-assisted triboelectric sensor
(S-TES) is proposed, which uses the vibration generated by vehicles
passing through uneven pavements to monitor the pavement damage. The
VPHMS consists of S-TES, the integration module, and the terminal
display module. The designed S-TES has high stability and can achieve
a high linear vibration amplitude measurement within 90 mm. Moreover,
the integration module is used to process signals and transmit wireless
data transmission. The terminal display module is used to receive
signals and display the measurement results on the screen. When a
vehicle equipped with VPHMS is driven over uneven pavements, the
system can accurately monitor the potholes and upheavals on the pavement
in real time. This work has significant application value in fields
such as pavement health monitoring and intelligent transportation
Vehicle-Mounted Pavement Health Monitoring System Based on a Spring-Guide-Assisted Triboelectric Sensor
The present pavement health monitoring is limited by
a professional
staff patrol. Herein, a vehicle-mounted pavement health monitoring
system (VPHMS) based on a spring-guide-assisted triboelectric sensor
(S-TES) is proposed, which uses the vibration generated by vehicles
passing through uneven pavements to monitor the pavement damage. The
VPHMS consists of S-TES, the integration module, and the terminal
display module. The designed S-TES has high stability and can achieve
a high linear vibration amplitude measurement within 90 mm. Moreover,
the integration module is used to process signals and transmit wireless
data transmission. The terminal display module is used to receive
signals and display the measurement results on the screen. When a
vehicle equipped with VPHMS is driven over uneven pavements, the
system can accurately monitor the potholes and upheavals on the pavement
in real time. This work has significant application value in fields
such as pavement health monitoring and intelligent transportation
Vehicle-Mounted Pavement Health Monitoring System Based on a Spring-Guide-Assisted Triboelectric Sensor
The present pavement health monitoring is limited by
a professional
staff patrol. Herein, a vehicle-mounted pavement health monitoring
system (VPHMS) based on a spring-guide-assisted triboelectric sensor
(S-TES) is proposed, which uses the vibration generated by vehicles
passing through uneven pavements to monitor the pavement damage. The
VPHMS consists of S-TES, the integration module, and the terminal
display module. The designed S-TES has high stability and can achieve
a high linear vibration amplitude measurement within 90 mm. Moreover,
the integration module is used to process signals and transmit wireless
data transmission. The terminal display module is used to receive
signals and display the measurement results on the screen. When a
vehicle equipped with VPHMS is driven over uneven pavements, the
system can accurately monitor the potholes and upheavals on the pavement
in real time. This work has significant application value in fields
such as pavement health monitoring and intelligent transportation