SIGNIFICAN ENHANCEMENT OF OPTICAL PROPERTIES THROUGH METHYLCELLULOSE (MC) / GADOLINIUM OXIDE COMPOSITES

In the present work, Methylcellulose (MC) with Gd2O3 composite films were prepared to study the optical properties. and investigate the effect of adding Gd2O3 nanoparticles with MC in linear optical investigation.W.I.A. and I.I.N. thank Department, Faculty of Science, Tanta University, for financial support

Fabrication, physical, structure characteristics, neutron and radiation shielding capacity of high-density neodymio-cadmium lead-borate glasses: Nd2O3/CdO/PbO/B2O3/Na2O

High-density glasses of neodymio-cadmium lead borate of chemical composition xNd2O3/20CdO/20PbO/(57-x)B2O3/3Na2O, where (0 (0Nd) ≤ x ≤ 5 (5Nd) wt%) have been fabricated by a melt quenching process. Physical, structure properties as well as gamma-radiation and neutron shielding effectiveness in wide photon energy range 0.015–15 MeV have been examined. The amorphous nature of xNd-glasses was confirmed, where there was a lack of their crystallinity. Density was gradually increased from 5.006 g/cm3 for 0Nd-glass sample to 5.245 g/cm3 for 5Nd-glass sample. In terms of the mass attenuation coefficient (MAC), introducing Nd3+ ions in the glass matrix has a direct constructive influence on the obtained values of MAC. Generally, the MAC trend follows the order (MAC)5Nd > (MAC)4Nd > (MAC)3Nd > (MAC)2Nd > (MAC)1Nd > (MAC)0Nd. The linear attenuation coefficient (LAC) has a similar trend as MAC for all xNd-glasses. In terms of the half-value layer (T1/2), the 5Nd-glasses possessed the minimum T1/2 values (0.004 cm at 15 keV to 4.301 cm at 15 MeV). Therefore, the T1/2 of the fabricated xNd-glasses has an inverse behavior of the MAC and LAC. Thus, (T1/2)0Nd > (T1/2)1Nd > (T1/2)2Nd > (T1/2)3Nd > (T1/2)4Nd > (T1/2)5Nd. The effective atomic number (Zeff) parameter follows the order (Zeff)5Nd > (Zeff)4Nd > (Zeff)3Nd > (Zeff)2Nd > (Zeff)1Nd > (Zeff)0Nd. In the energies preferred for radiation applications, 5Nd-glasses possess very low exposure (EBF) and energy absorption (EABF) buildup factor values. The fast neutron removal cross-section (FNRC) of the fabricated glasses is improved as the Nd3+ content increases in the glass matrix. © 2022, The Author(s), under exclusive licence to Springer-Verlag GmbH, DE part of Springer Nature.Taif University, TUTaif University Researchers Supporting Project number (TURSP-2020/84), Taif University, Taif, Saudi Arabia

Structural interpretation of potential field data using the enhancement techniques: a case study

The enhancement techniques of potential field data are commonly used to detect the boundary locations of geological structures. There are many different techniques for estimating the source boundaries. Through synthetic examples and Bouguer data from the southern Red Sea, we have evaluated the performance of 15 enhancement techniques. The findings show that the tilt angle of horizontal gradient (TAHG) and fast sigmoid (FSED) techniques perform better than other techniques under almost all scenarios. Moreover, these two techniques can avoid producing false structures or connected structures as other techniques. The extracted lineaments from the TAHG and FSED were compared with surface faults of the study area. As a result, major differences are caused by rifting effect on the oceanic crust. The obtained results provide valuable information to better understand the structural features of the southern Red Sea and to introduce a more reliable structural interpretation

Qualitative and Quantitative Characterization of Municipal Waste in Uncontrolled Dumpsites and Landfills Using Integrated Remote Sensing, Geological and Geophysical Data: A Case Study

The conducted research offers an environmental assessment of municipal waste (MW) using remote sensing (RS), geological, and geophysical datasets. As a test site, the present study aims to characterize one of the largest uncontrolled dumpsites in Egypt. RS data analysis indicates that high temperature values are concentrated at the MW and landfill site allocations as a result of the decomposition process, leading to fire risks. Moreover, the geological and structural data draw attention to the structural-controlled old topography role on MW distributions. Consequently, the dumpsite MW has larger surface quantities near the downthrows of the mapped faults. For MW characterization, geophysical data are acquired to produce2D/3D resistivity models. Because MW has the ability to become soft clay, the municipal organic waste and landfill leachate resistivities are lower than that of municipal solid waste and sandy soils. The geophysical inversion results indicate that the maximum thickness of MW calibrating with the drilled borehole data is 60 m. Furthermore, the estimated MW dumpsite volume is about 42.32 MCM. Accordingly, the MW can be characterized in an accurate qualitative and quantitative manner. Our findings, therefore, help the efforts of uncontrolled dumpsite development and thus contribute to sustainability plans

Paradigm of Geological Mapping of the Adıyaman Fault Zone of Eastern Turkey Using Landsat 8 Remotely Sensed Data Coupled with PCA, ICA, and MNFA Techniques

A principal and independent component analysis (PCA and ICA) and a minimum noise fraction analysis (MNFA) were applied in this study to Landsat 8 Operational Land Imager (OLI) images along the Adıyaman fault zone in Eastern Turkey. These analyses indicated that the lithologic units, fault patterns, and the morphological and structural features can be mapped highly accurately by using spectral-matching techniques in regions where rocks are well exposed. An inspection of all possible band combinations indicated that the PCA 134 and 231 and the ICA 132 band combinations give the best false color composite images for identifying the lithological units and contacts. The findings of the MNFA band combinations show that the MNFA 521 band combination also is robust for discriminating the lithological units, particularly Quaternary clastic units (colluvium/alluvium). MNFA band 1 alone provides the best image for tracing the tectonic and structural elements in the study area. The new up-to-date lithologic map of the Adıyaman fault zone we produced upon the interpretation of the processed OLI images reveals several river channels that are offset and beheaded by the Adıyaman fault, which verifies its Quaternary activity. This study demonstrated that, when used with the OLI data, the PCA, ICA, and MNFA are very powerful for lithological and structural mapping in actively deforming tectonic zones and hence can be applied to other regions elsewhere in the world where the climate is arid to semiarid, and the vegetation cover is scarce

Surface Characterization and Electrical Properties of Low Energy Irradiated PANI/PbS Polymeric Nanocomposite Materials

In this work, nanocomposite samples of polyaniline (PANI) and lead sulfide nanoparticles (PbSNPs) were prepared, utilizing the solution preparation method, for implantation in energy storage elements. The PANI/PbS films were irradiated by different fluences of oxygen beam: 5 × 1016, 10 × 1016, and 15 × 1016 ions.cm−2. The composite was investigated by XRD, SEM, DSC, and FTIR. After ion irradiation, the Tg and Tm values decreased by 4.8 °C and 10.1 °C, respectively. The conductivities, electrical impedances, and electrical moduli of untreated and irradiated samples were examined in frequencies ranging from 102 Hz to 5 MHz. Moreover, the ion beam caused a modification in the dielectric characteristics of PANI/PbS. The dielectric constant ε′ was improved from 31 to 611, and the electrical conductivity increased from 1.45 × 10−3 S/cm to 25.9 × 10−3 S/cm by enhancing the fluence to 15 × 1016 ions.cm−2. Additionally, the potential energy barrier, Wm, decreased from 0.43 eV to 0.23 eV. The induced changes in the dielectric properties and structural characteristics of the PANI/PbS samples were determined. These modifications provide an opportunity to use irradiated PANI/PbS samples for several applications, including microelectronics, batteries, and storage of electrical energy

Tailoring Variations in the Microstructures, Linear/Nonlinear Optical, and Mechanical Properties of Dysprosium-Oxide-Reinforced Borate Glasses

Hybrid dysprosium-doped borate glassy samples [B-Gly/Dy]HDG (Borate Glass/Dysprosium)Hybrid Doped Glass were prepared in this study via the melt-quenching method. Its linear/nonlinear optical, photoluminescence, hardness indentation, and micro-creep properties were analyzed. The amorphous structure for all the prepared samples was confirmed from the XRD patterns. In addition, density functional theory (DFT), optimized by TD-DFT and Crystal Sleuth, was used to study the structure and crystallinity of the [B-Gly/Dy]HDG as isolated molecules and agreed with the peaks of experimental XRD patterns. Additionally, theoretical lattice types were studied using Polymorph, a content studio software, and orthorhombic Pc21b (29) and triclinic P-1 (2) structures were provided. Both mechanical and optical properties were responses to different concentrations of Dy2O3 in the glassy borate system. It was found that the length of indentation increases by increasing the load time, and the hardness decreases by increasing the load time. The stress exponent value also increased from 4.1 to 6.3. The indentation strain increases by increasing the load time. The direct optical band gap was evaluated using the Davis–Mott relation. Urbach energy and its connection to the disorder degree in materials were studied depending on the Dy2O3 concentration. The acquired optical parameters were also analyzed to determine the nonlinear refractive index as well as the linear and third-order nonlinear optical susceptibility of the investigated glass samples. The photoluminescence emission spectra were recorded, and their attributed transitions were studied. The mechanical studies showed that the hardness values increased by increasing Dy2O3 concentrations from 4160.54 to 5631.58 Mpa. The stress exponent value also increased from 4.1 to 6.3. Therefore, the higher value of stress exponent (S) is more resistant to indentation creep