11 research outputs found
Local charge transfer doping in suspended graphene nanojunctions
We report electronic transport measurements in nanoscale graphene transistors
with gold and platinum electrodes whose channel lengths are shorter than 100
nm, and compare them with transistors with channel lengths from 1 \textmu{}m to
50 \textmu{}m. We find a large positive gate voltage shift in charge neutrality
point (NP) for transistors made with platinum electrodes but negligible shift
for devices made with gold electrodes. This is consistent with the transfer of
electrons from graphene into the platinum electrodes. As the channel length
increases, the disparity between the measured NP using gold and platinum
electrodes disappears.Comment: 11 pages, 3 figures, to appear in Appl. Phys. Let
Review—Use of impedance spectroscopy for the estimation of Li-ion battery state of charge, state of health and internal temperature
The rapid adoption of electric vehicles (EVs) and the evolving needs of portable electronic devices has intensified the need for enhanced state diagnosis of Li-ion batteries (LIBs). As the applications for LIBs continue to grow, so too does their operational requirements; ranging from faster charging and improved safety to optimized energy control and extended lifespan. In order to keep pace with the growing requirements of LIBs, improvements in the monitoring of battery states must be achieved. Although electrochemical impedance spectroscopy (EIS) has existed since the 1960's, its potential as a diagnosis tool has only received widespread attention in recent years. In this paper, a detailed review on the applicability of impedance measurements for the estimation of the vital battery parameters of state of charge (SOC), state of health (SOH) and internal temperature (IT) has been performed
Composition for energy generator- storage- and strain sensor and methods of use thereof
Compositions and devices for harvesting electrical energy from mechanical and thermal energy, storing such produced energy, and sensing strain based on low cost materials and processes. In embodiments, the compositions are flexible and include a flexible polymer embedded and coated with a nanostructured piezoelectric material
2D material integrated macroporous electrodes for Li-ion batteries
Three-dimensionally structured architectures are known to improve the performance of electrodes used in Li ion battery systems. In addition, integration of select 2D materials into 3D structures, for enhancing both electrical conductivity and electrochemical activity, will prove advantageous. Here a scalable one-step chemical vapor deposition technique is demonstrated for the controlled etching and simultaneous graphene growth on stainless steel substrates resulting in a 3D micro-mesh architecture that is ideal for high rate/high capacity electrodes; the graphene coated 3D stainless steel current collector is used with an MoS2 electrode material for demonstrating high stability and rate capacity in Li-ion batteries
Supercapacitor Operating At 200 Degrees Celsius
The operating temperatures of current electrochemical energy storage devices are limited due to electrolyte
degradation and separator instability at higher temperatures. Here we demonstrate that a tailored mixture
of materials can facilitate operation of supercapacitors at record temperatures, as high as 2006C. Composite
electrolyte/separator structures made from naturally occurring clay and room temperature ionic liquids,
with graphitic carbon electrodes, show stable supercapacitor performance at 2006C with good cyclic
stability. Free standing films of such high temperature composite electrolyte systems can become versatile
functional membranes in several high temperature energy conversion and storage applications
Curious Case of Positive Current Collectors: Corrosion and Passivation at High Temperature
In
the evaluation of compatibility of different components of cell
for high-energy and extreme-conditions applications, the highly focused
are positive and negative electrodes and their interaction with electrolyte.
However, for high-temperature application, the other components are
also of significant influence and contribute toward the total health
of battery. In present study, we have investigated the behavior of
aluminum, the most common current collector for positive electrode
materials for its electrochemical and temperature stability. For electrochemical
stability, different electrolytes, organic and room temperature ionic
liquids with varying Li salts (LiTFSI, LiFSI), are investigated. The
combination of electrochemical and spectroscopic investigations reflects
the varying mechanism of passivation at room and high temperature,
as different compositions of decomposed complexes are found at the
surface of metals
Ionic Liquid–Organic Carbonate Electrolyte Blends To Stabilize Silicon Electrodes for Extending Lithium Ion Battery Operability to 100 °C
Fabrication
of lithium-ion batteries that operate from room temperature to elevated
temperatures entails development and subsequent identification of
electrolytes and electrodes. Room temperature ionic liquids (RTILs)
can address the thermal stability issues, but their poor ionic conductivity
at room temperature and compatibility with traditional graphite anodes
limit their practical application. To address these challenges, we
evaluated novel high energy density three-dimensional nano-silicon
electrodes paired with 1-methyl-1-propylpiperidinium bisÂ(trifluoromethanesulfonyl)Âimide
(Pip) ionic liquid/propylene carbonate (PC)/LiTFSI electrolytes. We
observed that addition of PC had no detrimental effects on the thermal
stability and flammability of the reported electrolytes, while largely
improving the transport properties at lower temperatures. Detailed
investigation of the electrochemical properties of silicon half-cells
as a function of PC content, temperature, and current rates reveal
that capacity increases with PC content and temperature and decreases
with increased current rates. For example, addition of 20% PC led
to a drastic improvement in capacity as observed for the Si electrodes
at 25 °C, with stability over 100 charge/discharge cycles. At
100 °C, the capacity further increases by 3–4 times to
0.52 mA h cm<sup>–2</sup> (2230 mA h g<sup>–1</sup>)
with minimal loss during cycling
Three-Dimensionally Engineered Porous Silicon Electrodes for Li Ion Batteries
The ultimate goal of Li ion battery design should consist
of fully
accessible metallic current collectors, possibly of nanoscale dimensions,
intimately in contact with high capacity stable electrode materials.
Here we engineer three-dimensional porous nickel based current collector
coated conformally with layers of silicon, which typically suffers
from poor cycle life, to form high-capacity electrodes. These binder/conductive
additive free silicon electrodes show excellent electrode adhesion
resulting in superior cyclic stability and rate capability. The nickel
current collector design also allows for an increase in silicon loading
per unit area leading to high areal discharge capacities of up to
0.8 mAh/cm<sup>2</sup> without significant loss in rate capability.
An excellent electrode utilization (∼85%) and improved cyclic
stability for the metal/silicon system is attributed to reduced internal
stresses/fracture upon electrode expansion during cycling and shorter
ionic/electronic diffusion pathways that help in improving the rate
capability of thicker silicon layers