193 research outputs found
Direct Observation of Reductive Coupling Mechanism between Oxygen and Iron/Nickel in Cobalt-Free Li-Rich Cathode Material: An in Operando X-Ray Absorption Spectroscopy Study
Li-rich cathodes possess high capacity and are promising candidates in next-generation high-energy density Li-ion batteries. This high capacity is partly attributed to its poorly understood oxygen-redox activity. The present Li-rich cathodes contain expensive and environmentally-incompatible cobalt as a main transition metal. In this work, cobalt-free, iron-containing Li-rich cathode material (nominal composition LiMnNiFeO) is synthesized, which exhibits excellent discharge capacity (≈250 mAh g and cycling stability. In operando, X-ray absorption spectroscopy at Mn, Fe, and Ni K edges reveals its electrochemical mechanism. X-ray absorption near edge structure (XANES) features of Fe and Ni K edges show unusual behavior: when an electrode is charged to 4.5 V, Fe and Ni K edges’ XANES features shift to higher energies, evidence for Fe→Fe and Ni→Ni oxidation. However, when charged above 4.5 V, XANES features of Fe and Ni K edges shift back to lower energies, indicating Fe→Fe and Ni→Ni reduction. This behavior can be linked to a reductive coupling mechanism between oxygen and Fe/Ni. Though this mechanism is observed in Fe-containing Li-rich materials, the only electrochemically active metal in such cases is Fe. LiMnNiFeO has multiple electrochemically active metal ions; Fe and Ni, which are investigated simultaneously and the obtained results will assist tailoring of cost-effective Li-rich materials
Self-Standing, Collector-Free Maricite NaFePO4 / Carbon Nanofiber Cathode Endowed with Increasing Electrochemical Activity
Characterization and Comparative Study of Energy Efficient Mechanochemically Induced NASICON Sodium Solid Electrolyte Synthesis
In recent years, there is growing interest in solid-state electrolytes due to their many promising properties, making them key to the future of battery technology. This future depends among other things on easy processing technologies for the solid electrolyte. The sodium superionic conductor (NASICON) Na3Zr2Si2PO12 is a promising sodium solid electrolyte; however, reported methods of synthesis are time consuming. To this effect, attempt was made to develop a simple time efficient alternative processing route. Firstly, a comparative study between a new method and commonly reported methods was carried out to gain a clear insight into the mechanism of formation of sodium superionic conductors (NASICON). It was observed that through a careful selection of precursors, and the use of high-energy milling (HEM) the NASICON conversion process was enhanced and optimized, this reduces the processing time and required energy, opening up a new alternative route for synthesis. The obtained solid electrolyte was stable during Na cycling vs. Na-metal at 1 mA cm−1, and a room temperature conductivity of 1.8 mS cm−1 was attained
Garnet to hydrogarnet: effect of post synthesis treatment on cation substituted LLZO solid electrolyte and its effect on Li ion conductivity
We investigated why commercial LiLaZrO (LLZO) with Nb- and Ta substitution shows very low mobility on a local scale, as observed with temperature-dependent NMR techniques, compared to Al and W substituted samples, although impedance spectroscopy on sintered pellets suggests something else: conductivity values do not show a strong dependence on the type of substituting cation. We observed that mechanical treatment of these materials causes a symmetry reduction from garnet to hydrogarnet structure. To understand the impact of this lower symmetric structure in detail and its effect on the Li ion conductivity, neutron powder diffraction and Li NMR were utilized. Despite the finding that, in some materials, disorder can be beneficial with respect to ionic conductivity, pulsed-field gradient NMR measurements of the long-range transport indicate a higher Li diffusion barrier in the lower symmetric hydrogarnet structure. The symmetry reduction can be reversed back to the higher symmetric garnet structure by annealing at 1100 °C. This unintended phase transition and thus a reduction in conductivity is crucial for the processing of LLZO materials in the fabrication of all-solid state batteries
Probing thermally-induced structural evolution during the synthesis of layered Li-, Na-, or K-containing 3d transition-metal oxides
Layered alkali-containing 3d transition-metal oxides are of the utmost importance in the use of electrode materials for advanced energy storage applications such as Li-, Na-, or K-ion batteries. A significant challenge in the field of materials chemistry is understanding the dynamics of the chemical reactions between alkali-free precursors and alkali species during the synthesis of these compounds. In this study, in situ high-resolution synchrotron-based X-ray diffraction was applied to reveal the Li/Na/K-ion insertion-induced structural transformation mechanism during high-temperature solid-state reaction. The in situ diffraction results demonstrate that the chemical reaction pathway strongly depends on the alkali-free precursor type, which is a structural matrix enabling phase transitions. Quantitative phase analysis identifies for the first time the decomposition of lithium sources as the most critical factor for the formation of metastable intermediates or impurities during the entire process of Li-rich layered Li[Li0.2Ni0.2Mn0.6]O2 formation. Since the alkali ions have different ionic radii, Na/K ions tend to be located on prismatic sites in the defective layered structure (Na2/3-x[Ni0.25Mn0.75]O2 or K2/3-x[Ni0.25Mn0.75]O2) during calcination, whereas the Li ions prefer to be localized on the tetrahedral and/or octahedral sites, forming O-type structures
Synthesis and Characterization of a Multication Doped Mn Spinel, LiNiCuFeMnO, as 5 V Positive Electrode Material
The suitability of multication doping to stabilize the disordered Fd3̅m structure in a spinel is reported here. In this work, LiNiCuFeMnO was synthesized via a sol–gel route at a calcination temperature of 850 °C. LiNiCuFeMnO is evaluated as positive electrode material in a voltage range between 3.5 and 5.3 V (vs Li/Li) with an initial specific discharge capacity of 126 mAh g at a rate of C/2. This material shows good cycling stability with a capacity retention of 89% after 200 cycles and an excellent rate capability with the discharge capacity reaching 78 mAh g at a rate of 20C. In operando X-ray diffraction (XRD) measurements with a laboratory X-ray source between 3.5 and 5.3 V at a rate of C/10 reveal that the (de)lithiation occurs via a solid-solution mechanism where a local variation of lithium content is observed. A simplified estimation based on the in operando XRD analysis suggests that around 17–31 mAh g of discharge capacity in the first cycle is used for a reductive parasitic reaction, hindering a full lithiation of the positive electrode at the end of the first discharge
High‐Voltage Aqueous Mg‐Ion Batteries Enabled by Solvation Structure Reorganization
Herein, an eco-friendly and high safety aqueous Mg-ion electrolyte (AME) with a wide electrochemical stability window (ESW) 3.7 V, containing polyethylene glycol (PEG) and low-concentration salt (0.8 m Mg(TFSI)), is proposed by solvation structure reorganization of AME. The PEG agent significantly alters the Mg solvation and hydrogen bonds network of AMEs and forms the direct coordination of Mg and TFSI-, thus enhancing the physicochemical and electrochemical properties of electrolytes. As an exemplary material, VO nanowires are tested in this new AME and exhibit initial high discharge/charge capacity of 359/326 mAh g and high capacity retention of 80% after 100 cycles. The high crystalline -VO shows two 2-phase transition processes with the formation of -MgVO and Mg-rich MgVO (x 1.0) during the first discharge. Mg-rich MgVO (x 1.0) phase formed through electrochemical Mg-ion intercalation at room temperature is for the first time observed via XRD. Meanwhile, the cathode electrolyte interphase (CEI) in aqueous Mg-ion batteries is revealed for the first time. MgF originating from the decomposition of TFSI- is identified as the dominant component. This work offers a new approach for designing high-safety, low-cost, eco-friendly, and large ESW electrolytes for practical and novel aqueous multivalent batteries
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