What Workers Say: Employee Voice in the Anglo-American Workplace

[Excerpt] This book is about employee voice in the workplaces of the highly developed Anglo-American economies: the United States, Canada, the United Kingdom, Ireland, Australia, and New Zealand. These are among the most economically successful countries in the world. Despite being located in three different geographic areas, the Anglo-American countries have a common language and legal tradition, have close economic and political ties, and are linked by flows of people, goods, and capital. Many of the same firms operate in each country. The unions in each pay more attention to their counterparts within the group than to unions in other countries. The Anglo-American brand of capitalism – market oriented and open to competition, with modest welfare sates and income transfer systems – differentiates the countries from countries in the “social dialogue” model of the European Union (although the United Kingdom and Ireland are part of the Union) and from the highly unionized labor system in Scandinavia

The effect of forcing on the spatial structure and spectra of chaotically advected passive scalars

The stationary distribution of passive tracers chaotically advected by a two-dimensional large-scale flow is investigated. The tracer field is force by resetting the value of the tracer in certain localised regions. This problem is mathematically equivalent to advection in open flows and results in a fractal tracer structure. The spectral exponent of the tracer field is different from that for a passive tracer with the usual additive forcing (the so called Batchelor spectrum) and is related to the fractal dimension of the set of points that have never visited the forcing regions. We illustrate this behaviour by considering a time-periodic flow whose effect is equivalent to a simple two-dimensional area-preserving map. We also show that similar structure in the tracer field is found when the flow is aperiodic in time.Comment: 7 pages, 9 figure

Factors influencing the distribution of charge in polar nanocrystals

We perform first-principles calculations of wurtzite GaAs nanorods to explore the factors determining charge distributions in polar nanostructures. We show that both the direction and magnitude of the dipole moment $\mathbf{d}$ of a nanorod, and its electic field, depend sensitively on how its surfaces are terminated and do not depend strongly on the spontaneous polarization of the underlying lattice. We identify two physical mechanisms by which $\mathbf{d}$ is controlled by the surface termination, and we show that the excess charge on the nanorod ends is not strongly localized. We discuss the implications of these results for tuning nanocrystal properties, and for their growth and assembly.Comment: Accepted for publication in Phys. Rev. B Rapid Communication

Accurate ionic forces and geometry optimization in linear-scaling density-functional theory with local orbitals

Linear scaling methods for density-functional theory (DFT) simulations are formulated in terms of localized orbitals in real space, rather than the delocalized eigenstates of conventional approaches. In local-orbital methods, relative to conventional DFT, desirable properties can be lost to some extent, such as the translational invariance of the total energy of a system with respect to small displacements and the smoothness of the potential-energy surface. This has repercussions for calculating accurate ionic forces and geometries. In this work we present results from onetep, our linear scaling method based on localized orbitals in real space. The use of psinc functions for the underlying basis set and on-the-fly optimization of the localized orbitals results in smooth potential-energy surfaces that are consistent with ionic forces calculated using the Hellmann-Feynman theorem. This enables accurate geometry optimization to be performed. Results for surface reconstructions in silicon are presented, along with three example systems demonstrating the performance of a quasi-Newton geometry optimization algorithm: an organic zwitterion, a point defect in an ionic crystal, and a semiconductor nanostructure.<br/

Diffusion of passive scalar in a finite-scale random flow

We consider a solvable model of the decay of scalar variance in a single-scale random velocity field. We show that if there is a separation between the flow scale k_flow^{-1} and the box size k_box^{-1}, the decay rate lambda ~ (k_box/k_flow)^2 is determined by the turbulent diffusion of the box-scale mode. Exponential decay at the rate lambda is preceded by a transient powerlike decay (the total scalar variance ~ t^{-5/2} if the Corrsin invariant is zero, t^{-3/2} otherwise) that lasts a time t~1/\lambda. Spectra are sharply peaked at k=k_box. The box-scale peak acts as a slowly decaying source to a secondary peak at the flow scale. The variance spectrum at scales intermediate between the two peaks (k_box0). The mixing of the flow-scale modes by the random flow produces, for the case of large Peclet number, a k^{-1+delta} spectrum at k>>k_flow, where delta ~ lambda is a small correction. Our solution thus elucidates the spectral make up of the ``strange mode,'' combining small-scale structure and a decay law set by the largest scales.Comment: revtex4, 8 pages, 4 figures; final published versio

Density-functional investigation of the rhombohedral to simple cubic phase transition of arsenic

We report on our investigation of the crystal structure of arsenic under compression, focusing primarily on the pressure-induced A7 to simple cubic (sc) phase transition. The two-atom rhombohedral unit cell is subjected to pressures ranging from 0 GPa to 200 GPa; for each given pressure, cell lengths and angles, as well as atomic positions, are allowed to vary until the fully relaxed structure is obtained. We find that the nearest and next-nearest neighbor distances give the clearest indication of the occurrence of a structural phase transition. Calculations are performed using the local density approximation (LDA) and the PBE and PW91 generalized gradient approximations (GGA-PBE and GGA-PW91) for the exchange-correlation functional. The A7 to sc transition is found to occur at 21+/-1 GPa in the LDA, at 28+/-1 GPa in the GGA-PBE and at 29+/-1 GPa in the GGA-PW91; no volume discontinuity is observed across the transition in any of the three cases. We use k-point grids as dense as 66X66X66 to enable us to present reliably converged results for the A7 to sc transition of arsenic.Comment: To be published in Physical Review B; material supplementary to this article is available at arXiv:0810.169