Rational design for thermochromic luminescence in amorphous polystyrene films with bis-o-carborane-substituted enhanced conjugated molecule having aggregation-induced luminochromism

We designed the triad molecule, bis-o-carborane-substituted bis(thienylethynyl)benzene, as a filler for realizing thermochromic luminescent behaviors based on conventional polymer films, such as polystyrene. From the optical measurements, it was found that the triad can show solid-state emission and dual-luminescent properties with variable intensity ratios depending on media. From the mechanistic studies including the experiments with the methyl-substituted model compound, it was revealed that dual emission should be originated from the locally excited and twisted intramolecular charge transfer states, and the latter emission band is significantly enhanced in the solid states. We prepared amorphous films containing variable concentrations of the triad with the spin-coating method and investigated optical properties. It was found that intensity ratios were drastically changed by altering the concentration of the triad. By increasing the proportion of the triad, aggregation occurred, and emission color was apparently varied through the changes in intensity ratios of the dual emission property. Based on the aggregation-induced luminochromic property of the triad, thermochromic luminescence was finally realized by heating the amorphous films. The rational design for obtaining thermochromic luminescent amorphous films is illustrated in this paper

マウス神経発生における低分子量Gタンパク質Arl8bの機能解析

学位の種別: 課程博士審査委員会委員 : （主査）東京大学教授 堅田 利明, 東京大学教授 一條 秀憲, 東京大学教授 村田 茂穂, 東京大学教授 秋光 信佳, 東京大学特任准教授 田口 友彦University of Tokyo(東京大学

Delayed healing at free ALT donor site

Background The free anterolateral thigh (ALT) flap has been widely used for various kinds of reconstructions. However, delayed healing at the donor site occasionally occurs due to wound dehiscence or the partial loss of grafted skin at the donor site. The aim of the present study was to identify reliable predictive factors for delayed healing at the donor site after the harvest of a free ALT flap. Methods This study included 52 patients who underwent reconstructive procedures using free ALT flaps. The delayed healing group included patients with wounds at the donor site that had not healed over 3 weeks after surgery, and the normal healing group included patients who showed wound healing within 3 weeks after surgery. Multivariate logistic regression models were created to identify the risk factors for delayed healing at the ALT flap donor site. Results Among the 52 patients, 24 (46.2%) showed delayed healing at the donor site, and 6 patients required additional operative treatment. A high preoperative body mass index (BMI), smoking, and skin grafting were found to be significantly associated with delayed healing at the ALT donor site. Of the 37 patients who underwent skin grafting, 23 (62%) experienced delayed healing at the donor site. Conclusions A high preoperative BMI, smoking, and skin grafting were risk factors for delayed healing at the free ALT donor site. Skin grafting at the ALT donor site should be avoided in patients with a high BMI or a habit of smoking

Localized turbulence structures in transitional rectangular-duct flow

Direct numerical simulations of transitional flow in a rectangular duct of cross-sectional aspect ratio A≡s/h=1–9 (s and h being the duct half-span and half-height, respectively) have been performed in the Reynolds number range Re≡ubh/ν=650–1500 (ub and ν being the bulk velocity and the kinematic viscosity, respectively) in order to investigate the dependence on the aspect ratio of spatially localized turbulence structures. It was observed that the lowest Reynolds number ReT, estimated in a specific way, for localized (transiently sustaining) turbulence decreases monotonically from ReT=730 for A=1 (square duct) with increasing aspect ratio, and for A=5 it nearly attains a minimal value ReT≈670 that is consistent with the onset Reynolds number of turbulent spots in a plane channel (A=∞). Turbulent states consist of localized structures that undergo a fundamental change around A=4. At Re=ReT turbulence for A=1–3 is streamwise-localized similar to turbulent puffs in pipe flow, while for A=5–9 turbulence at Re=ReT is also localized in the spanwise direction, similar to turbulent spots in plane channel flow. This structural change in turbulent states at Re=ReT is attributed to the exclusion of turbulence from the vicinity of the duct sidewalls in the case of a wide duct with A≳4: here the friction length on the sidewalls is so long that the size (around 100 times the friction length) of a self-sustaining minimal flow unit of streamwise vortices and streaks is larger than the duct height and, therefore, it cannot be accommodated

Statistical Mechanics of Vortices from D-branes and T-duality

We propose a novel and simple method to compute the partition function of statistical mechanics of local and semi-local BPS vortices in the Abelian-Higgs model and its non-Abelian extension on a torus. We use a D-brane realization of the vortices and T-duality relation to domain walls. We there use a special limit where domain walls reduce to gas of hard (soft) one-dimensional rods for Abelian (non-Abelian) cases. In the simpler cases of the Abelian-Higgs model on a torus, our results agree with exact results which are geometrically derived by an explicit integration over the moduli space of vortices. The equation of state for U(N) gauge theory deviates from van der Waals one, and the second virial coefficient is proportional to 1/sqrt{N}, implying that non-Abelian vortices are "softer" than Abelian vortices. Vortices on a sphere are also briefly discussed.Comment: 20 pages, 18 figure