Physical Properties of Metallic Antiferromagnetic CaCo{1.86}As2 Single Crystals

We report studies of CaCo{1.86}As2 single crystals. The electronic structure is probed by angle-resolved photoemission spectroscopy (ARPES) measurements of CaCo{1.86}As2 and by full-potential linearized augmented-plane-wave calculations for the supercell Ca8Co15As16 (CaCo{1.88}As2). Our XRD crystal structure refinement is consistent with the previous combined refinement of x-ray and neutron powder diffraction data showing a collapsed-tetragonal ThCr2Si2-type structure with 7(1)% vacancies on the Co sites corresponding to the composition CaCo{1.86}As2 [D. G. Quirinale et al., Phys. Rev. B 88, 174420 (2013)]. The anisotropic magnetic susceptibility chi(T) data are consistent with the magnetic neutron diffraction data of Quirianale et al. that demonstrate the presence of A-type collinear antiferromagnetic order below the Neel temperature TN = 52(1) K with the easy axis being the tetragonal c axis. However, no clear evidence from the resistivity rho(T) and heat capacity Cp(T) data for a magnetic transition at TN is observed. A metallic ground state is demonstrated from band calculations and the rho(T), Cp(T) and ARPES data, and spin-polarized calculations indicate a competition between the A-type AFM and FM ground states. The Cp(T) data exhibit a large Sommerfield electronic coefficient reflecting a large density of states at the Fermi energy D(EF), consistent with the band structure calculations which also indicate a large D(EF) arising from Co 3d bands. At 1.8 K the M(H) data for H|| c exhibit a well-defined first-order spin-flop transition at an applied field of 3.5 T. The small ordered moment of 0.3 muB/Co obtained from the M(H) data at low T, the large exchange enhancement of chi and the lack of a self-consistent interpretation of the chi(T) and M(H,T) data in terms of a local moment Heisenberg model together indicate that the magnetism of CaCo{1.86}As2 is itinerant.Comment: 18 pages, 15 figures, 4 tables, 61 references; v2: extended the fits of experimental data by additional electronic structure calculations; published versio

The Burst and Transient Source Experiment Earth Occultation Technique

An Earth orbiting detector sensitive to gamma ray photons will see step-like occultation features in its counting rate when a gamma ray point source crosses the Earth's limb. This is due to the change in atmospheric attenuation of the gamma rays along the line of sight. In an uncollimated detector, these occultation features can be used to locate and monitor astrophysical sources provided their signals can be individually separated from the detector background. We show that the Earth occultation technique applied to the Burst and Transient Source Experiment (BATSE) on the Compton Gamma Ray Observatory (CGRO) is a viable and flexible all-sky monitor in the low energy gamma ray and hard X-ray energy range (20 keV - 1 MeV). The method is an alternative to more sophisticated photon imaging devices for astronomy, and can serve well as a cost-effective science capability for monitoring the high energy sky. Here we describe the Earth occultation technique for locating new sources and for measuring source intensity and spectra without the use of complex background models. Examples of transform imaging, step searches, spectra, and light curves are presented. Systematic uncertainties due to source confusion, detector response, and contamination from rapid background fluctuations are discussed and analyzed for their effect on intensity measurements. A sky location-dependent average systematic error is derived as a function of galactic coordinates. The sensitivity of the technique is derived as a function of incident photon energy and also as a function of angle between the source and the normal to the detector entrance window. Occultations of the Crab Nebula by the Moon are used to calibrate Earth occultation flux measurements independent of possible atmospheric scattering effects.Comment: 39 pages, 24 figures. Accepted for publication in the Astrophysical Journal Supplement

Review of top of rail friction modifier tribology

© 2016 Informa UK Limited, trading as Taylor & Francis Group.The aim of this paper was to review the current state of research for top of rail friction modifiers (TORFM). In the railway industry, friction modifiers is a catch all term for a wide range of products applied for different purposes which has led to confusion. It is hoped that recently published definitions will aid industry to a better understanding of the different products and how they function. The benefits of friction modifiers are well understood with a large body of research supporting the benefits. Comparatively, there is a lot less knowledge of the optimum amount of product to achieve the benefits or how far down the track from an application site the benefit will be seen. Modelling of the products is another area where there is little research, with most of the modelling papers found focussing on dry wheel–rail contact due to the complexity of introducing a third-body layer to a friction force model. Furthermore, only one paper was found which relates how friction modifiers are affected by contaminants or other applied products such as lubricants. With many different products applied to wheels and rail for different purposes, understanding their interaction is key. At the time of this review, there are currently no standards that prescribe how TORFM should behave although the European Committee for Standardisation is currently developing them at the moment. This review has also attempted to appraise the research against a set of criteria. Depending on how many of the criteria the piece of research filled, it was categorised as A, B or C. It was found that most of the research was of category, this was mainly due to only one test method being used or the scale presented. Category A research incorporated modelling or multiple test-scales to support the results presented

Mechanisms of decoherence in weakly anisotropic molecular magnets

Decoherence mechanisms in crystals of weakly anisotropic magnetic molecules, such as V15, are studied. We show that an important decohering factor is the rapid thermal fluctuation of dipolar interactions between magnetic molecules. A model is proposed to describe the influence of this source of decoherence. Based on the exact solution of this model, we show that at relatively high temperatures, about 0.5 K, the quantum coherence in a V15 molecule is not suppressed, and, in principle, can be detected experimentally. Therefore, these molecules may be suitable prototype systems for study of physical processes taking place in quantum computers.Comment: 4 pages RevTeX, 1 figure (PostScript

Ba{1-x}KxMn2As2: An Antiferromagnetic Local-Moment Metal

The compound BaMn2As2 with the tetragonal ThCr2Si2 structure is a local-moment antiferromagnetic insulator with a Neel temperature TN = 625 K and a large ordered moment mu = 3.9 mu_B/Mn. We demonstrate that this compound can be driven metallic by partial substitution of Ba by K, while retaining the same crystal and antiferromagnetic structures together with nearly the same high TN and large mu. Ba_{1-x}K_xMn2As2 is thus the first metallic ThCr2Si2-type MAs-based system containing local 3d transition metal M magnetic moments, with consequences for the ongoing debate about the local moment versus itinerant pictures of the FeAs-based superconductors and parent compounds. The Ba_{1-x}K_xMn2As2 class of compounds also forms a bridge between the layered iron pnictides and cuprates and may be useful to test theories of high Tc superconductivity.Comment: 5 two-column typeset pages, 5 figures, 20 references; v2: minor revisions, 4 new references, published versio

The X-ray Cluster Dipole

We estimate the dipole of the whole sky X-ray flux-limited sample of Abell/ACO clusters (XBACs) and compare it to the optical Abell/ACO cluster dipole. The X-ray cluster dipole is well aligned ($\le 25^{\circ}$) with the CMB dipole, while it follows closely the radial profile of its optical cluster counterpart although its amplitude is $\sim 10 - 30$ per cent lower. In view of the fact that the the XBACs sample is not affected by the volume incompleteness and the projection effects that are known to exist at some level in the optical parent Abell/ACO cluster catalogue, our present results confirm the previous optical cluster dipole analysis that there are significant contributions to the Local Group motion from large distances ($\sim 160h^{-1}$Mpc). In order to assess the expected contribution to the X-ray cluster dipole from a purely X-ray selected sample we compare the dipoles of the XBACs and the Brightest Cluster Sample (Ebeling et al. 1997a) in their overlap region. The resulting dipoles are in mutual good aggreement with an indication that the XBACs sample slightly underestimates the full X-ray dipole (by $\le 5$ per cent) while the Virgo cluster contributes about 10 - 15 per cent to the overall X-ray cluster dipole. Using linear perturbation theory to relate the X-ray cluster dipole to the Local group peculiar velocity we estimate the density parameter to be $\beta_{c_{x}} \simeq 0.24 \pm 0.05$.Comment: 16 pages, latex, + 4 ps figures, submitted to Ap