In Situ Growth Dynamics of Uniform Bilayer Graphene with Different Twisted Angles Following Layer-by-Layer Mode

Synthesis of large-area uniform bilayer graphene (BLG) with different twisted angles has gathered extensive interest but remains a challenge, hindered by the ubiquitous layer-plus-island growth and the uncontrollable layer rotation. Herein, using real-time surface imaging, film uniformity and stacking structures in BLG were well controlled by a two-step carbon segregation on Ni(111) films following the layer-by-layer growth mode. The aligned first graphene layers formed at 850 °C through a thermodynamics-limit process, followed by decreasing temperatures to grow the second layers, eventually enabling the extremely uniform 15°-twisted BLG at 790 °C and AB-stacked BLG at 720 °C, respectively. Essentially, the growth dynamics is perceived to determine that for the different stacking structures, nonaligned second layers are more kinetically preferable than aligned ones at relatively high temperatures, but the case reverses at low temperatures. This work conveys a fundamental dynamic understanding of the controllable integration of uniform BLG and tuning stacking structures

In Situ Growth Dynamics of Uniform Bilayer Graphene with Different Twisted Angles Following Layer-by-Layer Mode

Synthesis of large-area uniform bilayer graphene (BLG) with different twisted angles has gathered extensive interest but remains a challenge, hindered by the ubiquitous layer-plus-island growth and the uncontrollable layer rotation. Herein, using real-time surface imaging, film uniformity and stacking structures in BLG were well controlled by a two-step carbon segregation on Ni(111) films following the layer-by-layer growth mode. The aligned first graphene layers formed at 850 °C through a thermodynamics-limit process, followed by decreasing temperatures to grow the second layers, eventually enabling the extremely uniform 15°-twisted BLG at 790 °C and AB-stacked BLG at 720 °C, respectively. Essentially, the growth dynamics is perceived to determine that for the different stacking structures, nonaligned second layers are more kinetically preferable than aligned ones at relatively high temperatures, but the case reverses at low temperatures. This work conveys a fundamental dynamic understanding of the controllable integration of uniform BLG and tuning stacking structures

In Situ Growth Dynamics of Uniform Bilayer Graphene with Different Twisted Angles Following Layer-by-Layer Mode

Synthesis of large-area uniform bilayer graphene (BLG) with different twisted angles has gathered extensive interest but remains a challenge, hindered by the ubiquitous layer-plus-island growth and the uncontrollable layer rotation. Herein, using real-time surface imaging, film uniformity and stacking structures in BLG were well controlled by a two-step carbon segregation on Ni(111) films following the layer-by-layer growth mode. The aligned first graphene layers formed at 850 °C through a thermodynamics-limit process, followed by decreasing temperatures to grow the second layers, eventually enabling the extremely uniform 15°-twisted BLG at 790 °C and AB-stacked BLG at 720 °C, respectively. Essentially, the growth dynamics is perceived to determine that for the different stacking structures, nonaligned second layers are more kinetically preferable than aligned ones at relatively high temperatures, but the case reverses at low temperatures. This work conveys a fundamental dynamic understanding of the controllable integration of uniform BLG and tuning stacking structures

In Situ Growth Dynamics of Uniform Bilayer Graphene with Different Twisted Angles Following Layer-by-Layer Mode

Synthesis of large-area uniform bilayer graphene (BLG) with different twisted angles has gathered extensive interest but remains a challenge, hindered by the ubiquitous layer-plus-island growth and the uncontrollable layer rotation. Herein, using real-time surface imaging, film uniformity and stacking structures in BLG were well controlled by a two-step carbon segregation on Ni(111) films following the layer-by-layer growth mode. The aligned first graphene layers formed at 850 °C through a thermodynamics-limit process, followed by decreasing temperatures to grow the second layers, eventually enabling the extremely uniform 15°-twisted BLG at 790 °C and AB-stacked BLG at 720 °C, respectively. Essentially, the growth dynamics is perceived to determine that for the different stacking structures, nonaligned second layers are more kinetically preferable than aligned ones at relatively high temperatures, but the case reverses at low temperatures. This work conveys a fundamental dynamic understanding of the controllable integration of uniform BLG and tuning stacking structures

In Situ Growth Dynamics of Uniform Bilayer Graphene with Different Twisted Angles Following Layer-by-Layer Mode

Synthesis of large-area uniform bilayer graphene (BLG) with different twisted angles has gathered extensive interest but remains a challenge, hindered by the ubiquitous layer-plus-island growth and the uncontrollable layer rotation. Herein, using real-time surface imaging, film uniformity and stacking structures in BLG were well controlled by a two-step carbon segregation on Ni(111) films following the layer-by-layer growth mode. The aligned first graphene layers formed at 850 °C through a thermodynamics-limit process, followed by decreasing temperatures to grow the second layers, eventually enabling the extremely uniform 15°-twisted BLG at 790 °C and AB-stacked BLG at 720 °C, respectively. Essentially, the growth dynamics is perceived to determine that for the different stacking structures, nonaligned second layers are more kinetically preferable than aligned ones at relatively high temperatures, but the case reverses at low temperatures. This work conveys a fundamental dynamic understanding of the controllable integration of uniform BLG and tuning stacking structures

In Situ Growth Dynamics of Uniform Bilayer Graphene with Different Twisted Angles Following Layer-by-Layer Mode

Synthesis of large-area uniform bilayer graphene (BLG) with different twisted angles has gathered extensive interest but remains a challenge, hindered by the ubiquitous layer-plus-island growth and the uncontrollable layer rotation. Herein, using real-time surface imaging, film uniformity and stacking structures in BLG were well controlled by a two-step carbon segregation on Ni(111) films following the layer-by-layer growth mode. The aligned first graphene layers formed at 850 °C through a thermodynamics-limit process, followed by decreasing temperatures to grow the second layers, eventually enabling the extremely uniform 15°-twisted BLG at 790 °C and AB-stacked BLG at 720 °C, respectively. Essentially, the growth dynamics is perceived to determine that for the different stacking structures, nonaligned second layers are more kinetically preferable than aligned ones at relatively high temperatures, but the case reverses at low temperatures. This work conveys a fundamental dynamic understanding of the controllable integration of uniform BLG and tuning stacking structures

Creating a Nanospace under an h‑BN Cover for Adlayer Growth on Nickel(111)

Heterostructures of two-dimensional (2D) atomic crystals have attracted increasing attention, while fabrication of the 2D stacking structures remains a challenge. In this work, we present a route toward formation of 2D heterostructures <i>via</i> confined growth of a 2D adlayer underneath the other 2D overlayer. Taking a hexagonal boron nitride (h-BN) monolayer on Ni(111) as a model system, both epitaxial and nonepitaxial h-BN islands have been identified on the Ni surface. Surface science studies combined with density functional theory calculations reveal that the nonepitaxial h-BN islands interact weakly with the Ni(111) surface, which creates a 2D nanospace underneath the h-BN islands. An additional h-BN or graphene layer can be grown in the space between the nonepitaxial h-BN islands and Ni(111) surface, forming h-BN/h-BN bilayer structures and h-BN/graphene heterostructures. These results suggest that confined growth under 2D covers may provide an effective route to obtain stacks of 2D atomic crystals

Electroreduction of CO₂ in a Non-aqueous ElectrolyteThe Generic Role of Acetonitrile

Transition metal carbides, especially Mo2C, are praised to be efficient electrocatalysts to reduce CO2 to valuable hydrocarbons. However, on Mo2C in an aqueous electrolyte, exclusively the competing hydrogen evolution reaction takes place, and this discrepancy to theory was traced back to the formation of a thin oxide layer at the electrode surface. Here, we study the CO2 reduction activity at Mo2C in a non-aqueous electrolyte to avoid such passivation and to determine products and the CO2 reduction reaction pathway. We find a tendency of CO2 to reduce to carbon monoxide. This process is inevitably coupled with the decomposition of acetonitrile to a 3-aminocrotonitrile anion. Furthermore, a unique behavior of the non-aqueous acetonitrile electrolyte is found, where the electrolyte, instead of the electrocatalyst, governs the catalytic selectivity of the CO2 reduction. This is evidenced by in situ electrochemical infrared spectroscopy on different electrocatalysts as well as by density functional theory calculations

RIP3 depletion ameliorated lung injury and improved survival rate in LPS-induced ARDS in mice.

<p>(A-B) Pathological changes of lung tissues as determined by H&E staining (200×, n = 5). (C) Body temperature of LPS treated RIP3-WT and RIP3-KO mice (n = 10~16). (D) Survival rate of LPS treated RIP3-WT and RIP3-KO mice (n = 20). RIP3-WT and RIP3-KO mice were both divided into control and LPS groups, respectively. The LPS group mice were instilled with 30 mg/kg LPS, while the control group mice were instilled with PBS. The mice were sacrificed 24 h after LPS instillation. The data are presented as mean±s.e.m; **P<0.01 versus the respective control group; &P<0.05 versus the LPS treated RIP3-WT group.</p

RIP3 depletion reduced the necrotic cells in the lung and decreased the expression of MLKL, but had no impact on cleaved caspase-3 in LPS-induced ARDS.

<p>(A) The number of necrotic cells as determined by PI staining (100×). Frozen sections were stained with propidium iodide (PI, red) and nuclear stain (DAPI, blue). The cells were counted by the Cell^P imaging software. (B) MLKL expression as detected by western blotting. (C) Cleaved caspase-3 expression as detected by western blotting. RIP3-WT and RIP3-KO mice were divided into control and LPS groups, respectively. The LPS group mice were instilled with 30 mg/kg LPS, while the control group mice were instilled with PBS. The mice were sacrificed 24 h after LPS instillation. The data are presented as mean±s.e.m; (n = 10). **P<0.01 versus the respective control group; ^&P<0.05 versus the LPS treated RIP3-WT group.</p