Sharp Transition between Coalescence and Noncoalescence of Sessile Drops

Unexpectedly, under certain conditions, sessile drops from different but completely miscible liquids do not always coalesce instantaneously upon contact: the drop bodies remain separated in a temporary state of noncoalescence, connected through a thin liquid bridge. Here we investigate the transition between the states of instantaneous coalescence and temporary noncoalescence. Experiments reveal that it is barely influenced by viscosities and absolute surface tensions. The main system control parameters for the transition are the arithmetic means of the three-phase angles, $\overline{\Theta}_a$ and the surface tension differences $\Delta\gamma$ between both liquids. These relevant parameters can be combined into a single system parameter, a speciffic Marangoni number $\widetilde{M} = 3\Delta\gamma / (2\overline{\gamma}\overline{\Theta}_a^2)$. This $\widetilde{M}$ universally characterizes the coalescence respectively transition behavior as a function of both, the physicochemical liquid properties and the shape of the liquid body in the contact region. The transition occurs at a certain threshold value $\widetilde{M}_t$ and is sharp within the experimental resolution. The experimentally observed threshold value of $\widetilde{M}_t \approx 2$ agrees quantitatively with values obtained by simulations assuming authentic real space data. The simulations indicate that the absolute value of $\widetilde{M}_t$ very weakly depends on the molecular diffusivity.Comment: 9 pages, 6 figure

Non-coalescence of sessile drops from different but miscible liquids: Hydrodynamic analysis of the twin drop contour as self stabilizing, traveling wave

Capillarity always favors drop fusion. Nevertheless sessile drops from different but completely miscible liquids often do not fuse instantaneously upon contact. Rather, intermediate non-coalescence is observed. Two separate drop bodies, connected by a thin liquid neck move over the substrate. Supported by new experimental data a thin film hydrodynamic analysis of this state is presented. Presumably advective and diffusive volume fluxes in the neck region establish a localized and temporarily stable surface tension gradient. This induces a local surface (Marangoni) flow that stabilizes a traveling wave i.e., the observed moving twin drop configuration. The theoretical predictions are in excellent agreement with the experimental findings.Comment: 5 pages, 5 figure

BRST Cohomology and Phase Space Reduction in Deformation Quantisation

In this article we consider quantum phase space reduction when zero is a regular value of the momentum map. By analogy with the classical case we define the BRST cohomology in the framework of deformation quantization. We compute the quantum BRST cohomology in terms of a `quantum' Chevalley-Eilenberg cohomology of the Lie algebra on the constraint surface. To prove this result, we construct an explicit chain homotopy, both in the classical and quantum case, which is constructed out of a prolongation of functions on the constraint surface. We have observed the phenomenon that the quantum BRST cohomology cannot always be used for quantum reduction, because generally its zero part is no longer a deformation of the space of all smooth functions on the reduced phase space. But in case the group action is `sufficiently nice', e.g. proper (which is the case for all compact Lie group actions), it is shown for a strongly invariant star product that the BRST procedure always induces a star product on the reduced phase space in a rather explicit and natural way. Simple examples and counter examples are discussed.Comment: LaTeX2e, 34 pages, revised version: minor changes and corrected typo