Mononitration of durene

Reaction conditions under which the nitration of durene give predominantly, and in high yield, mononitrodurene (I), rather than dinitrodurene were found. The nitrating agent was No2+RF6-. Nitration with nitrosulfuric acid also gave mononitrodurene; however, byproducts such as 2.3.5.6-Me4C6HCH2C6H2Me3-2,4,5, were also formed. The NO2 PF6- gave an intermediate additional compound with durene. The reaction carried out with 3.6-dideuterodurene in D2O shows no isotope effect

Illumination uniformity in endoscopic imaging

Standardised endoscopic digital images were taken and analysed using an image analysis software (National Instruments Vision Assistant version 7.1.1). The luminance plane was extracted and the pixel intensity distribution was determined along a horizontal line at the position of highest average intensity (centroid). The data was exported to MS Excel and the pixel intensity (y-axis) was plotted against pixel position (x-axis). A trendline using a 2nd order polynomial curve was fitted to each data set. The resultant equation for each curve was compared with equations obtained from other images taken under various illumination conditions and settings

Vortex lattices in the lowest Landau level for confined Bose-Einstein condensates

We present the results of numerical calculations of the groundstates of weakly-interacting Bose-Einstein condensates containing large numbers of vortices. Our calculations show that these groundstates appear to be close to uniform triangular vortex lattices. However, slight deviations from a uniform triangular lattice have dramatic consequences on the overall particle distribution. In particular, we demonstrate that the overall particle distribution averaged on a lengthscale large compared to the vortex lattice constant is well approximated by a Thomas-Fermi profile.Comment: 5 pages, 4 figure

Onset of Interlayer Phase Coherence in a Bilayer Two-Dimensional Electron System: Effect of Layer Density Imbalance

Tunneling and Coulomb drag are sensitive probes of spontaneous interlayer phase coherence in bilayer two-dimensional electron systems at total Landau level filling factor $\nu_T = 1$. We find that the phase boundary between the interlayer phase coherent state and the weakly-coupled compressible phase moves to larger layer separations as the electron density distribution in the bilayer is imbalanced. The critical layer separation increases quadratically with layer density difference.Comment: 4 pages, 3 figure