Outcome-driven Service Provider Performance under Conditions of Complexity and Uncertainty

Proceedings Paper (for Acquisition Research Program)This paper describes applying ROI analysis principles for SOA performance management, creating Service-level Agreements (SLAs) to articulate agreements between the Government and external service providers, and managing SLAs through a governance framework (Hanf & Buck, 2009, March). This white paper highlights key findings of research undertaken by The MITRE Corporation (MITRE) and the resulting recommendations for (1) applying Return-on-Investment (ROI) analysis principles as the foundation for more effective performance management of Government Service-oriented Architecture (SOA), (2) creating comprehensive Service-level Agreements (SLAs) to articulate agreements between the Government and external service providers, and (3) managing SLAs through a governance framework (Oakley-Bogdewic & Buck, 2009; Hanf & Buck, 2009, March 25). As illustrated in Figure 1, MITRE''s recommendations address the additional managerial complexity and uncertainty that SOA objectives and proposed solutions often create.Naval Postgraduate School Acquisition Research ProgramApproved for public release; distribution is unlimited

Regioselective 1,4-hydroboration of pyridines catalyzed by an acid-initiated boronium cation

The reaction of the commercially available ammonium salt NH4BPh4 with a pyridine-activated pinacolborane species generates a boronium cation that facilitates the 1,4-selective hydroboration of pyridines in polar solvents. This catalytic reaction is amenable to a host of reactive functional groups and provides access to sterically bulky hydroboration products, previously inaccessible by metal-free routes. Further, the regioselectivity of this reaction can be altered by reducing the polarity of the reaction solvent, resulting in greater proportions of the 1,2-hydroboration product.E. N. K. thanks NSERC of Canada for a PGSD as well as the Cambridge Commonwealth, European, and International Trust and Gonville and Caius College for funding

The influence of halides in polyoxotitanate cages; dipole moment, splitting and expansion of d-orbitals and electron-electron repulsion

Metal-doped polyoxotitanate (M-POT) cages have been shown to be efficient single-source precursors to metal-doped titania [TiO$_2$(M)] (state-of-the-art photocatalytic materials) as well as molecular models for the behaviour of dopant metal ions in bulk titania. Here we report the influence halide ions have on the optical and electronic properties of a series of halide-only, and cobalt halide-‘doped’ POT cages. In this combined experimental and computational study we show that halide ions can have several effects on the band gaps of halide-containing POT cages, influencing the dipole moment (hole–electron separation) and the structure of the valance band edge. Overall, the band gap behaviour stems from the effects of increasing orbital energy moving from F to I down Group 17, as well as crystal-field splitting of the d-orbitals, the potential effects of the Nephelauxetic influence of the halides and electron–electron repulsion.We thank the EPSRC (Doctoral Prize for P. D. M.), A*STAR Singapore (Scholarship for N. L.), the Studienstiftung des deutschen Volkes, Fonds of the Chemical Industry (S. H.) for funding. The authors would like to acknowledge the use of the EPSRC UK National Service for Computational Chemistry Software (NSCCS) at Imperial College London and contributions from its staff in carrying out this work

In Situ Characterisation of Permanent Magnetic Quadrupoles for focussing proton beams

High intensity laser driven proton beams are at present receiving much attention. The reasons for this are many but high on the list is the potential to produce compact accelerators. However two of the limitations of this technology is that unlike conventional nuclear RF accelerators lasers produce diverging beams with an exponential energy distribution. A number of different approaches have been attempted to monochromise these beams but it has become obvious that magnetic spectrometer technology developed over many years by nuclear physicists to transport and focus proton beams could play an important role for this purpose. This paper deals with the design and characterisation of a magnetic quadrupole system which will attempt to focus and transport laser-accelerated proton beams.Comment: 20 pages, 42 figure

Low energy expenditure and resting behaviour of humpback whale mother-calf pairs highlights conservation importance of sheltered breeding areas

Understanding the behaviour of humpback whale mother-calf pairs and the acoustic environment on their breeding grounds is fundamental to assessing the biological and ecological requirements needed to ensure a successful migration and survival of calves. Therefore, on a breeding/resting ground, Exmouth Gulf, Western Australia, we used animal-borne DTAGs to quantify the fine-scale behaviour and energetic expenditure of humpback whale mothers and calves, while sound recorders measured the acoustic environment. We show that: (i) lactating humpback whales keep their energy expenditure low by devoting a significant amount of time to rest, and their use of energy, inferred from respiration rates, is ~half than that of adults on their foraging grounds; (ii) lactating females mainly rest while stationary at shallow depths within reach of the hull of commercial ships, thus increasing the potential for ship strike collisions; (iii) the soundscape is dominated by biological sources; and (iv) even moderate increases of noise from vessels will decrease the communication range of humpback whales. Planned commercial infrastructure in Exmouth Gulf will cause a substantial increase in shipping traffic with the risk of ship strikes and acoustic disturbance potentially compromising energy reserves for the southern migration of humpback whales

Benefits of a marketing cooperative in transition agriculture: Mórakert purchasing and service co-operative

The paper analyses the potential benefits of marketing cooperatives in Hungary, employing a transaction cost economics framework. We found that the purchased quantity, the existence of contracts, flexibility and trust are the most important factors farmers consider when selling their products via a cooperative. The most striking result is that diversification has positive influences on the share of cooperatives in farmers’ sale. Furthermore, farmers with larger bargaining power have less willingness to sell their product to the cooperative. Surprisingly, asset specificity has rather negative effects on the share of cooperatives in members’ sales

An experimental and theoretical study of the coordination and donor properties of tris-2-pyridyl-phosphine ligands

Producción CientíficaThe coordination characteristics and donor/acceptor properties of a series of 2-pyridyl substituted phosphine ligands have been investigated using structural, spectroscopic and DFT calculational studies. A range of different coordination modes are observed in Mo and W carbonyl complexes of tris-2-pyridyl-phosphine ligands of the type P(2-py’) (2-py’ = substituted or unsubstituted 2-pyridyl group), including an unprecedented example exhibiting N,N′,μ2-π coordination. DFT calculations were used to assess the relative donor/acceptor properties of a range of related 2-pyridyl-phosphine ligands with respect to PPh3 and PtBu3.Ministerio de Ciencia, Innovación y Universidades (PGC2018-096880-A-I00. AEI / FEDER, UE

A non-chiral lithium aluminate reagent for the determination of enantiomeric excess of chiral alcohols

Here we illustrate a new method for the rapid determination of ee’s of chiral alcohols using the thermally-stable, non-chiral lithium aluminate reagent [EtAl(6-Me-2-py)$_3$Li] (1). $\textit{In situ}$ reaction of the alcohols with 1 produces robust dimers in solution, present as diastereomeric pairs ($\textit{SS/RR}$ and $\textit{RS}$) with distinct resonances in their $^1$H and $^7$Li NMR spectra. The ee can be calculated simply from integration of the $^1$H and/or $^7$Li NMR spectra.We thank the EU for a Marie Curie Intra European Fellowship within the seventh European Community Framework Programme (R. G. R.) and an Advanced Investigator Award (D. S. W.). We also thank the Fonds der Chemischen Industrie and the Studienstiftung des deutschen Volkes (Scholarships for S. H.)

Pattern logics and auxiliary relations

A common theme in the study of logics over finite structures is adding auxiliary predicates to enhance expressiveness and convey additional information. Examples include adding an order or arith-metic for capturing complexity classes, or the power of real-life declarative languages. A recent trend is to add a data-value com-parison relation to words, trees, and graphs, for capturing modern data models such as XML and graph databases. Such additions often result in the loss of good properties of the underlying logic. Our goal is to show that such a loss can be avoided if we use pattern-based logics, standard in XML and graph data querying. The essence of such logics is that auxiliary relations are tested locally with respect to other relations in the structure. These logics are shown to admit strong versions of Hanf and Gaif-man locality theorems, which are used to prove a homomorphism preservation theorem, and a decidability result for the satisfiability problem. We discuss applications of these results to pattern logics over data forests, and consequently to querying XML data