Manufacturing equivalent Clinker by indirect mechanosynthesis process

International audienceThis study is focused to the proposition of new cement manufacturing process. It is widely known that the cement production is responsible for a significant CO2 release each year (approximatively 4 billon ton). So, it is became necessary to find another cement manufacturing process with a minimum CO2 emission. The aim of this work is to manufacture equivalent clinker by indirect mechanosynthesis process. It consists to combine between mechanical activation of the raw materials (mixture of limestone and clay) and heat treatment less than 900 °C. The equivalent clinker obtained by this method shows the presence of the alite (tricalcim silicate) C3S and belite (dicalcium silicate) C2S and Tricalcium aluminate C3A. CO2 emission by this technique is estimated by 0.3 Ton for 1 Ton of equivalent clinker

Magnetic properties of nanocrystalline Fe-10%Ni alloy obtained by planetary ball mills

International audiencePlanetary ball mill PM 400 from Retsch (with different milling times for X = 400 rpm, x = 800 rpm) and P4 vario ball mill from Fritsch (with different milling conditions (X/x), X and x being the disc and the vial rotation speeds, respectively) are used for obtaining nanocrystalline Fe-10wt% Ni. The structure and magnetic properties are studied by using X-ray diffraction, SEM and hysteresis measurements, respectively. The bcc-Fe(Ni) phase formation is identified by X-ray diffraction. The higher the shock power and the higher milling time are, the larger the bcc lattice parameter and the lower the grain size. The highest value of the coercivity is 1600 A/m for Fe-10 wt.%Ni (with shock mode (424 rpm/100 rpm) after 36 h of milling), while the lowest value is 189 A/m for (400 rpm/800 rpm) after 72 h of milling. The milling performed in the friction mode has been found to lead the formation of alloys exhibiting a soft magnetic behavior for nanocrystalline Fe-10%Ni

Analysis of structure and magnetic properties of nanocrystalline milled alloys

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Structure and magnetic properties of nanocrystalline Co–Ni and Co–Fe mechanically alloyed

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First principles investigation of the substitutional doping of Mn in Mg2Ni phase and the electronic structure of Mg3MnNi2 phase

International audienceThe substitutional doping of Mn in Mg2Ni phase and the electronic structure of Mg3MnNi2 phase have been investigated by first principles density functional theory calculations. The calculation of enthalpy of formation shows that among the four different lattice sites of Mg(6f), Mg(6i), Ni(3b) and Ni(3d) in Mg2Ni unit cell, the most preferable site of substitution of Mn in Mg2Ni lattice has been confirmed to be Mg(6i) lattice site. The constructed Mg9Mn3Mg(6i)Ni6 structure by replacing 3 Mg atoms at Mg(6i) lattice sites with 3 Mn atoms in the Mg2Ni unit cell is less stable. In contrast, the cubic Mg3MnNi2 phase that has the same composition as that of Mg9Mn3Mg(6i)Ni6 structure possesses good stability. Analysis of density of states (DOS) indicates that there is a strong hybridization between Mg s, Mg p and Ni d electrons, which is dominant in controlling the structural stability of pure and Mn-doped Mg2Ni phases. The Mn-substitution in Mg2Ni unit cell weakens the interaction between Mg s, Mg p and Ni d electrons, especially for Mg9Mn3Mg(6i)Ni6 phase. The cubic Mg3MnNi2 phase possesses a strong hybridization between Mn and Mg, Ni atomic orbits under simultaneously retaining the strong bonding among Mg s, Mg p and Ni d electrons. Based on the calculated results, the stability of phases gradually decreases along the sequence pure Mg2Ni phase &gt Mg3MnNi2 phase &gt Mn-substitution doped Mg2Ni phase

Cement and Clinker Production by Indirect Mechanosynthesis Process

Global cement production has reached 3.9 billion tons. However, the clinkerization process, which is the basis of cement production, is responsible for an approximate annual global CO2 emission of 2 billion tons. As part of CEMBUREAU’s 5C strategy, the European cement industry aims to achieve carbon neutrality throughout the cement-concrete value chain by 2050. This article is a continuation of the previous article on the indirect mechanosynthesis clinkerization process, which combines mechanical activation (high-energy milling) and thermal treatment at lower temperatures (from 900 °C) than those used for conventional clinkerization to produce clinker. With this process, we manufactured cement and clinker from industrial and laboratory raw mixes, which had to be rectified by adding kaolinite in compliance with the different cement indicators (LSF, SM, AM). The cement and clinker produced by indirect mechanosynthesis (15 min of mechanical activation and heat treatment 900 °C or 1200 °C) were characterized. In order to test the hydraulic properties of the cement produced, cement pastes were made. Mechanical and structural studies were carried out (between 70 and 90% of C2S). Mechanical tests revealed for 7 curing days, the values of 3.60 and 7.60 MPa at 900 °C and 1200 °C, respectively, in comparison to commercial cements CEM I and CEM III (23.03 and 19.14 MPa)

Formulation of Modified Cement Mortars Using Optimal Combination of Fly Ashes, Shiv, and Hemp Fibers

This study reports the combined effects of fly ashes, hemp fibers, and shives on the strength performance of modified mortars. Fly ashes are first processed using high-intensity mechanical milling. Natural fibers are observed using X-ray microtomography to reveal the microstructural arrangement. Preliminary formulations are attempted with different proportions of hemp fibers and shives up to 4%. X-ray diffraction, infrared, and thermal gravimetric analysis (TGA) methods are used to reveal the main structural changes in modified cement pastes. Workability and strength characteristics of various formulations are evaluated for ranking. The best performing modified mortars are selected based on their strength performance to formulate the mix proportions of milled fly ash and cement mortar. The experimental results demonstrate the beneficial effect of adding hemp fibers with shiv to achieve acceptable workability. In addition, it was found that the optimal hemp content in modified mortar was 3%. This amount minimizes the negative effect of natural additions on mechanical strength. Finally, fly ashes are found to be an efficient leverage to formulate modified mortars exhibiting a strength performance superior to that of the reference mortar. (C) 2019 American Society of Civil Engineers

Cement and Clinker Production by Indirect Mechanosynthesis Process

Global cement production has reached 3.9 billion tons. However, the clinkerization process, which is the basis of cement production, is responsible for an approximate annual global CO2 emission of 2 billion tons. As part of CEMBUREAU’s 5C strategy, the European cement industry aims to achieve carbon neutrality throughout the cement-concrete value chain by 2050. This article is a continuation of the previous article on the indirect mechanosynthesis clinkerization process, which combines mechanical activation (high-energy milling) and thermal treatment at lower temperatures (from 900 °C) than those used for conventional clinkerization to produce clinker. With this process, we manufactured cement and clinker from industrial and laboratory raw mixes, which had to be rectified by adding kaolinite in compliance with the different cement indicators (LSF, SM, AM). The cement and clinker produced by indirect mechanosynthesis (15 min of mechanical activation and heat treatment 900 °C or 1200 °C) were characterized. In order to test the hydraulic properties of the cement produced, cement pastes were made. Mechanical and structural studies were carried out (between 70 and 90% of C2S). Mechanical tests revealed for 7 curing days, the values of 3.60 and 7.60 MPa at 900 °C and 1200 °C, respectively, in comparison to commercial cements CEM I and CEM III (23.03 and 19.14 MPa)