Modeling and gPROMS based simulation of adsorption process for the removal of Cu (II) from aqueous wastewater

40-46The present work studies the performance of Indion 730 (Strong acid) ion exchange resin for the removal of Cu (II). The modeling and gPROMS based simulation is used to study the sorption capacity, equilibrium, and performances of Indion 730 ion exchange resin. The extraction effectiveness of the resin is studied by using breakthrough curves. The experimental and simulation results were compared. A numerical model is proposed for the investigation of the ion exchange phenomenon using gPROMS using various optimized parameters like flow rate, bed height, and initial concentration of wastewater containing Cu (II) heavy metal ion in the column. For instance, the effects of flow rate, bed height, and inlet concentration of heavy metal on a breakthrough curve are investigated in depth. The results illustrate that the predicted theoretical breakthrough curves show analogous patterns with the corresponding investigational output with a discrepancy of the equilibrium time. The predictions of the model will help to discover the optimal conditions of operation

Synthesis and Characterization of Multifunctional Metal‐Organic Framework (Ni‐ZIF‐67) Decorated Waterborne Polyurethane (Ni‐ZIF‐67/WPU) Nanocomposites: Sonochemical Approach

Abstract This work investigates the effect of a modified nickel‐doped metal‐organic framework (Ni‐ZIF‐67) as a filler on thermal, mechanical, and water vapor permeability properties of environmentally friendly waterborne polyurethane (WPU). The facile and greener ultrasound (sonochemical) technique is developed to prepare multifunctional Ni‐ZIF‐67@WPU nanocomposites, exhibiting superior crystallinity and uniform distribution. The resultant Ni‐ZIF‐67 nanoparticles and Ni‐ZIF‐67@WPU films are characterized by various techniques, including powder XRD, FE‐SEM, FTIR, TGA, UTM, contact angle, and antibacterial properties. Ni‐ZIF‐67@WPU nanocomposites exhibited excellent three‐fold mechanical performance (tensile strength ≈22 MPa) at a very low 5 wt.% filler loading and high thermal stability compared to pristine WPU. In addition, Ni‐ZIF‐67@WPU exhibited optimum water vapor permeability performance at 5.0 wt.% filler with the potential antibacterial application. Demonstrate that the rapid and facile synthesis approach can enhance the interaction of filler and matrix, high surface area, and tuneable pore size of filler material. This new insight has a new green approach for fabricating advanced nanocomposites toward practical utilization