Adsorption of methyl orange from aqueous solution onto calcined Lapindo volcanic mud

In this study, calcined Lapindo volcanic mud (LVM) was used as an adsorbent to remove an anionic dye, methyl orange (MO), from an aqueous solution by the batch adsorption technique. Various conditions were evaluated, including initial dye concentration, adsorbent dosage, contact time, solution pH, and temperature. The adsorption kinetics and equilibrium isotherms of the LVM were studied using pseudo-first-order and -second-order kinetic equations, as well as the Freundlich and Langmuir models. The experimental data obtained with LVM fits best to the Langmuir isotherm model and exhibited a maximum adsorption capacity (qmax) of 333.3 mg g-1; the data followed the second-order equation. The intraparticle diffusion studies revealed that the adsorption rates were not controlled only by the diffusion step. The thermodynamic parameters, such as the changes in enthalpy, entropy, and Gibbs free energy, showed that the adsorption is endothermic, random and spontaneous at high temperature. The results indicate that LVM adsorbs MO efficiently and could be utilized as a low-cost alternative adsorbent for the removal of anionic dyes in wastewater treatment

Performance of tight ultrafiltration membrane in textile wastewater treatment via MPR system : effect of pressure on membrane fouling

Industrial textile wastewater can be considered as main water polluting source in which constitutes a threat to human health and ecosystems; due to high water consumption and generated a large volume of color liquid waste. In the present study, the effect of various applied pressure in membrane photocatalytic reactor (MPR) system using ZnO-PEG nanoparticles and polypiperazine amide tight ultrafiltration (UF-PPA) for textile wastewater treatment was systematically investigated mainly through membrane fouling phenomenon. Results showed that the final permeate flux after 180 min was found to increase with the increase of applied pressure which obtained 0.4133 at 6 bar. Under 6 bar of pressure, the dye rejection of permeate was successfully reduced by approximately 100%. The Field Scanning Electron Microscopy (FESEM) analysis was also revealed that 6 bar of applied pressure did not affect or changed the structure of membrane cross-sectional pattern of UF-PPA membrane. In summary, the integrated usage of ZnO-PEG nanoparticles in photocatalysis combined with UF-PPA process improved the membrane fouling phenomenon and able to completely remove the colour from the feed of industrial dye wastewater

Limb hypothermia for preventing paclitaxel-induced peripheral neuropathy in breast cancer patients: A pilot study

10.3389/fonc.2016.00274Frontiers in Oncology6JAN27